Answered: For determing Keq – the Equilibrium…

For determing Keq – the Equilibrium Constant of a Coordination Complex, list out the glassware, tools, equipment and other materials used for this experiment. Be specific.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter21: Transition Metals And Coordination Chemistry

Section: Chapter Questions

Problem 5RQ

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For determing Keq – the Equilibrium Constant of a Coordination Complex, list out the glassware, tools, equipment and other materials used for this experiment. Be specific.

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When species combine to produce a coordination complex, the equilibrium constant for the reaction is called is the formation constant, Kf.For example, the iron(II) ion, Fe2+, can combine with the cyanide ion, CN−, to form the complex [Fe(CN)6]4− according to the equation Fe2+(aq)+6CN−(aq)⇌[Fe(CN)6]4−(aq) where Kf=4.21×1045.This reaction is what makes cyanide so toxic to human beings and other animals. The cyanide ion binds to the iron that red blood cells use to carry oxygen around the body, thus interfering with the blood's ability to deliver oxygen to the tissues. It is this toxicity that has made the use of cyanide in gold mining controversial. Most states now ban the use of cyanide in leaching gold out of low-grade ore. The average human body contains 6.30 L of blood with a Fe2+ concentration of 2.50×10−5 M . If a person ingests 9.00 mL of 12.0 mM NaCN , what percentage of iron(II) in the blood would be sequestered by the cyanide ion?
You should record any visual observations you make (colors,appearances, physical states, etc)of determining Keq – the Equilibrium Constant of a Coordination Complex experiment(determine the value of Keq for the reaction between iron(III) ions and thiocyanate ions, SCN– , or mixing specified amounts of Fe3+ and SCN–, a reaction occurs to produce the complex ion thiocyanatoiron (III), FeSCN2+, but not all the reactants react, etc)You should also record any numeric observations (masses, volumes, concentrations).