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- Among TiCl4, VCl3 and FeCl2- which one will be drawn more strongly into a magnetic field and why?What type of stretching results in IR absorption?6) This question is concerned with vibrational spectra (Infrared and Raman). a) How many normal modes of vibration are expected in these molecules? (Show calculations) i) Theobromine (the caffeine-like stimulant that is found in chocolate) b) In the molecular vibration shown here for trans-1,4-dichlorocyclohexane, both chlorine atoms stretch away from the carbon to which they are bonded (arrows). Will this mode be IR active? Will this mode be Raman active? In each case, why or why not? ii) Cyanopolyyne (an organic molecular wire that has been detected spectroscopically in interstellar space, and is postulated to be a precursor to biomolecules: HC=C-C=C-C=N c) Why are CH4 and CO₂ considered greenhouse gases, but O₂ and N₂ are not? d) Are the vibrations shown here a degenerate pair (Yes/No)? Why or why not? HN CI CH3 ci↑ ∙H -F CH3 -F
- 2. Describe some of the vibrational mode at stretching and bending associated with Infrared Spectroscopy. Draw representative structure denoting such vibrational modes.Why can UV or higher energy radiation not be used for non-destructive spectroscopy of polymer structure ? Why is resolution limited by wavelength?Explain surface characterisation techniques
- Using the knowledge established in the previous parts, answer the original question: Ultraviolet light with a wavelength longer than about 295 nm has little germicidal value. What is the frequency (in Hz) that corresponds to this wavelength? Hz2. Do you observe any change in the form of the absorbance bands while moving from nonpolar to polar solvents?how many IR bands are there in PdL2Cl2?
- Outline some methods for obtaining ultra-high orientation in polymers (e.g. Kevlar).The IR spectrum of HCN shows three strong absorption band at 3312 cm⁻¹, 2089 cm⁻¹ and 712 cm⁻¹ from this information alone can you deduce whether HCN is linear or nonlinear? Assuming that HCN is linear assign vibration to the three absorption bands.Which has a lower characteristic stretching Frequency, the C=O bond or band C-O bond.