TABLE 6.2 Properties of Amphoteric Solvents Solvent Acid Cation Base Anion pkion (25° C) Boiling Point (°C) Sulfuric acid, H2SO4 H3SO4+ HSO4 3.4 (10°) 330 Hydrogen fluoride, HF H₂F+ HF2 ~12 (0°) 19.5 Water, H₂O H3O+ OH 14.0 100 Acetic acid, CH3COOH CH3COOH₂+ CH3COO 14.45 118.2 Methanol, CH3OH CH3OH₂+ CH3O 16.6 64.7 Ammonia, NH3 NH4+ NH2 27 -33.4 Acetonitrile, CH3CN CH,CNH* CH2CN 34.4 81

Introduction to General, Organic and Biochemistry
11th Edition
ISBN:9781285869759
Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Publisher:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar Torres
Chapter6: Solutions And Colloids
Section: Chapter Questions
Problem 6.38P: 6-38 Describe how we would prepare 250 mL of 0.10 M NaOH from solid NaOH and water.
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Data provides in picture attached. Calculate the concentration of CH3CNH+ in CH3CN at 25º C.

TABLE 6.2 Properties of Amphoteric Solvents
Solvent
Acid Cation
Base Anion
pkion (25° C) Boiling Point (°C)
Sulfuric acid, H2SO4
H3SO4+
HSO4
3.4 (10°)
330
Hydrogen fluoride, HF
H₂F+
HF2
~12 (0°)
19.5
Water, H₂O
H3O+
OH
14.0
100
Acetic acid, CH3COOH
CH3COOH₂+
CH3COO
14.45
118.2
Methanol, CH3OH
CH3OH₂+
CH3O
16.6
64.7
Ammonia, NH3
NH4+
NH2
27
-33.4
Acetonitrile, CH3CN
CH,CNH*
CH2CN
34.4
81
Transcribed Image Text:TABLE 6.2 Properties of Amphoteric Solvents Solvent Acid Cation Base Anion pkion (25° C) Boiling Point (°C) Sulfuric acid, H2SO4 H3SO4+ HSO4 3.4 (10°) 330 Hydrogen fluoride, HF H₂F+ HF2 ~12 (0°) 19.5 Water, H₂O H3O+ OH 14.0 100 Acetic acid, CH3COOH CH3COOH₂+ CH3COO 14.45 118.2 Methanol, CH3OH CH3OH₂+ CH3O 16.6 64.7 Ammonia, NH3 NH4+ NH2 27 -33.4 Acetonitrile, CH3CN CH,CNH* CH2CN 34.4 81
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