Predict the FINAL product for the following synthetic transformation: NH2 HNO3 H3O+ H2SO4 ? A B 0 NH2 NH2 NH2 O₂N O₂N A B C D NO2 NO2 D NH2 2 NO2
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- When cis-2-decalone is dissolved in ether containing a trace of HCl, an equilibrium is established with trans-2-decalone. The latter ketone predominates in the equilibrium mixture. Propose a mechanism for this isomerization and account for the fact that the trans isomer predominates at equilibrium.Identify A, B, and C, intermediates in the synthesis of the five-membered ring called an α- methylene-γ-butyrolactone. This heterocyclic ring system is present in some antitumor agents.Alt Fn Ctrl M2210: WS12 Provide the major organic product of the following reactions. Br2 OC(CH3)3 HBr hv hv ROOR rovide the major organic product of the following reactions.
- A C5H3 alkyne is reacted with Lindlar's catalyst and hydrogen gas to yield product with the following'H NMR resonances. Provide the structure for Product A and the alkyne 0.78 ppm triplet 3H 1.60 ppm doublet 3H 2.05 ppm doublet of quartets 2H 5.40 ppm doublet of quartets 1H 5.34 ppm doublet of triplets 1HReaction of phenol with acetone in the presence of an acid catalyst gives a compound known as bisphenol A, which is used in the production of epoxy and polycarbonate resins Propose a mechanism for the formation of bisphenol A. OH H;PO, + H,O НО HO Phenol Acetone Bisphenol AHydrolysis of amides is an important reaction, because it represents the first step in the digestion of dietary protein. Which of the following compounds is formed as a result of the hydrolysis of N,N-diethylpropanamide as shown below? CH3CH2 N-CH2CH3 + H₂O CH2CH3 HCI OA) B) CH3CH2 NH2 HO N-CH2CH3 CH2CH3 H CH3CH2 NHCH2CH3 D)
- Provide the major product of the following reaction:Provide the major expected product: OH OH LOH H2SO4 A.Reagent 3 list; commas separate the choices benzylamine,cyclohexlbromide, cyclohexylamine NaBH3CN catalytic H+, h30, NaOH Reagent 4 list; CH3(Ch2)2MgBr, cyclohexylamine NaBH3CN catalytic H+, Na2 Cr2 O7 H2O H2SO4,cyclohexabromide reagent 5 list; cyclohexylamine NaBH3CN catalytic H+,CH3(Ch2)2MgBr, cyclohexabromide, benzylamine
- X6-156. Arrange the following substituted anilines in increasing order of reactivity toward acetic anhydride: sllo NH2 ร้อเป็น NH2 NH2 edi NH2 O₂N. (a) (b) ---- (c) (d) bund NO2 CI H3C-N-CH3 Insmiy X 6-157. Suggest a mechanism for the preparation of acetic anhydride from acetic acid and acetyl chloride in the presence pyridine (an amine base).What is the major organic product obtained form the following sequence of reactions (assume that mixtures of ortho and para disubstituted compounds can be separated; continue the synthesis with either one)?Which of the following compounds undergoes the most rapid nucleophilic substitution with amide ion? A, B, C, or D?
