22. Calculate the heat given off when one mole of BH, reacts withexcess oxygen according to the followingreaction:B₂H9(9)B₂O3(g)H₂O (9)2 B5H (g) + 12 Oa. -8687 kJb. -4343 kJc. -4041 kJd. 8393 kJ2(g)à 5 B₂O3(9)+ 9H₂O (9)2AH=73.2 kJ/mol;AH°= -1272.77 kJ/molAH,°= -241.82 kJ/mol

The problem is asking us to calculate the heat given off when one mole of B2H6 reacts with excess…

Answered: 22. Calculate the heat given off when…

World of Chemistry

7th Edition

ISBN:9780618562763

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter10: Energy

Section: Chapter Questions

Problem 31A

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The heat of neutralization, Hneut, can be defined as the amount of heat released (or absorbed), q, per mole of acid (or base) neutralized. Hneut for nitric acid is -52 kJ/mol HNO3. At 27.3C, 50.00 mL of 0.743M HNO3 is neutralized by 1.00 M Sr(OH)2 in a coffee-cup calorimeter. (a) How many mL of Sr(OH)2 were used in the neutralization? (b) What is the final temperature of the resulting solution? (Use the assumptions in Question 11.)
The thermochemical equation for the burning of methane, the main component of natural gas, is CH4(g)+2O2(g)CO2(g)+2H2O(l)H=890kJ (a) Is this reaction endothermic or exothermic? (b) What quantities of reactants and products are assumed if H = 890 kJ? (c) What is the enthalpy change when 1.00 g methane burns in an excess of oxygen?
When one mol of KOH is neutralized by sulfuric acid, q=56 kJ. (This is called the heat of neutralization.) At 23.7C, 25.0 mL of 0.475 M H2SO4 is neutralized by 0.613 M KOH in a coffee-cup calorimeter. Assume that the specific heat of all solutions is 4.18J/gC, that the density of all solutions is 1.00 g/mL, and that volumes are additive. (a) How many mL of KOH is required to neutralize H2SO4? (b) What is the final temperature of the solution?
Using the data in Appendix G, calculate the standard enthalpy change for each of the following reactions: (a) Si(s)+2F2(g)SiF4(g) (b) 2C(s)+2H2(g)+O2(g)CH3CO2H(l) (c) CH4(g)+N2(g)HCN(g)+NH3(g) ; (d) CS2(g)+3Cl2(g)CCl4(g)+S2Cl2(g)
How much heat is produced by combustion of 125 g of methanol under standard state conditions?
How much heat is produced when loo mL of 0.250 M HCl (density, 1.00 g/mL) and 200 mL of 0.150 M NaOH (density, 1.00 g/mL) are mixed? HCl(aq)+NaO(aq)NaCl(aq)+H2O(l)H298=58kJ If both solutions are at the same temperature and the heat capacity of the products is 4.19 J/g C, how much will the temperature increase? What assumption did you make in your calculation?
How much will the temperature of a cup (180 g) of coffee at 95 C be reduced when a 45 g silver spoon (specific heat 0.24 J/g C) at 25 C is placed in the coffee and the two are allowed to reach the same temperature? Assume that the coffee has the same density and specific heat as water.
How much heat is produced by burning 4.00 moles of acetylene under standard state conditions?
An industrial process for manufacturing sulfuric acid, H2SO4, uses hydrogen sulfide, H2S, from the purification of natural gas. In the first step of this process, the hydrogen sulfide is burned to obtain sulfur dioxide, SO2. 2H2S(g)+3O2(g)2H2O(l)+2SO2(g);H=1124kJ The density of sulfur dioxide at 25C and 1.00 atm is 2.62 g/L, and the molar heat capacity is 30.2 J/(mol C). (a) How much heat would be evolved in producing 1.00 L of SO2 at 25C and 1.00 atm? (b) Suppose heat from this reaction is used to heat 1.00 L of the SO2 from 25C to 500C for its use in the next step of the process. What percentage of the heat evolved is required for this?
9.65 When 0.0157 g of a compound with a heat of combustion of —37.6 kJ/mol is burned in a calorimeter, 18.5 j of heat is released. What is the molar mass of the compound?
When steam condenses to liquid water, 2.26 kJ of heat is released per gram. The heat from 168 g of steam is used to heat a room containing 6.44 104 g of air (20 ft 12 ft 8 ft). The specific heat of air at normal pressure is 1.015 J/(gC). What is the change in air temperature, assuming the heat from the steam is all absorbed by air?
For the reaction HgO(s)Hg(l)+12O2(g),H=+90.7kJ: a.What quantity of heat is required to produce 1 mole of mercury by this reaction? b.What quantity of heat is required to produce 1 mole of oxygen gas by this reaction? c.What quantity of heat would be released in the following reaction as written? 2Hg(l) + O2(g) 2HgO(s)

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