5% Sn1 reaction rates 5) List the following alkyl halides in order of their increasing reactivity as substrates in SN1 reactions with H2NCH 3. :CI :Ci-
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- 7Write the steps that are critical in the following reaction in order to explain the stereo-chemical outcome at the carbon marked with the asterisk.3. The following three SNAR transformations follow different mechanisms. Draw an intermediate or transition state for each reaction that relates the correct mechanism. Write a short sentence as to why that is the correct intermediate for the reaction. Reaction 1: Reaction 2: NO2 NO2 NO₂ + NaOMe NO2 + NaOH2 1. aq NaHCO3. 100 C 2. H₂O+ OMe NO2 NO₂ OH ŇO₂ NO2 Reaction 3: CFa Br CF3 8--2 + NaNH2 NH3 NH₂ Intermediate/transition state Intermediate/transition state Intermediate/transition state
- 13. Which one of the following represents the transition state of the rate-determining step of the reaction shown below between tert-butyl bromide and methanol in which isobutylene is formed? The reaction takes place with an E1 mechanism. The overall reaction is- H3C H3C CH3 H3C CH3 Omm Θό -Br Ꮎ -Br H A CH3 H3C B H3C H3C SOOH-CH2 CH3 SOHCH2CH H -Br H (CH3)3C-Br (CH3)2C=CH2 + HBr с D CH3OH CH3 CH34. Outline a detailed mechanism for the reaction below. Identify the abbreviation for the reaction mechanism. НО H3PO4Consider the three-step mechanism for the reaction of A through intermediates B and C to produce D shown below. Which of the three steps is rate-limiting?
- Which of the structures shown depicts the most stable carbocation intermediate formed in a hydrohalogenation reaction? I II III IV V12. In the hydrogenation reaction shown, which of the alkenes below would yield the observed products? H₂, Pd/C alkene + one diastereomer || III IV (A) I and II (B) II and III (C) IV and III (D) II and IV (E) I and IIIWhich of the following labelled hydrogens will be the most susceptible for base-abstraction in an elimination reaction mechanism? H₂ H₂ 0000 He Ha H₂ H₂ H₂ Hd Br t-BuOH A 4