D Хо 000 000 LL F E B C >> A Please predict the products for each of the following reactions below (reaction 8): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate MCPBA 1. NaOH, Br₂ 2. H3O+ 3. Br2, PBг3 4. H₂O 9 8 10 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel 1. NaOH 2. H A B HO E 2. U 1. LDA, THF FO Br2 H3O+ 1. NaOH, Br₂ 2. H₂O+ 2 1. LDA, THF 2. Mel 1. LDA, THF 2. Br COOEt 1. LDA, THF 2. F
D Хо 000 000 LL F E B C >> A Please predict the products for each of the following reactions below (reaction 8): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate MCPBA 1. NaOH, Br₂ 2. H3O+ 3. Br2, PBг3 4. H₂O 9 8 10 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel 1. NaOH 2. H A B HO E 2. U 1. LDA, THF FO Br2 H3O+ 1. NaOH, Br₂ 2. H₂O+ 2 1. LDA, THF 2. Mel 1. LDA, THF 2. Br COOEt 1. LDA, THF 2. F
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 41AP: In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following...
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Transcribed Image Text:D
Хо
000 000
LL
F
E
B C
>>
A
Please predict the products for each of the following reactions below (reaction 8):
Hint: one of the reactions is the Baeyer-Villiger Reaction
Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate
MCPBA
1. NaOH, Br₂
2. H3O+
3. Br2, PBг3
4. H₂O
9
8
10
1. LDA, THF
2. Mel
3. LDA, THF
4. Mel
1. NaOH
2.
H
A
B
HO
E
2. U
1. LDA, THF
FO
Br2
H3O+
1. NaOH, Br₂
2. H₂O+
2
1. LDA, THF
2. Mel
1. LDA, THF
2.
Br
COOEt
1. LDA, THF
2.
F
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