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- 2. Consijder the reactiojn scheme below a. Draw the major product of this reaction. Show clearly (using wedge-and-dash lines) all stereoisomers formed under these reaction conditions. 1. BH3:THF 2. H2O2, NaOH b. What is the stereochemical relationship between the different stereoisomer products you drew in part 2a.?What are the major products of the following reactions? Include stereochemistry. a. 1. Hg(OAc)₂, CH₂OH 2. NaBH4, H₂O, EtOH b. 1. Hg (OAc)₂, (CH3)₂CHOH 2. NaB H₁, H₂O, EtOH4. Predict the major organic product(s) of the following reactions. Be sure to clearly identify stereochemistry as appropriate. a. b. C. d. 1. BH3, THF 2. H₂O₂, NaOH Br CH₂12 1. Mg, THF 2. D₂0 Zn-Cu CH₂Cl2 Na DMF
- Predict the major products of the following reaction. Be sure to use wedge and dash bonds to show the stereochemistry of the products when it's important, for example to distinguish between two different major products...10. Write out the mechanism (intermediate/transition state) for this reaction. Indicate stereochemistry in product. H₂C Br H KOH S21. Identify the products of the following transformations. Br HCI CH; H;C-c=CH, 1. BH3 2. HO, H;0,, H,0 H*, H;O Br2 H,O
- Q1: Determine the major product(s) of the following reaction with correct stereochemistry where applicable. H2SO4 (cat.) H) XH OH heat Br 1) MeOH SN1 Q2. Ranke the following in the order of increasing reactivity towards SN1 reaction. CH3 CH3 CH3 H2C CH2 CH3 CH3 H₂C CH2 CH3 CH3 H2C CH2 H3C Br H3C Br H3C CI Br I ။ III IV Least reactive Most reactiveDraw the final major product(s) for each reaction in the designated box. Indicate stereochemistry Page 7 WInen applicable. Br TMSCI 1. Mg, Et20 Bu4N F НО EtzN 2. THE 3. HСI (aq) РСС 1. MeMgBr Jones reagent ОН CH2CI2 2. HCI (aq) XS HBr МСРВА NaSH (aq) CH2CI24. Provide the products for the reactions. Take note of the changes and how they tie together for the overall result. Br NaNH2 H20 З еq Br Br NaNH2 2 eq Br Bгz 1. NANH2, 3 eq 2. H20 Он conc. H2SO4 Br2 1. NaNH2, 3 eq heat 2. Нао