Gmail 9:43 AM Tue Nov 19 CozortExam-2 Fall 2024 copy fx ... Home Insert Draw Page Layout Formulas Data Review View AŒŒ < A✓ = Enter text or formula here A D E G H 8 9 3-In a phosphorous acid solution, the starting concentration is C₁ = [H2PHO3] = 3.18 10 (*Define) 11 Define: = x = 12 13 => = = ( 14 ("Calculate) 15 pH = 16 (*Define) numeral 17 => pH 18 (*Calculate) 19 20 Define: = 21 numeral unit 22 => [PO3² (aq)] = 23 (*Calculate) 24 K M N о P Q 99% General S T U V M, find the equilibrium concs. of [H3O+], [HPO3¯(aq)], [PO3²¯], and the pH knowing that (Ka₁ = 3.0x102, Ka2 = 1.66x107) ? [HPO3 (aq)] [H3O+] Ca Και )1/2 numeral unit = X )1/2 + [H3O+] log [OH-] x y Ka2 ) 1/2 [H3O+] [PO3(aq)] 4- Determine the [HPO3], [H₂PO3] as well as [H3O+] & [OH-] concentrations in a sodium phosphite Na₂PO3 salt solution at a conc of Cs = [PO3²] = 22222 26 Define: 28 30 => 31 (*Calculate) = X = = = ( numeral unit 0.017 M (Kai 3.0x102, Kaz 1.66x107) ? [HPO3(aq)] [OH-] Cs. Ka2 1/2 Kw Και 1/2 32 33 => [H3O+] = X + 34 (*Define) 35 36 => [H3O+] = 37 (*Calculate) numeral unit => pH (*Calculate) = 38 39 Define: [H2PO3(aq)] = Kbl Και Kw [H3O+] [H2PO3(aq)] Kaz 40 41 numeral unit 42 => [H2PO3(aq)] = 43 (*Calculate) 44 45 46 5-(a) Determine the [H3O+] concentration in a sodium biphosphite Na₂HPO3 salt solution at a conc of Cs = [HPO3] 0.14 M (Kai 3.0x102, Kaz 1.66x107) ? 47 48 Let's test if we can do an approximation where, Cs/ Kal > 100 => 49 Cs Και = 50 50 (Yes we can / No we cannot) apply the approximation. As you might predicted, solve the relations below: 51 52 => [H3O+] = Kal Kw 1/2 Cs Ka2 53 ("Define) 54 numeral unit 55 => [H3O+] = = 56 (*Calculate) 57 58 59 (b) If the sodium biphosphite Na₂HPO3 salt solution at a conc of Cs = [HPO3¯] = 1.5 M is added to a weak acid of 0.05 60 numeral 61 Define: pKal = 62 =>> pkal = (*Calculate) 63 64 Define: => PH = [H3O+] 65 66 67 => pH numeral = 68 69 70 (*Calculate) (c)What mass (g) of sodium biphosphite Na₂HPO3 salt is needed to prepare a buffer of pH = 3 using a 100 71 (*Use pKal obtained in part(b)) 72 Define: => PM 73 74 => PM = 75 (*Calculate) 76 77 Define: => m = 78 79 80 m = (*Calculate) numeral unit = 81 Sheet1 Sheet2 Sheet3 + numeral > < = M phosphorous acid solution. Calculate the pH of this buffer using Henderson Hasselbalch equation? Και Kw Ka2 log + log [H2PO3(aq)] [HPO3(aq)] pkal [OH-] mL volumetric flask when the molarity of the weak acid H2PO3 solution is [H2PO3] = 0.014 M [FW(Na₂HPO3) = 125.96 g/mole] pH ) [H₂PO3(aq)] FW pkal numeral V Log( + 10 e pH PM

World of Chemistry, 3rd edition
3rd Edition
ISBN:9781133109655
Author:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan L. Zumdahl, Donald J. DeCoste
Chapter1: Chemistry: An Introduction
Section: Chapter Questions
Problem 7A
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Gmail 9:43 AM Tue Nov 19
CozortExam-2 Fall 2024 copy
fx
...
Home
Insert
Draw
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Formulas
Data
Review
View
AŒŒ
<
A✓
=
Enter text or formula here
A
D
E
G
H
8
9
3-In a phosphorous acid solution, the starting concentration is C₁ = [H2PHO3] =
3.18
10
(*Define)
11
Define:
=
x
=
12
13
=>
=
=
(
14
("Calculate)
15
pH
=
16
(*Define)
numeral
17
=>
pH
18
(*Calculate)
19
20
Define:
=
21
numeral
unit
22
=>
[PO3² (aq)]
=
23
(*Calculate)
24
K
M
N
о
P
Q
99%
General
S
T
U
V
M, find the equilibrium concs. of [H3O+], [HPO3¯(aq)], [PO3²¯], and the pH knowing that (Ka₁ = 3.0x102, Ka2 = 1.66x107) ?
[HPO3 (aq)] [H3O+] Ca
Και
)1/2
numeral
unit
=
X
)1/2
+
[H3O+]
log
[OH-]
x
y
Ka2
) 1/2
[H3O+]
[PO3(aq)]
4- Determine the [HPO3], [H₂PO3] as well as [H3O+] & [OH-] concentrations in a sodium phosphite Na₂PO3 salt solution at a conc of Cs = [PO3²] =
22222
26
Define:
28
30
=>
31 (*Calculate)
=
X
=
=
=
(
numeral unit
0.017
M (Kai 3.0x102, Kaz 1.66x107) ?
[HPO3(aq)] [OH-]
Cs.
Ka2
1/2
Kw
Και
1/2
32
33
=>
[H3O+]
=
X
+
34
(*Define)
35
36
=> [H3O+]
=
37 (*Calculate)
numeral unit
=>
pH
(*Calculate)
=
38
39
Define: [H2PO3(aq)]
=
Kbl
Και
Kw
[H3O+]
[H2PO3(aq)] Kaz
40
41
numeral unit
42
=> [H2PO3(aq)]
=
43 (*Calculate)
44
45
46
5-(a) Determine the [H3O+] concentration in a sodium biphosphite Na₂HPO3 salt solution at a conc of Cs = [HPO3] 0.14
M (Kai 3.0x102, Kaz 1.66x107) ?
47
48
Let's test if we can do an approximation where, Cs/ Kal > 100
=>
49
Cs
Και
=
50
50
(Yes we can / No we cannot)
apply the approximation. As you might predicted, solve the relations below:
51
52
=>
[H3O+]
=
Kal
Kw
1/2
Cs
Ka2
53
("Define)
54
numeral
unit
55
=>
[H3O+]
=
=
56 (*Calculate)
57
58
59
(b) If the sodium biphosphite Na₂HPO3 salt solution at a conc of Cs = [HPO3¯] =
1.5 M is added to a weak acid of
0.05
60
numeral
61
Define: pKal =
62
=>> pkal =
(*Calculate)
63
64 Define:
=>
PH
=
[H3O+]
65
66
67
=>
pH
numeral
=
68
69
70
(*Calculate)
(c)What mass (g) of sodium biphosphite Na₂HPO3 salt is needed to prepare a buffer of pH =
3
using a
100
71
(*Use pKal obtained in part(b))
72
Define:
=>
PM
73
74
=>
PM
=
75
(*Calculate)
76
77 Define:
=>
m
=
78
79
80
m
=
(*Calculate)
numeral unit
=
81
Sheet1
Sheet2
Sheet3
+
numeral
>
<
=
M phosphorous acid solution. Calculate the pH of this buffer using Henderson Hasselbalch equation?
Και
Kw
Ka2
log
+
log [H2PO3(aq)] [HPO3(aq)] pkal
[OH-]
mL volumetric flask when the molarity of the weak acid H2PO3 solution is [H2PO3] = 0.014 M
[FW(Na₂HPO3) = 125.96 g/mole]
pH
)
[H₂PO3(aq)]
FW pkal
numeral
V
Log(
+
10
e
pH
PM
Transcribed Image Text:Gmail 9:43 AM Tue Nov 19 CozortExam-2 Fall 2024 copy fx ... Home Insert Draw Page Layout Formulas Data Review View AŒŒ < A✓ = Enter text or formula here A D E G H 8 9 3-In a phosphorous acid solution, the starting concentration is C₁ = [H2PHO3] = 3.18 10 (*Define) 11 Define: = x = 12 13 => = = ( 14 ("Calculate) 15 pH = 16 (*Define) numeral 17 => pH 18 (*Calculate) 19 20 Define: = 21 numeral unit 22 => [PO3² (aq)] = 23 (*Calculate) 24 K M N о P Q 99% General S T U V M, find the equilibrium concs. of [H3O+], [HPO3¯(aq)], [PO3²¯], and the pH knowing that (Ka₁ = 3.0x102, Ka2 = 1.66x107) ? [HPO3 (aq)] [H3O+] Ca Και )1/2 numeral unit = X )1/2 + [H3O+] log [OH-] x y Ka2 ) 1/2 [H3O+] [PO3(aq)] 4- Determine the [HPO3], [H₂PO3] as well as [H3O+] & [OH-] concentrations in a sodium phosphite Na₂PO3 salt solution at a conc of Cs = [PO3²] = 22222 26 Define: 28 30 => 31 (*Calculate) = X = = = ( numeral unit 0.017 M (Kai 3.0x102, Kaz 1.66x107) ? [HPO3(aq)] [OH-] Cs. Ka2 1/2 Kw Και 1/2 32 33 => [H3O+] = X + 34 (*Define) 35 36 => [H3O+] = 37 (*Calculate) numeral unit => pH (*Calculate) = 38 39 Define: [H2PO3(aq)] = Kbl Και Kw [H3O+] [H2PO3(aq)] Kaz 40 41 numeral unit 42 => [H2PO3(aq)] = 43 (*Calculate) 44 45 46 5-(a) Determine the [H3O+] concentration in a sodium biphosphite Na₂HPO3 salt solution at a conc of Cs = [HPO3] 0.14 M (Kai 3.0x102, Kaz 1.66x107) ? 47 48 Let's test if we can do an approximation where, Cs/ Kal > 100 => 49 Cs Και = 50 50 (Yes we can / No we cannot) apply the approximation. As you might predicted, solve the relations below: 51 52 => [H3O+] = Kal Kw 1/2 Cs Ka2 53 ("Define) 54 numeral unit 55 => [H3O+] = = 56 (*Calculate) 57 58 59 (b) If the sodium biphosphite Na₂HPO3 salt solution at a conc of Cs = [HPO3¯] = 1.5 M is added to a weak acid of 0.05 60 numeral 61 Define: pKal = 62 =>> pkal = (*Calculate) 63 64 Define: => PH = [H3O+] 65 66 67 => pH numeral = 68 69 70 (*Calculate) (c)What mass (g) of sodium biphosphite Na₂HPO3 salt is needed to prepare a buffer of pH = 3 using a 100 71 (*Use pKal obtained in part(b)) 72 Define: => PM 73 74 => PM = 75 (*Calculate) 76 77 Define: => m = 78 79 80 m = (*Calculate) numeral unit = 81 Sheet1 Sheet2 Sheet3 + numeral > < = M phosphorous acid solution. Calculate the pH of this buffer using Henderson Hasselbalch equation? Και Kw Ka2 log + log [H2PO3(aq)] [HPO3(aq)] pkal [OH-] mL volumetric flask when the molarity of the weak acid H2PO3 solution is [H2PO3] = 0.014 M [FW(Na₂HPO3) = 125.96 g/mole] pH ) [H₂PO3(aq)] FW pkal numeral V Log( + 10 e pH PM
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