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- C1jpg, jpeg, png files only! 7 Provide a short answer for why the secondary alkyl halide is the major product versus the tertiary alkyl halide from free radical halogention H₂C HJ NBS peroxides H₂C Br H₂C Br= + enantiomer + enantiomer Major Minor Delete KThis is an example of a [1,3] sigmatropic rearrangement. Can someone explain how this is 1,3 (number the carbons) and draw the anion / cation transition state
- Predict the major product of this reaction. K2Cr2O7 H3O* II HO2C. CO2H НО HO. II IV HO2C. HO A) I B) I| C) II D) IVChemistry Identify the structure of (E)-4,5-dimethylhept-3- ene. صلى سلم ماده معده صلر What is the expected major product of the following reaction? HBr ? || IV OV Br 11 ||| Br IV Br مام VOf the two alkene products that result from this reaction, which is the expected major product? Why? + PPH3 H. E-Stilbene 7-Stilbene O 1) The major product is Z-stillbene as it has less steric hinderance. 2) The major product is Z-stillbene as it has more steric hindrance. O 3) The major product is E-stillbene as it has more steric hindrance. 4) The major product is E-stillbene as it has less steric hinderance.
- 9- Predict the product of each of the following sigmatropic reactions, indicating the [x,y] rearrangement for each. ممل H3C H DH3C CH₂CH3 H H3C DH3C CH₂CH39. The four compounds listed below undergo SN1 reactions at increasingly faster rates. For each compound, provide the contributing resonance forms for the carbocation intermediate that would be formed. Explain why the resonance forms provide information about the rate differences. Br eloo esnsib to0 018-terl (V-) woled bew Br TII ỌCH3 VI Br efin 8 to muloage AMA H ar ni ese of oaqe uoy bluow 6uleot iedW 8 Snoltone gaiwollot erl of 18 Br oubog toom) (blsitrwob) blall wol ta anoloiq olemots yino ed bluow enerfT A Jolduch.a.ed.bluow.nodhsa.ailysad ad no anotong onl tot leipie enT 8 Jolght s od bluaw anoioiq lytom er tot lenpie erdT Jolduob s ed bluow anoto anegotbyd S yino not olsigatni bhiow anolong lydlam arl hol langiae enT3Rank the following carbocations according to stability (1: most stable, 5: least stable.)