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What is the major product of the elimination below? Please explain why the correct answer is letter A. Include detailed steps and a drawing explaining the mechanism of the reaction.
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- What or what are the nitration products of substances a, b and c below? CH3 CN OMe a) b) c) CF3What products will be formed in the reaction below? CI (A) (B) CI на ether CI (C) (D) CI CI Compounds A and B O Compounds A and C OCompounds B and D O Compounds C and DIdentify the product Q in the following reaction. CH,N2 Q CH,ОН, hv -COOE -COOME (В) (A) -COOME -COOME (C) (D)
- 8.108 Propose a plausible mechanism for the following transformation, which was used as the key step in the formation of the natural product heliol.Which of the following pairs of compounds are keto-enol tautomers? ОН (a) and H. II ОН ОН (b) and I II ОН (c) CH and CH I IIWhich compound is the major product of the reaction below? NH2 NH2 0 HN HN-O CI N(C2H5)3 (A) (B) (C) (D) Compound A Compound B Compound C Compound D
- Which is the major product of the reaction below? (1) Na EtO /EIOH (2) dil H*, H-O (A) (B) H2COO OCH3 (C) OCH3 (D) OCH3 Compound A Compound D Compound C Compound B(a) What is the structure of C, which is formed by oxy-Cope rearrangement of B with NaOEt? (b) Draw a stepwise mechanism for the conversion of C to the bicyclic alcohol D.(R)-Carvone, the major component of the oil of spearmint, undergoesacid-catalyzed isomerization to carvacrol, a major component of the oilof thyme. Draw a stepwise mechanism and explain why thisisomerization occurs.
- Provide products for the following reactions, including stereochemistry when necessary: a) NBS ROOR b) NBS ROOR c) NBS ROORIejimalide B, an anticancer agent with a 24-membered ring, is isolated from a tunicate found off Ie Island in Okinawa. (a) Label each double bond in iejimalide B as E or Z. (b) Label each tetrahedral stereogenic center as R or S. (c) How many stereoisomers are possible for iejimalide B?Reaction of 5,5-dimethoxypentan-2-one with methylmagnesium iodide followed by treatment with aqueous acid forms cyclic hemiacetal Y. Draw a stepwise mechanism that illustrates how Y is formed.