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What is the major product of the elimination below? Please explain why the correct answer is letter A. Include detailed steps and a drawing explaining the mechanism of the reaction.
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- Draw the major product formed for each reaction. Assume the reactions are irreversible. Include stereochemistry when products contain stereocenter(s). (d) (e) Br NaOCH3 HO CI NaHDraw the main organic product formed in each of the following reactions: (a) (b) (c) + HNO3 / H₂SO4 O CI CI AICI 3 AICI3(a) 11. (b) What is the major product of the elimiation below? |||-- EtONa EtOH (C) (d)
- Identify the product Q in the following reaction. CH,N2 Q CH,ОН, hv -COOE -COOME (В) (A) -COOME -COOME (C) (D)A key step in the synthesis of β-vetivone, a major constituent of vetiver, a perennial grass found in tropical and subtropical regions of the world, involved the reaction of compound A and dihalide B with two equivalents of LDA to form C. Draw a stepwise mechanism for this reaction. β-Vetivone contains a spiro ring system—that is, two rings that share a single carbon atom.8.108 Propose a plausible mechanism for the following transformation, which was used as the key step in the formation of the natural product heliol.
- Give the major products or reagents represented by letters C and D :Which of the following pairs of compounds are keto-enol tautomers? ОН (a) and H. II ОН ОН (b) and I II ОН (c) CH and CH I IIDraw a stepwise mechanism for the following reaction, one step in the synthesis of the cholesterol-lowering drug pitavastatin, marketed in Japan as a calcium salt under the name Livalo.
- Which of the following compounds is the major product of the reaction sequenc shown below? (1) Na CNCH3CN Br (A) (B) NH2 (2) H* H20, A он (C) (D) HO. O Compound C )Compound A Compound D )Compound BWhich is the major product of the reaction below? (1) Na EtO /EIOH (2) dil H*, H-O (A) (B) H2COO OCH3 (C) OCH3 (D) OCH3 Compound A Compound D Compound C Compound B(a) What is the structure of C, which is formed by oxy-Cope rearrangement of B with NaOEt? (b) Draw a stepwise mechanism for the conversion of C to the bicyclic alcohol D.