Please predict the products for each of the following reactions below (reaction 9): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate Br A B E LL F MCPBA 1. NaOH, Br2 2. H3O+ 3. Br₂, PBг3 4. H₂O 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel 1. NaOH 2. H 10 9 Br2 H3O+ 2. H3O+ 1. NaOH, Br2 2 2 1. LDA, THF 8 7 5 3 2. Mel 4 1. LDA, THF 2. COOEt Br 1. LDA, THF 2. 1. LDA, THF 2. A B D OH Br CBr3 E Br OH Br (mixture of two compounds) F Br OH
Please predict the products for each of the following reactions below (reaction 9): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate Br A B E LL F MCPBA 1. NaOH, Br2 2. H3O+ 3. Br₂, PBг3 4. H₂O 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel 1. NaOH 2. H 10 9 Br2 H3O+ 2. H3O+ 1. NaOH, Br2 2 2 1. LDA, THF 8 7 5 3 2. Mel 4 1. LDA, THF 2. COOEt Br 1. LDA, THF 2. 1. LDA, THF 2. A B D OH Br CBr3 E Br OH Br (mixture of two compounds) F Br OH
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 41AP: In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following...
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Transcribed Image Text:Please predict the products for each of the following reactions below (reaction 9):
Hint: one of the reactions is the Baeyer-Villiger Reaction
Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate
Br
A
B
E
LL
F
MCPBA
1. NaOH, Br2
2. H3O+
3. Br₂, PBг3
4. H₂O
1. LDA, THF
2. Mel
3. LDA, THF
4. Mel
1. NaOH
2.
H
10
9
Br2
H3O+
2. H3O+
1. NaOH, Br2
2
2
1. LDA, THF
8
7
5
3
2. Mel
4
1. LDA, THF
2.
COOEt
Br
1. LDA, THF
2.
1. LDA, THF
2.
A
B
D
OH
Br
CBr3
E
Br
OH
Br
(mixture of two compounds)
F
Br
OH
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