2. Considering these strategies, how might you synthesise the compounds (12) which are used to inhibit the germination of weeds. 7 73 OMe ArN CI (12)
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- draw the products formed if the compound reacts with: [assymetric synthesis] a.) NADH (Re Reduction) b.) NaBH4 c.) LiAlH4Draw the organic product(s) formed when CH3CH2CH2OH is treated withfollowing reagent : [1] NaH; [2] CH3CH2Brrivatives: Nucleophilic Acyl Substitution Reactions - EOC O C-O [References] One step in the gluconeogenesis pathway for the biosynthesis of glucose is the partial reduction of 3-phosphoglycerate to give glyceraldehyde 3-phosphate. The process occurs by phosphorylation with ATP to give 1,3-bisphosphoglycerate, reaction with a thiol group on the enzyme to give an enzyme-bound thioester, and reduction with NADH. H-C-OH ATP ADP CH₂OPO32- 3-phosphoglycerate 0= OPO32- C H-C-OH CH₂OPO32 1,3-bisphosphoglycerate Enz-SH PO43- O= C S-Enz H-C-OH CH₂OPO3² (Enzyme-bound thioester) NADH/H+ O=C NAD*, Enz-SH H H-C-OH CH₂OPO3²- glyceraldehyde 3-phosphate Propose a structure for the first intermediate in the reaction of the enzyme-bound thioester with NADH to form glyceraldehyde 3-phosphate. To simplify the drawing process, substitute the structure below for the enzyme-bound thioester. S-CH3 substitute for the CH2CH3 enzyme-bound thioester You do not have to consider stereochemistry. • You do not have…
- Draw the product formed when (CH3CH2CH2CH2)2CuLi is treated withattached compound. In some cases, no reaction occurs.التاريخ تليله : Egbgbl You need to prefare l:5Lof 25 Wy Solutionof adurg, how much activeingredient is cequired?The following isomerization reaction, drawn using D-glucose as starting material, occurs with all aldohexoses in the presence of base. Draw a stepwise mechanism that illustrates how each compound is formed. сно сно сно CH2OH C=0 H- OH H- -OH но- H- но H- "OH но H- Но H- но H- H- -H- H20 H- HO- O- H- -O- H- -OH -O- OH ČHOH CH,OH ČH2OH ČH2OH (recovered starting material) D-glucose