Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 5, Problem 45E
How much heat is produced by burning 4.00 moles of acetylene under standard state conditions?
Expert Solution & Answer
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Predict the major products of this organic reaction:
HBr (1 equiv)
cold
?
Some important notes:
• Draw the major product, or products, of this reaction in the drawing area below.
• You can draw the products in any arrangement you like.
• Pay careful attention to the reaction conditions, and only include the major products.
• Be sure to use wedge and dash bonds when necessary, for example to distinguish between major products that are enantiomers.
• Note that there is only 1 equivalent of HBr reactant, so you need not consider the case of multiple additions.
Erase something
Explanation
Check
2025 McGraw Hill LLC. All Rights Reserved. Ter
Q14. Fill this chart: (please refer to ppt notes/browser to answer these questions)
What alcohol is also called wood alcohol?
What is the common name of ethanol?
Draw the structure of phenol and thiophene?
Are bigger chain alcohol like heptanol and octanol
are soluble or insoluble in water and explain it ?
Are ethers soluble or insoluble in water?
What suffix and prefix are used for alcohol while
naming alcohol and ether?
What the process called when we add water to any
alkene to make alcohol?
Q16. Draw the diagram of following aromatic compound (practice from previous module)
Aniline
Phenol
Benzoic acid
Methyl benzoate
Q17. a. Write the oxidation reactions for the 2 propanol.
b. Write the oxidation reaction of the ethanol.
Question 11 of 18 (1 point) Question Attempt: 3 of
How many signals do you expect in the 'H NMR spectrum for this molecule?
Br
Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red.
Note for advanced students: In this question, any multiplet is counted as one signal.
Number of signals in the 'H NMR spectrum.
1
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
No additional Hs to color in top
molecule
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box…
Chapter 5 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 5 - A burning match and a bonfire may have the same...Ch. 5 - Prepare a table identifying several energy...Ch. 5 - Explain the difference between heat capacity and...Ch. 5 - Calculate the heat capacity, in joules and in...Ch. 5 - Calculate the heat capacity, in joules and in...Ch. 5 - How much heat, in joules and in calories, must be...Ch. 5 - How much heat, in joules and in calories, is...Ch. 5 - How much would the temperature of 275 g of water...Ch. 5 - If 14.5 kJ of heat were added to 485 g of liquid...Ch. 5 - A piece of unknown substance weighs 44.7 g and...
Ch. 5 - A piece of unknown solid substance weighs 437.2 g,...Ch. 5 - An aluminum kettle weighs 1.05 kg. (a) What is the...Ch. 5 - Most people find waterbeds uncomfortable unless...Ch. 5 - A 500-mL bottle of water at room temperature and a...Ch. 5 - Would the amount of heat measured for the reaction...Ch. 5 - Would the amount of heat absorbed by the...Ch. 5 - Would the amount of heat absorbed by the...Ch. 5 - How many milliliters of water at 23 C with a...Ch. 5 - How much will the temperature of a cup (180 g) of...Ch. 5 - A 45-g aluminum spoon (specific heat 0.88 J/g C)...Ch. 5 - The temperature of the cooling water as it leaves...Ch. 5 - A 70.0-g piece of metal at 80.0 °C is placed in...Ch. 5 - If a reaction produces 1.506 kJ of heat, which is...Ch. 5 - A 0.500-g sample of KCl is added to 50.0 g of...Ch. 5 - Dissolving 3.0 g of CaCl2(s) in 150.0 g of water...Ch. 5 - When 50.0 g of 0.200 M NaCl(aq) at 24.1 C is added...Ch. 5 - The addition of 3.15 g of Ba(OH)28H2O to a...Ch. 5 - The reaction of 50 mL of acid and 50 mL of base...Ch. 5 - If the 3.21 g of NH4NO3 in Example 5.6 were...Ch. 5 - When 1.0 g of fructose, C6H12O6(s), a sugar...Ch. 5 - When a 0.740-g sample of trinitrotoluene (TNT),...Ch. 5 - One method of generating electricity is by burning...Ch. 5 - The amount of fat recommended for someone with a...Ch. 5 - A teaspoon of the carbohydrate sucrose (common...Ch. 5 - What is the maximum mass of carbohydrate in a 6-oz...Ch. 5 - A pint of premium ice cream can contain 1100...Ch. 5 - A serving of a breakfast cereal contains 3 g of...Ch. 5 - Which is the least expensive source of energy in...Ch. 5 - Explain how the heat measured in Example 5.5...Ch. 5 - Using the data in the check your learning section...Ch. 5 - Calculate the enthalpy of solution ( H for the...Ch. 5 - Calculate H for the reaction described by the...Ch. 5 - Calculate the enthalpy of solution ( H for the...Ch. 5 - Although the gas used in an oxyacetylene torch...Ch. 5 - How much heat is produced by burning 4.00 moles of...Ch. 5 - How much heat is produced by combustion of 125 g...Ch. 5 - How many moles of isooctane must be burned to...Ch. 5 - What mass of carbon monoxide must be burned to...Ch. 5 - When 2.50 g of methane burns in oxygen, 125 kJ of...Ch. 5 - How much heat is produced when loo mL of 0.250 M...Ch. 5 - A sample of 0.562 g of carbon is burned in oxygen...Ch. 5 - Before the introduction of chlorofluorocarbons,...Ch. 5 - Homes may be heated by pumping hot water through...Ch. 5 - Which of the enthalpies of combustion in Table 5.2...Ch. 5 - Does the standard enthalpy of formation of H2O(g)...Ch. 5 - Joseph Priestly prepared oxygen in 1774 by heating...Ch. 5 - How many kilojoules of heat will be released when...Ch. 5 - How many kilojoules of heat will be released when...Ch. 5 - The following sequence of reactions occurs in the...Ch. 5 - Both graphite and diamond burn....Ch. 5 - From the molar heats of formation in Appendix G,...Ch. 5 - Which produces more heat?...Ch. 5 - Calculate H298 for the process...Ch. 5 - Calculate H298 for the process...Ch. 5 - Calculate H for the process Hg2Cl2(s)2Hg(l)+Cl2(g)...Ch. 5 - Calculate H298 for the process...Ch. 5 - Calculate the standard molar enthalpy of formation...Ch. 5 - Using the data in Appendix G, calculate the...Ch. 5 - Using the data in Appendix G, calculate the...Ch. 5 - The following reactions can be used to prepare...Ch. 5 - The decomposition of hydrogen peroxide, H2O2, has...Ch. 5 - Calculate the enthalpy of combustion of propane,...Ch. 5 - Calculate the enthalpy of combustion of butane,...Ch. 5 - Both propane and butane are used as gaseous fuels....Ch. 5 - The white pigment TiO2 is prepared by the reaction...Ch. 5 - Water gas, a mixture of H2 and CO, is an important...Ch. 5 - In the early days of automobiles, illumination at...Ch. 5 - From the data in Table 5.2, determine which of the...Ch. 5 - The enthalpy of combustion of hard coal averages...Ch. 5 - Ethanol, C2H5OH, is used as a fuel for motor...Ch. 5 - Among the substances that react with oxygen and...Ch. 5 - How much heat is produced when 1.25 g of chromium...Ch. 5 - Ethylene, C2H2, a byproduct from the fractional...Ch. 5 - The oxidation of the sugar glucose, C6H12O6, is...Ch. 5 - Propane, C3H8, is a hydrocarbon that is commonly...Ch. 5 - During a recent winter month in Sheboygan,...
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