Please correct answer and don't use hand raiting 4. For each of the following molecules, considering only σ donation from the ligand, give thesymmetry labels for the LGOs.a) Cr(CO)6 (octahedral)b) [MnCl5]³ (Square Pyramidal)c) Fe(CO)s (trigonal bipyramidal)d) [PtC14]² (Square planar)

To determine the symmetry labels for the ligand group orbitals (LGOs) of each molecule, we'll…

Answered: 4. For each of the following molecules,…

Chemistry & Chemical Reactivity

10th Edition

ISBN:9781337399074

Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel

Chapter22: The Chemistry Of The Transistion Elements

Section: Chapter Questions

Problem 40PS

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Similar questions

Four different octahedral chromium coordination compounds exist that all have the same oxidation state for chromium and have H2O and Cl as the ligands and counterions. When 1 mole of each of the four compounds is dissolved in water, how many moles of silver chloride will precipitate upon addition of excess AgNO3?
Give the number of unpaired electrons in octahedral complexes with strong-field ligands for (a) Rh3+ (b) Mn3+ (c) Ag+ (d) Pt4+ (e) Au3+
For each d electron configuration, state the number of unpaired electrons expected in octahedral complexes. Give an example complex for each case. (Two answers are possible for some of these cases.) (a) d2 (b) d4 (c) d6 (d) d8
Sketch and explain the most likely crystal field diagram for the following complex ion: Note: The CN ligand produces a much stronger crystal field than NH3. Assume the NH3 ligands lie on the z axis.
Experiments show that K4[Cr(CN)6] is paramagnetic and has two unpaired electrons. The related complex K4[Cr(SCN)6] is paramagnetic and has four unpaired electrons. Account for the magnetism of each compound using the ligand field model. Predict where the SCN ion occurs in the spectro-chemical series relative to CN.
Trimethylphosphine, P(CH3)3, can act as a ligand by donating the lone pair of electrons on the phosphorus atom. If trimethylphosphine is added to a solution of nickel(Il) chloride in acetone, a blue compound that has a molecular mass of approximately 270 g and contains 21.5% Ni, 26.0% Cl, and 52.5% P(CH3)3 can be isolated. This blue compound does not have any isomeric forms. What are the geometry and molecular formula of the blue compound?

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4. For each of the following molecules, considering only σ donation from the ligand, give the symmetry labels for the LGOs. a) Cr(CO)6 (octahedral) b) [MnCl5]³ (Square Pyramidal) c) Fe(CO)s (trigonal bipyramidal) d) [PtC14]² (Square planar)