Chemistry by OpenStax (2015-05-04)
1st Edition
ISBN: 9781938168390
Author: Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher: OpenStax
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Textbook Question
Chapter 5, Problem 36E
A pint of premium ice cream can contain 1100 Calories. What mass of fat, in grams and pounds, must be produced in the body to store an extra
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NMR spectrum of ethyl acetate has signals whose chemical shifts are indicated below. Which hydrogen or set of hydrogens corresponds to the signal at
4.1 ppm? Select the single best answer.
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ethyl acetate
H NMR: 1.3 ppm, 2.0 ppm, 4.1 ppm
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How many signals do you expect in the H NMR spectrum for this molecule?
Br Br
Write the answer below.
Also, in each of the drawing areas below is a copy of the molecule, with Hs shown. In each copy, one of the H atoms is colored red. Highlight in red all other H
atoms that would contribute to the same signal as the H already highlighted red
Note for advanced students: In this question, any multiplet is counted as one signal.
1
Number of signals in the 'H NMR spectrum.
For the molecule in the top drawing area, highlight in red any other H atoms that will contribute to
the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
Check
For the molecule in the bottom drawing area, highlight in red any other H atoms that will contribute
to the same signal as the H atom already highlighted red.
If no other H atoms will contribute, check the box at right.
O
✓
No additional Hs to color in top
molecule
ง
No additional Hs to color in bottom…
in the kinetics experiment, what were the values calculated? Select all that apply.a) equilibrium constantb) pHc) order of reactiond) rate contstant
Chapter 5 Solutions
Chemistry by OpenStax (2015-05-04)
Ch. 5 - A burning match and a bonfire may have the same...Ch. 5 - Prepare a table identifying several energy...Ch. 5 - Explain the difference between heat capacity and...Ch. 5 - Calculate the heat capacity, in joules and in...Ch. 5 - Calculate the heat capacity, in joules and in...Ch. 5 - How much heat, in joules and in calories, must be...Ch. 5 - How much heat, in joules and in calories, is...Ch. 5 - How much would the temperature of 275 g of water...Ch. 5 - If 14.5 kJ of heat were added to 485 g of liquid...Ch. 5 - A piece of unknown substance weighs 44.7 g and...
Ch. 5 - A piece of unknown solid substance weighs 437.2 g,...Ch. 5 - An aluminum kettle weighs 1.05 kg. (a) What is the...Ch. 5 - Most people find waterbeds uncomfortable unless...Ch. 5 - A 500-mL bottle of water at room temperature and a...Ch. 5 - Would the amount of heat measured for the reaction...Ch. 5 - Would the amount of heat absorbed by the...Ch. 5 - Would the amount of heat absorbed by the...Ch. 5 - How many milliliters of water at 23 C with a...Ch. 5 - How much will the temperature of a cup (180 g) of...Ch. 5 - A 45-g aluminum spoon (specific heat 0.88 J/g C)...Ch. 5 - The temperature of the cooling water as it leaves...Ch. 5 - A 70.0-g piece of metal at 80.0 °C is placed in...Ch. 5 - If a reaction produces 1.506 kJ of heat, which is...Ch. 5 - A 0.500-g sample of KCl is added to 50.0 g of...Ch. 5 - Dissolving 3.0 g of CaCl2(s) in 150.0 g of water...Ch. 5 - When 50.0 g of 0.200 M NaCl(aq) at 24.1 C is added...Ch. 5 - The addition of 3.15 g of Ba(OH)28H2O to a...Ch. 5 - The reaction of 50 mL of acid and 50 mL of base...Ch. 5 - If the 3.21 g of NH4NO3 in Example 5.6 were...Ch. 5 - When 1.0 g of fructose, C6H12O6(s), a sugar...Ch. 5 - When a 0.740-g sample of trinitrotoluene (TNT),...Ch. 5 - One method of generating electricity is by burning...Ch. 5 - The amount of fat recommended for someone with a...Ch. 5 - A teaspoon of the carbohydrate sucrose (common...Ch. 5 - What is the maximum mass of carbohydrate in a 6-oz...Ch. 5 - A pint of premium ice cream can contain 1100...Ch. 5 - A serving of a breakfast cereal contains 3 g of...Ch. 5 - Which is the least expensive source of energy in...Ch. 5 - Explain how the heat measured in Example 5.5...Ch. 5 - Using the data in the check your learning section...Ch. 5 - Calculate the enthalpy of solution ( H for the...Ch. 5 - Calculate H for the reaction described by the...Ch. 5 - Calculate the enthalpy of solution ( H for the...Ch. 5 - Although the gas used in an oxyacetylene torch...Ch. 5 - How much heat is produced by burning 4.00 moles of...Ch. 5 - How much heat is produced by combustion of 125 g...Ch. 5 - How many moles of isooctane must be burned to...Ch. 5 - What mass of carbon monoxide must be burned to...Ch. 5 - When 2.50 g of methane burns in oxygen, 125 kJ of...Ch. 5 - How much heat is produced when loo mL of 0.250 M...Ch. 5 - A sample of 0.562 g of carbon is burned in oxygen...Ch. 5 - Before the introduction of chlorofluorocarbons,...Ch. 5 - Homes may be heated by pumping hot water through...Ch. 5 - Which of the enthalpies of combustion in Table 5.2...Ch. 5 - Does the standard enthalpy of formation of H2O(g)...Ch. 5 - Joseph Priestly prepared oxygen in 1774 by heating...Ch. 5 - How many kilojoules of heat will be released when...Ch. 5 - How many kilojoules of heat will be released when...Ch. 5 - The following sequence of reactions occurs in the...Ch. 5 - Both graphite and diamond burn....Ch. 5 - From the molar heats of formation in Appendix G,...Ch. 5 - Which produces more heat?...Ch. 5 - Calculate H298 for the process...Ch. 5 - Calculate H298 for the process...Ch. 5 - Calculate H for the process Hg2Cl2(s)2Hg(l)+Cl2(g)...Ch. 5 - Calculate H298 for the process...Ch. 5 - Calculate the standard molar enthalpy of formation...Ch. 5 - Using the data in Appendix G, calculate the...Ch. 5 - Using the data in Appendix G, calculate the...Ch. 5 - The following reactions can be used to prepare...Ch. 5 - The decomposition of hydrogen peroxide, H2O2, has...Ch. 5 - Calculate the enthalpy of combustion of propane,...Ch. 5 - Calculate the enthalpy of combustion of butane,...Ch. 5 - Both propane and butane are used as gaseous fuels....Ch. 5 - The white pigment TiO2 is prepared by the reaction...Ch. 5 - Water gas, a mixture of H2 and CO, is an important...Ch. 5 - In the early days of automobiles, illumination at...Ch. 5 - From the data in Table 5.2, determine which of the...Ch. 5 - The enthalpy of combustion of hard coal averages...Ch. 5 - Ethanol, C2H5OH, is used as a fuel for motor...Ch. 5 - Among the substances that react with oxygen and...Ch. 5 - How much heat is produced when 1.25 g of chromium...Ch. 5 - Ethylene, C2H2, a byproduct from the fractional...Ch. 5 - The oxidation of the sugar glucose, C6H12O6, is...Ch. 5 - Propane, C3H8, is a hydrocarbon that is commonly...Ch. 5 - During a recent winter month in Sheboygan,...
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Similar questions
- true or false, given that a 20.00 mL sample of NaOH took 24.15 mL of 0.141 M HCI to reach the endpoint in a titration, the concentration of the NaOH is 1.17 M.arrow_forwardin the bromothymol blue experiment, pKa was measured. A closely related compound has a Ka of 2.10 x 10-5. What is the pKa?a) 7.1b) 4.7c) 2.0arrow_forwardcalculate the equilibrium concentration of H2 given that K= 0.017 at a constant temperature for this reaction. The inital concentration of HBr is 0.050 M.2HBr(g) ↔ H2(g) + Br2(g)a) 4.48 x 10-2 M b) 5.17 x 10-3 Mc) 1.03 x 10-2 Md) 1.70 x 10-2 Marrow_forward
- true or falsegiven these two equilibria with their equilibrium constants:H2(g) + CI2(l) ↔ 2HCI(g) K= 0.006 CI2(l) ↔ CI2(g) K= 0.30The equilibrium contstant for the following reaction is 1.8H2(g) + CI2 ↔ 2HCI(g)arrow_forwardI2(g) + CI2(g) ↔ 2ICIK for this reaction is 81.9. Find the equilibrium concentration of I2 if the inital concentration of I2 and CI2 are 0.010 Marrow_forwardtrue or false,the equilibrium constant for this reaction is 0.50.PCI5(g) ↔ PCI3(g) + CI2(g)Based on the above, the equilibrium constant for the following reaction is 0.25.2PCI5(g) ↔. 2PCI3(g) + 2CI2(g)arrow_forward
- true or false, using the following equilibrium, if carbon dioxide is added the equilibrium will shift toward the productsC(s) + CO2(g) ↔ 2CO(g)arrow_forward2S2O2/3- (aq) + I2 (aq) ---> S4O2/6- (aq) +2I- (aq) Experiment I2 (M) S2O3- (M) Initital Rate (M/s) 1 0.01 0.01 0.0004 2 0.01 0.02 0.0004 3 0.02 0.01 0.0008 Calculate the overall order for this reaction using the table data a) 3b) 0c) 2d) 1arrow_forwardthe decomposition of N2O5 is the first order with a half-life of 1.98 minutes. If the inital concentration of N2O5 is 0.200 M, what is the concentration after 6 minutes?a) 0.612 Mb) 0.035 Mc) 0.024 Md) 0.100 Marrow_forward
- 20.00 mL of 0.150 M HCI is titrated with 0.075 M NaOH. What volume of NaOH is needed?a) 50 mLb) 20 mLc) 40 mLd) 26.66 mLarrow_forward20.00 mL of 0.150 M NaOH is titrated with 37.75 mL of HCI. What is the molarity of the HCI?a) 0.150 Mb) 0.079 Mc) 0.025 Md) 0.050 Marrow_forwardin the following reaction, the OH- acts as which of these?NO2- (aq) + H2O (l) ⇌ OH- (aq) + HNO2 (aq)a) not a weak acidb) basec) acidarrow_forward
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