The reaction below will form CH H₂O H3C H H2SO4 a) 2 compounds and a meso compound. b) a meso compound. c) a racemic mixture. d) a pair of enantiomers and a meso compound. e) a pair of enantiomers. f) a pair of diastereomers.
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- :$;$;$;$$:$$:$;$4) Draw an alkene (minimum of 4 carbons) that is in the E conformation and a different alkene (also 4 carbon minimum) that is in the Z conformation. Provide an explanation as to what makes it E or Z.1.) Please draw all stereoisomers of the given molecule. Also, label each as enantiomers, diastereomers, or meso compounds.
- What type of product t is formed from this reaction? A meso compound, a racemic mixture or a single enantiomer?What product(s) is(are) formed in the following reaction Br/CH-Clz Br plus enantiomer H3C Et Br Br H and H3C Br H3C Et Et Br он ...Et plus enantiomer H3C BrPredict the major product of this series of reactions. The squiggly bond simply indicates the stereochemistry is unknown, i.e., wedge or dash. HBr compound I 1. NaH 2. compoundI 3. H2, Lindlar 4. Br2, H20 OH Br А. Br C. OH OH Br Br В. D. OH A.
- 5) For the following reactions: a. Complete the reactions with both possible chiral products. b. Determine and label the absolute configuration (R or S) of all stereocenters. c. Label the reaction type and the stereochemical relationship (meso, enantiomer, diastereomer, or none). d. Draw out the reaction mechanism showing lone pairs, arrows, bond making/breaking, etc. for each reaction. CH (R) CH, (S) OsO,, NAHSO, a) (S)oH (R H. Reaction type Cis Hydroxylation Stereochemical Enantiomers Relationship Mechanism: EXAMPLE MECHANISM (you do not need to know this mechanism for Chem 345) Rapent tove ut oppastasde OH HO. OHsee these instructions. Consider stereochemistry and enter either enantiomer (but not both) if a racemic mixture of products forms. If a mixture of two diastereomers is expected, enter either (but not both). 1. MgCl 2. H₂O:):)):;););)/(/);$:$
- 1) RCO H 2) [H₂SOJ. ? Modify the given structure to draw the major product(s). Use the single bond tool to interconvert between double and single bonds. If a racemic mixture of enantiomers is expected, draw both enantiomers. Note: you can select a structure and use Copy and Paste to save drawing time. H₂C. OH th CH, CH₂ OH H₂C OH aff CH₂ CH₂ Edit Drawinga) Draw both chair conformations of the starting alkyl bromide. Indicate which conformation, if either is more stable. Briefly justify your answer. b) The starting alkyl halide has two chiral carbons. What are the configurations (R/S) at each of these carbons? c) Identify the mechanism (E1/E2) which reactions 1, 2, and 3 proceed by. d) Provide mechanisms that explain the products formed in reactions 1, 2, and 3. All electron movement must be shown in order to receive full credit. e) Indicate which product is the major and which product is the minor in reactions 2 and 3. Briefly justify your answer.a) Draw both chair conformations of the starting alkyl bromide. Indicate which conformation, if either is more stable. Briefly justify your answer. b) The starting alkyl halide has two chiral carbons. What are the configurations (R/S) at each of these carbons? c) Identify the mechanism (E1/E2) which reactions 1, 2, and 3 proceed by. d) Provide mechanisms that explain the products formed in reactions 1, 2, and 3. All electron movement must be shown in order to receive full credit. e) Indicate which product is the major and which product is the minor in reactions 2 and 3. Briefly justify your answer.