2- Identify the nuclephile and electrophile in each reaction below and label them. a. b. :0: :0: + H-Cl = + :C=N: C. H-Ö-H + H3C-MgBr H + cr :0: CN + CH4 + HÖ: MgBr 3- MATCH each definition to one of the terms below. Place the letter of the term in the blank to the left of the definition. a. polarization b. addition reaction C. homolytic bond breakage d. electrophile e. polar reaction f. substitution g. nucleophile h. radical reaction i. elimination reaction heterolytic bond breakage a. A process involving symmetrical bond breaking and bond making. b. This occurs when both bonding electrons remain with one product fragment. C. A reaction where two reactants exchange parts to give two new products. d. A general term for species which have electron rich sites that can form a bond by donating a pair of electrons to an electron poor site. d. blank to the left of the definition. 4- MATCH each definition to one of the terms below. Place the letter corresponding to the term in the a. transition state b. endergonic reaction standard Gibbs free energy change exergonic reaction c. activation energy f. reaction intermediate a. A species that lies at an energy minimum between steps on a reaction. b. The energy needed by reactants to reach the transition state. C. A reaction where AG° is negative. d. AG°=-RT In Keq 4
2- Identify the nuclephile and electrophile in each reaction below and label them. a. b. :0: :0: + H-Cl = + :C=N: C. H-Ö-H + H3C-MgBr H + cr :0: CN + CH4 + HÖ: MgBr 3- MATCH each definition to one of the terms below. Place the letter of the term in the blank to the left of the definition. a. polarization b. addition reaction C. homolytic bond breakage d. electrophile e. polar reaction f. substitution g. nucleophile h. radical reaction i. elimination reaction heterolytic bond breakage a. A process involving symmetrical bond breaking and bond making. b. This occurs when both bonding electrons remain with one product fragment. C. A reaction where two reactants exchange parts to give two new products. d. A general term for species which have electron rich sites that can form a bond by donating a pair of electrons to an electron poor site. d. blank to the left of the definition. 4- MATCH each definition to one of the terms below. Place the letter corresponding to the term in the a. transition state b. endergonic reaction standard Gibbs free energy change exergonic reaction c. activation energy f. reaction intermediate a. A species that lies at an energy minimum between steps on a reaction. b. The energy needed by reactants to reach the transition state. C. A reaction where AG° is negative. d. AG°=-RT In Keq 4
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2,3 and 4 please!
Transcribed Image Text:2- Identify the nuclephile and electrophile in each reaction below and label them.
a.
b.
:0:
:0:
+
H-Cl
=
+ :C=N:
C.
H-Ö-H + H3C-MgBr
H
+
cr
:0:
CN
+
CH4
+ HÖ: MgBr
3- MATCH each definition to one of the terms below. Place the letter of the term in the blank to the left of
the definition.
a. polarization
b. addition reaction
C.
homolytic bond breakage
d. electrophile
e.
polar reaction
f.
substitution
g.
nucleophile
h.
radical reaction
i.
elimination reaction
heterolytic bond breakage
a.
A process involving symmetrical bond breaking and bond making.
b.
This occurs when both bonding electrons remain with one product fragment.
C.
A reaction where two reactants exchange parts to give two new products.
d.
A general term for species which have electron rich sites that can form a bond by donating
a pair of electrons to an electron poor site.
d.
blank to the left of the definition.
4- MATCH each definition to one of the terms below. Place the letter corresponding to the term in the
a.
transition state
b. endergonic reaction
standard Gibbs free energy change
exergonic reaction
c. activation energy
f.
reaction intermediate
a.
A species that lies at an energy minimum between steps on a reaction.
b.
The energy needed by reactants to reach the transition state.
C.
A reaction where AG° is negative.
d.
AG°=-RT In Keq
4
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