2. Considering these strategies, how might you synthesise the compounds (12) which are used to inhibit the germination of weeds. 7 73 OMe ArN CI (12)
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- Draw the products formed when A and B are treated with each of the following reagents: (a) Br2, FeBr3; (b) HNO3 , H2SO4 ; (c) CH3CH2COCl,AlCl3.Digitalis is a preparation made from the dried seeds and leaves of the purple foxglove, Digitalis purpurea, a plant native to southern and central Europe and cultivated in the United States. The preparation is a mixture of several active components, including digitalin. Digi- talis is used in medicine to increase the force of myocardial contraction and as a conduction depressant to decrease heart rate (the heart pumps more forcefully but less often). HC OH H,C H CH3 H. H. (a) Describe this glycosidic bond OCH, H A (b) Draw an open-chain Fischer projection of this monosaccharide CH3 H. (e) Describe this glycosidic bond OCH, HA H. HO H) H. OH НО (d) Name this monosaccharide unit H. OH DigitalinAspartame, the sweetener used in the commercial products NutraSweet and Equal, is 200 times sweeter than sucrose. What products will be obtained ifaspartame is hydrolyzed completely in an aqueous solution of HCl?
- Digitalis is a preparation made from the dried seeds and leaves of the purple foxglove, Digitalis purpurea, a plant native to southern and central Europe and cultivated in the United States. The preparation is a mixture of several active components, including digitalin. Digitalis is used in medicine to increase the force of myocardial contraction and as a conduction depressant to decrease heart rate (the heart pumps more forcefully but less often).Atorvastatin (Lipitor) is used to decrease patient serum cholesterol levels. It works by inhibiting an enzyme called HMG-CoA reductase. In one synthesis of atorvastatin that produces the desired single enantiomer of the final product, the following reagents are used. Draw the structure of synthetic intermediate A. to H3C- -CI NaCN A B HO, DMSO Pyridine Use the wedge/hash bond tools to indicate stereochemistry where it exists. Should you want to restart the exercise, the drop-down menu labeled on the sketcher. starting points can be used to redraw the starting molecule P aste ору H3C, „CH3 CHEH3 НО. CH3 Previous Next :Othe carbonyl donor or precursor in the following reaction is: a. A b. B c. C d. NaOH
- Draw the arrow-pushing mechanism of the following reaction:In the following reaction, iodine monochloride (ICI) effectively serves as a source of an electrophilic lodonium species, l'U. Org. Chem 2005, 70, 3511-3517). Propose a mechanism for the formation of each of the two products, A and B. OMe Fr A MeO ICI OMe BProstaglandins are a class of cicosanoids, fatty acid derivatives with a variety of extremely potent actions on vertebrate tissues. They are responsible for producing fever and inflammation and its associated pain. Prostaglandins are derived from the 20- carbon fatty acid arachidonic acid in a reaction catalyzed by the enzyme prostaglandin endoperoxide synthase. This enzyme, a cyclooxygenase, uses oxygen to convert arachidonic acid to PGG2, the immediate precursor of many different prostaglandins. Rate of formation of PGG2 with 10 mg/ml ibuprofen (mM/min) Arachidonic acid (mM) Rate of formation of PGG2 (mM/min) 0.190 12.3 0.228 13.9 0.342 17.5 0.570 1.33 22.2 28.8 7.71 8.88 11.9 16.3 24.0 The kinetic data given in the table are for the reaction catalyzed by a mutant of prostaglandin endoperoxide synthase. Focusing here on the first two columns, determine the Vmax and Km of the enzyme. Vmax = Km mM/min mM
- What reagents are needed to convert attached compound to acetophenone (C6H5COCH3)?[ 16 ] which of following compound(s) is/are neither acetal nor hemiacetal ? он Но Он осH-CHз CHз ОН OCH3 (1) ( II ) ( III ) (IV ) (V) (a ) compounds III and V (b) compounds Il and II (c) compounds I and V (d ) compounds IV and V (e) compounds I and IVd-Glucuronic acid is found widely in plants and animals. One of its functions is to detoxify poisonous HO-containing compounds by reacting with them inthe liver to form glucuronides. Glucuronides are water soluble and, therefore, readily excreted. After ingestion of a poison such as turpentine or phenol, theglucuronides of these compounds are found in urine. Draw the structure of the glucuronide formed by the reaction of β-d-glucuronic acid and phenol.
