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In the early days of automobiles, illumination at night was provided by burning acetylene,
Calculate the standard enthalpy of the reaction. The
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- The carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.arrow_forwardAluminum is produced commercially by the electrolysis of Al2O3 in the presence of a molten salt. If a plant has a continuous capacity of 1.00 million A, what mass of aluminum can be produced in 2.00 h?arrow_forward4.48 Elemental phosphorous is used in the semiconductor industry. It can be obtained from an ore called fluoroapatite via reaction with SiO2 and C: 4Ca5( PO4)3F+18SiO2+30C3P4+30CO+18CaSiO3+2CaF2 Suppose a particular semiconductor production plant requires 1500 kg of P4. If the recovery of P4 from this reaction is 73% efficient, what mass of fluoroapatite is needed?arrow_forward
- Three reactions very important to the semiconductor industry are The reduction of silicon dioxide to crude silicon, SiO2(s) + 2 C(s) → Si(s) + 2 CO(g) ΔrH° = 689.9 kJ/mol The formation of silicon tetrachloride from crude silicon, Si(s) + 2 Cl2(g) → SiCl4(g) ΔrH° = −657.01 kJ/mol The reduction of silicon tetrachloride to pure silicon with magnesium, SiCl4(g) + 2 Mg(s) → 2 MgCl2(s) + Si(s) ΔrH° = −625.6 kJ/mol Calculate the overall enthalpy change when 1.00 mol sand, SiO2, changes into very pure silicon by this series of reactions.arrow_forwardEthanol, C2H5OH, is a gasoline additive that can be produced by fermentation of glucose. C6H12O62C2H5OH+2CO2 (a) Calculate the mass (g) of ethanol produced by the fermentation of 1.000 lb glucose. (b) Gasohol is a mixture of 10.00 mL ethanol per 90.00 mL gasoline. Calculate the mass (in g) of glucose required to produce the ethanol in 1.00 gal gasohol. Density of ethanol = 0.785 g/mL. (c) By 2022, the U. S. Energy Independence and Security Act calls for annual production of 3.6 1010 gal of ethanol, no more than 40% of it produced by fermentation of corn. Fermentation of 1 ton (2.2 103 lb) of corn yields approximately 106 gal of ethanol. The average corn yield in the United States is about 2.1 105 lb per 1.0 105 m2. Calculate the acreage (in m2) required to raise corn solely for ethanol production in 2022 in the United States.arrow_forwardOne of the few industrial-scale processes that produce organic compounds electrochemically is used by the Monsanto Company to produce1,4-dicyanobutane. The reduction reaction is 2CH2CHCH+2H++2eNC(CH2)4CN The NC(CH2)4CN is then chemically reduced using hydrogen gas to H2N(CH2)6NH2, which is used in the production of nylon. What current must be used to produce 150.kg NC(CH2)4CN per hour?arrow_forward
- 4.60 Why are fuel additives used?arrow_forwardThere are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. In the first step, calcium carbide and water react to form acetylene and calcium hydroxide: CaC,(s)+2H,O(9)→C,H,(9)+Ca(OH);(s) In the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6C,H,(9)+3 CO,(9)+4H;O(9)→5CH,CHCO,H(9) Write the net chemical equation for the production of acrylic acid from calcium carbide, water and carbon dioxide. Be sure your equation is balanced. O-0 Torme of Le Check 02021 McGraw Hill LLC A ights Reser Explanation Addressarrow_forwardHydrogen holds great promise as a fuel in our economy because it is a gas and can be transported through pipelines, it burns without producing pollutants, and it could be used to fuel cells to generate electricity on demand. Hydrogen can be produced by the electrolysis of water to which a drop or two of sulfuric acid has been added to make the solution electrically conductive. The overall chemical reaction is 2H2O(l)→2H2(g)+O2(g) E°=-1.23V How much electrical energy, in kWh, is required to produce 1.00 kg H2(g)? H = 1 g/molarrow_forward
- Nitric acid is often manufactured from the atmospheric gases nitrogen and oxygen, plus hydrogen prepared by reforming of natural gas, in a two-step process. In the first step, nitrogen and hydrogen react to form ammonia: N2(9)+3 H,(9)→2NH;(g) In the second step, ammonia and oxygen react to form nitric acid and water: NH3(9)+2O,(9)→HNO,(9)+H,O(9) Write the net chemical equation for the production of nitric acid from nitrogen, hydrogen and oxygen. Be sure your equation is balanced.arrow_forwardWrite the chemical reaction of Iron Sulfide (FeS2) to create Sulfuric acid in mines. It reacts with O2 in the air and 02 saturated in water.arrow_forwardThe molecular weight of sperm whale myoglobin is 17.8 kDa.17.8 kDa. The myoglobin content of sperm whale muscle is about 80 g · kg−1.80 g · kg−1. In contrast, the myoglobin content of some human muscles is about 8 g · kg−1.8 g · kg−1. Compare the amounts of O2O2 bound to myoglobin in human muscle and in sperm whale muscle. Assume that the myoglobin is saturated with O2,O2, and that the molecular weights of human and sperm whale myoglobin are the same. How much O2O2 is bound to myoglobin in human muscle? How much O2O2 is bound to myoglobin in whale muscle? The amount of oxygen dissolved in tissue water at 37°C37°C is about 3.5×10−5 M.3.5×10−5 M. What is the ratio of myoglobin‑bound oxygen to dissolved oxygen in the tissue water of sperm whale muscle?arrow_forward
- Chemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningGeneral Chemistry - Standalone book (MindTap Cour...ChemistryISBN:9781305580343Author:Steven D. Gammon, Ebbing, Darrell Ebbing, Steven D., Darrell; Gammon, Darrell Ebbing; Steven D. Gammon, Darrell D.; Gammon, Ebbing; Steven D. Gammon; DarrellPublisher:Cengage LearningChemistry & Chemical ReactivityChemistryISBN:9781133949640Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage Learning
- Chemistry & Chemical ReactivityChemistryISBN:9781337399074Author:John C. Kotz, Paul M. Treichel, John Townsend, David TreichelPublisher:Cengage LearningChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
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