Answered: πp Op * Πρ Пр бр Пр A B 0 C₁₁* < C₁₂ <…

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πp Op * Πρ Пр бр Пр A B 0 C₁₁* < C₁₂ < C₁₂ 2 C₁₂ < C₁₂ < C₁₂* + C₁₂ < C₁₂ < C₁₂* D C₁₂ < C₁₂* < Cl₂ + 2

Introduction to General, Organic and Biochemistry

11th Edition

ISBN:9781285869759

Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres

Chapter2: Atoms

Section: Chapter Questions

Problem 2.8P

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Question

Consider the MO diagrams for these diatomic species. Rank the following diatomic species in order of bond dissociation energy (from smallest to largest).

πp
Op
*
Πρ
Пр
бр
Пр
A
B
0
C₁₁* < C₁₂ < C₁₂
2
C₁₂ < C₁₂ < C₁₂*
+
C₁₂ < C₁₂ < C₁₂*
D
C₁₂ < C₁₂* < Cl₂
+
2

Formula Formula Bond dissociation energy (BDE) is the energy required to break a bond, making it an endothermic process. BDE is calculated for a particular bond and therefore consists of fragments such as radicals since it undergoes homolytic bond cleavage. For the homolysis of a X-Y molecule, the energy of bond dissociation is calculated as the difference in the total enthalpy of formation for the reactants and products. X-Y → X + Y BDE = Δ H f X + Δ H f Y – Δ H f X-Y where, ΔHf is the heat of formation.

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