Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 5, Problem 29E
If the 3.21 g of
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These are synthesis questions. You need to show how the starting material can be converted into
the product(s) shown. You may use any reactions we have learned. Show all the reagents you
need. Show each molecule synthesized along the way and be sure to pay attention to the
regiochemistry and stereochemistry preferences for each reaction. If a racemic molecule is made
along the way, you need to draw both enantiomers and label the mixture as "racemic".
All of the carbon atoms of the products must come from the starting material!
?
H
H
Q5: Draw every stereoisomer for 1-bromo-2-chloro-1,2-difluorocyclopentane. Clearly show
stereochemistry by drawing the wedge-and-dashed bonds. Describe the relationship
between each pair of the stereoisomers you have drawn.
Classify each pair of molecules according to whether or not they can participate in hydrogen bonding with one another.
Participate in hydrogen bonding
CH3COCH3 and CH3COCH2CH3
H2O and (CH3CH2)2CO
CH3COCH3 and CH₂ CHO
Answer Bank
Do not participate in hydrogen bonding
CH3CH2OH and HCHO
CH3COCH2CH3 and CH3OH
Chapter 5 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 5 - A burning match and a bonfire may have the same...Ch. 5 - Prepare a table identifying several energy...Ch. 5 - Explain the difference between heat capacity and...Ch. 5 - Calculate the heat capacity, in joules and in...Ch. 5 - Calculate the heat capacity, in joules and in...Ch. 5 - How much heat, in joules and in calories, must be...Ch. 5 - How much heat, in joules and in calories, is...Ch. 5 - How much would the temperature of 275 g of water...Ch. 5 - If 14.5 kJ of heat were added to 485 g of liquid...Ch. 5 - A piece of unknown substance weighs 44.7 g and...
Ch. 5 - A piece of unknown solid substance weighs 437.2 g,...Ch. 5 - An aluminum kettle weighs 1.05 kg. (a) What is the...Ch. 5 - Most people find waterbeds uncomfortable unless...Ch. 5 - A 500-mL bottle of water at room temperature and a...Ch. 5 - Would the amount of heat measured for the reaction...Ch. 5 - Would the amount of heat absorbed by the...Ch. 5 - Would the amount of heat absorbed by the...Ch. 5 - How many milliliters of water at 23 C with a...Ch. 5 - How much will the temperature of a cup (180 g) of...Ch. 5 - A 45-g aluminum spoon (specific heat 0.88 J/g C)...Ch. 5 - The temperature of the cooling water as it leaves...Ch. 5 - A 70.0-g piece of metal at 80.0 °C is placed in...Ch. 5 - If a reaction produces 1.506 kJ of heat, which is...Ch. 5 - A 0.500-g sample of KCl is added to 50.0 g of...Ch. 5 - Dissolving 3.0 g of CaCl2(s) in 150.0 g of water...Ch. 5 - When 50.0 g of 0.200 M NaCl(aq) at 24.1 C is added...Ch. 5 - The addition of 3.15 g of Ba(OH)28H2O to a...Ch. 5 - The reaction of 50 mL of acid and 50 mL of base...Ch. 5 - If the 3.21 g of NH4NO3 in Example 5.6 were...Ch. 5 - When 1.0 g of fructose, C6H12O6(s), a sugar...Ch. 5 - When a 0.740-g sample of trinitrotoluene (TNT),...Ch. 5 - One method of generating electricity is by burning...Ch. 5 - The amount of fat recommended for someone with a...Ch. 5 - A teaspoon of the carbohydrate sucrose (common...Ch. 5 - What is the maximum mass of carbohydrate in a 6-oz...Ch. 5 - A pint of premium ice cream can contain 1100...Ch. 5 - A serving of a breakfast cereal contains 3 g of...Ch. 5 - Which is the least expensive source of energy in...Ch. 5 - Explain how the heat measured in Example 5.5...Ch. 5 - Using the data in the check your learning section...Ch. 5 - Calculate the enthalpy of solution ( H for the...Ch. 5 - Calculate H for the reaction described by the...Ch. 5 - Calculate the enthalpy of solution ( H for the...Ch. 5 - Although the gas used in an oxyacetylene torch...Ch. 5 - How much heat is produced by burning 4.00 moles of...Ch. 5 - How much heat is produced by combustion of 125 g...Ch. 5 - How many moles of isooctane must be burned to...Ch. 5 - What mass of carbon monoxide must be burned to...Ch. 5 - When 2.50 g of methane burns in oxygen, 125 kJ of...Ch. 5 - How much heat is produced when loo mL of 0.250 M...Ch. 5 - A sample of 0.562 g of carbon is burned in oxygen...Ch. 5 - Before the introduction of chlorofluorocarbons,...Ch. 5 - Homes may be heated by pumping hot water through...Ch. 5 - Which of the enthalpies of combustion in Table 5.2...Ch. 5 - Does the standard enthalpy of formation of H2O(g)...Ch. 5 - Joseph Priestly prepared oxygen in 1774 by heating...Ch. 5 - How many kilojoules of heat will be released when...Ch. 5 - How many kilojoules of heat will be released when...Ch. 5 - The following sequence of reactions occurs in the...Ch. 5 - Both graphite and diamond burn....Ch. 5 - From the molar heats of formation in Appendix G,...Ch. 5 - Which produces more heat?...Ch. 5 - Calculate H298 for the process...Ch. 5 - Calculate H298 for the process...Ch. 5 - Calculate H for the process Hg2Cl2(s)2Hg(l)+Cl2(g)...Ch. 5 - Calculate H298 for the process...Ch. 5 - Calculate the standard molar enthalpy of formation...Ch. 5 - Using the data in Appendix G, calculate the...Ch. 5 - Using the data in Appendix G, calculate the...Ch. 5 - The following reactions can be used to prepare...Ch. 5 - The decomposition of hydrogen peroxide, H2O2, has...Ch. 5 - Calculate the enthalpy of combustion of propane,...Ch. 5 - Calculate the enthalpy of combustion of butane,...Ch. 5 - Both propane and butane are used as gaseous fuels....Ch. 5 - The white pigment TiO2 is prepared by the reaction...Ch. 5 - Water gas, a mixture of H2 and CO, is an important...Ch. 5 - In the early days of automobiles, illumination at...Ch. 5 - From the data in Table 5.2, determine which of the...Ch. 5 - The enthalpy of combustion of hard coal averages...Ch. 5 - Ethanol, C2H5OH, is used as a fuel for motor...Ch. 5 - Among the substances that react with oxygen and...Ch. 5 - How much heat is produced when 1.25 g of chromium...Ch. 5 - Ethylene, C2H2, a byproduct from the fractional...Ch. 5 - The oxidation of the sugar glucose, C6H12O6, is...Ch. 5 - Propane, C3H8, is a hydrocarbon that is commonly...Ch. 5 - During a recent winter month in Sheboygan,...
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- Nonearrow_forwardGiven the standard enthalpies of formation for the following substances, determine the reaction enthalpy for the following reaction. 4A (g) + 2B (g) → 2C (g) + 7D (g) AHrxn =?kJ Substance AH in kJ/mol A (g) - 20.42 B (g) + 32.18 C (g) - 72.51 D (g) - 17.87arrow_forwardDetermine ASran for Zn(s) + 2HCl(aq) = ZnCl2(aq) + H2(aq) given the following information: Standard Entropy Values of Various Substance Substance So (J/mol • K) 60.9 Zn(s) HCl(aq) 56.5 130.58 H2(g) Zn2+(aq) -106.5 55.10 CI (aq)arrow_forward
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- Determine the entropy change for the reaction SO2(g) + O2(g) following information: Standard Entropy Values of Various Substance Substance SO2(g) 02(g) SO3(g) So (J/mol K) 248.2 205.0 256.8 → SO3(g) given thearrow_forwardIndicate which one of the following reactions most certainly results in a negative AS sys. O1402(g) + 3NH4NO3 (s) + C10 H22(1) → 3N2(g) + 17H2O(g) + 10CO2(g) ○ CO2(aq) = CO2(g) ○ H₂O(g) = H₂O(s) CaCO3(g) = CaO(s) + CO2(g) O CuSO4.5H2O(s) = CuSO4(s) + 5H2O(g)arrow_forwardEstimate the DH°rxn of the reaction below: H H-C-C=C-H H Н A table of bond energy Bond H Bond Energy (kJ/mol) C-H 413 C-O 360 C=O 743 C-C 348 |C = C 612 O-H 463 H-H 436 + H-H -> H H-C. - H | | 1 HHHarrow_forward
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Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY