5% Sn1 reaction rates 5) List the following alkyl halides in order of their increasing reactivity as substrates in SN1 reactions with H2NCH 3. :CI :Ci-
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- 7Write the steps that are critical in the following reaction in order to explain the stereo-chemical outcome at the carbon marked with the asterisk.13. Which one of the following represents the transition state of the rate-determining step of the reaction shown below between tert-butyl bromide and methanol in which isobutylene is formed? The reaction takes place with an E1 mechanism. The overall reaction is- H3C H3C CH3 H3C CH3 Omm Θό -Br Ꮎ -Br H A CH3 H3C B H3C H3C SOOH-CH2 CH3 SOHCH2CH H -Br H (CH3)3C-Br (CH3)2C=CH2 + HBr с D CH3OH CH3 CH3
- H3C-C O: H ethanal :CN: and the electrophile is cyanide ion In the step you have just written, the nucleophile is slow rate-determining Ö—0—1 H3C-C-C=N; adductComplete the diagram of reactions without mechanisms by giving the reaction conditions or the missing productThe major organic product in the reaction sequence below is:
- Which of the following labelled hydrogens will be the most susceptible for base-abstraction in an elimination reaction mechanism? H₂ H₂ 0000 He Ha H₂ H₂ H₂ Hd Br t-BuOH A 4a) Sketch the energy diagram for the conversion of tertiary butyl bromide to methyl t-butyl ether. Note that this is a two step reaction with the t-butyl cation as an intermediate. Assume that this is overall an exothermic reaction. Show the location of both transition states and the intermediate. The first step has the higher energy of activation and is the rate determining step. (CH3)3C-Br ------> (CH3)3C+ + Br- (CH3)3C+ + H3CO- ------> (CH3)3C-O-CH3 (b)Draw the curved arrow mechanism and the transition state when the tertiary butyl carbocation reacts with the methoxide ion to give an ether. (CH3)3C+ + H3CO- ------> (CH3)3C-O-CH3OH OH ∞∞ BF3 Et₂O This reaction takes place via a pinacol rerrangement. Please, draw curved arrows to show the movement of electrons in this SPECIFIC step of the reaction mechanism. +BF3 HO: :OH OH (BF3OH)
- which of the following electrophiles would yield the fastest reaction rate in an SN1 reactionWhat is(are) the major final product(s) formed during the following sequence of reactions? 01 11 V 1.0₂ 2. (CH₂)₂S C₂H₂O 2 identical molecules ||| =PPhy < IV орнаFor the nitration of a monosubstituted benzene, which substituent, when attached to benzene, produces the fastest reaction rate? —Br —CH3 -OCOCH3 —OCH3