Answered: Question 5: He2+1 would have the same…

Question 5: He2+1 would have the same bond order and magnetism (paramagnetic/diamagnetic) as H₂-1 O True O False Check Reuse <> Embed H-P

Chemistry: The Molecular Science

5th Edition

ISBN:9781285199047

Author:John W. Moore, Conrad L. Stanitski

Publisher:John W. Moore, Conrad L. Stanitski

Chapter7: Molecular Structures

Section: Chapter Questions

Problem 26QRT

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2.
For each statement, indicate whether it is true or false. (a) Inorder to make a covalent bond, the orbitals on each atom inthe bond must overlap. (b) A p orbital on one atom cannotmake a bond to an s orbital on another atom. (c) Lone pairsof electrons on an atom in a molecule influence the shape ofa molecule. (d) The 1s orbital has a nodal plane. (e) The 2porbital has a nodal plane.
Describe the types of bonds and the orbitas in CH3-CH=CH-CH3 Drawa strcture indicating the sigma and pi bonds. (USse colors to represen te orbitals and the overlapping of the orbitals.)
The sulfate ion can be represented with four S—O bonds orwith two S—O and two S=O bonds. (a) Which representation is better from the stand point of formal charges? (b) What is theshape of the sulfate ion, and what hybrid orbitals of S are postu-lated for the σ bonding? (c) In view of the answer to part (b),what orbitals of S must be used for the π bonds? What orbitalsof O? (d) Draw a diagram to show how one atomic orbital fromS and one from O overlap to form a π bond.
Give the hybridization for the O in H3O+.
(a) Methane (CH4) and the perchlorate ion (ClO4- ) are bothdescribed as tetrahedral. What does this indicate about theirbond angles? (b) The NH3 molecule is trigonal pyramidal, while BF3 is trigonal planar. Which of these molecules is flat?
The cations O2+ and N2+ are formed when molecules of O2 and N2 are subjected to intense, high-energy solar radiation in Earths upper atmosphere. Write the electron configuration for O2+. Predict its bond order and magnetic behavior.
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Which atomic orbitals overlap to form the bonds in ClF?
The molecular orbital diagram of NO shown in Figure 10.47 also applies to the following species. Write the molecular orbital electron configuration of each, indicating the bond order and the number of unpaired electrons. (a) LiBe+ (b) CO+ (c) CN (d) OF Figure 10.47 Molecular orbital diagram for nitric oxide (NO). The molecular orbital diagram for NO predicts a bond order of 2.5 and predicts that the molecule is paramagnetic with one unpaired electron. These predictions are verified by experimental measurements.
Histidine is an essential amino acid that the body uses to form proteins. The Lewis structure of histidine follows. What are the approximate values for bond angles 1 through 5 (indicated on the structure by blue numbers)?
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