In radical reactions, there are sometimes non-halogenated side products formed from other termination steps. Choose the possible side product of the reaction shown below? || I A Y Br2 hv == B C III IV D IV
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- didentify the Allowry reactions, as substitution, elimination, or addition DrawWelection arrows to show how the in each reactors Circle and identify any reactive bands break & form intermediates of carbon. Ħ Br Br → AH-Br →→ → XB²Please add elements to the reactions as for chemdoodle requires themb) Identify A and B and provide mechanism of the reaction. NH2 HONO heat A `CO2H H;CO,C
- The following figure shows the energy profile of a nucleophilic substitution reaction. Potential energy :ÖH H HII.C H C-1 H HO--C---I HH Reaction coordinate H -CH HO–CHITH H + 1 According to this, it is correct to affirm: O The activation energy (4G°) shows that it is thermodynamically favorable. O Represents a reaction that occurs in one step where a pentavalent chemical species is formed. O The intermediate has lower energy than any transition state. O The formation of the intermediate releases energy and is therefore thermodynamically favourable.Below is the equation for a nucleophilic substitution reaction and some experimental data. CH3CH2Br + CH3COO- ⇌ CH3CH2CO2CH3 + Br- ΔH=-75 kJ/mol Rate = k [CH3CH2Br][CH3COO-] Which reaction energy profile would be the best representative of the data provided?Plastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside the lenses that occurs when the lenses are exposed to sunlight. The original dye absorbs UV light but not visible light and is thus colorless, while the rearrangement product absorbs visible light and is thus darkened. (a) Show the mechanism of the rearrangement. (b) Why does the rearrangement product absorb at a longer wavelength (visible light) than the original dye (UV)?
- Give mechanism (name) for the reaction belowPpCH,CH,СH, CI CH,СНHCICH, + 2HCI 2CH,CH,СH, + 2C1, The chlorination of propane proceeds as a radical chain reaction. Sort the 7 reaction steps (you may need to scroll down to see them all) into categories of: Initiation Propagation Termination сн, сH,CH,. CH3CH2CH2 CH,CH, CH, -di: сHсHCH- di: а — б: — 2б Cl CH3CH2CH2 CнснсH. СH,сH,CH, -н CH3CHCH3 н— н—й: сн,бнсн, CH,CнсH, CH CHCH сH,снсH,
- When benzyl bromide is treated separately with KI and CH3OH, the substitution products are different but the reaction rates are about the same. KI Br (a) What does this suggest about the mechanism-is it SN1 or SN2? Explain. (b) Draw the complete mechanism (including curved arrows) for the formation of each product. (c) If the concentration of KI were doubled, what would happen to the rate of the substitution reaction? HOCH3 ?The process shown is classified as a halogen step. CI CH3 -애' + CHsCIProvide the mechanism and products of the reactions