Please predict the products for each of the following reactions below (reaction 4): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate EtOOC A B D E LL MCPBA 1. NaOH, Br2 2. H3O+ 3. Br2, PBr3 4. H₂O 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel 1. NaOH 2. H 9 10 10 Br2 H3O+ 1 1. NaOH, Br2 2. H₂O+ 1. LDA, THF 3 2. Mel 8 4 7 5. 1. LDA, THF 2. Br COOEt 1. LDA, THF 2. 1. LDA. THF 2. B D E COOEt EtOOC COOEt EtOOC F COOEt

Organic Chemistry
9th Edition
ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions
Section30.SE: Something Extra
Problem 41AP: In light of your answer to Problem 30-40, explain why a mixture of products occurs in the following...
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Please predict the products for each of the following reactions below (reaction 4):
Hint: one of the reactions is the Baeyer-Villiger Reaction
Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate
EtOOC
A
B
D
E
LL
MCPBA
1. NaOH, Br2
2. H3O+
3. Br2, PBr3
4. H₂O
1. LDA, THF
2. Mel
3. LDA, THF
4. Mel
1. NaOH
2.
H
9
10
10
Br2
H3O+
1
1. NaOH, Br2
2. H₂O+
1. LDA, THF
3
2. Mel
8
4
7
5.
1. LDA, THF
2.
Br
COOEt
1. LDA, THF
2.
1. LDA. THF
2.
B
D
E
COOEt
EtOOC
COOEt
EtOOC
F
COOEt
Transcribed Image Text:Please predict the products for each of the following reactions below (reaction 4): Hint: one of the reactions is the Baeyer-Villiger Reaction Hint: in case of 3, 4, 5, 6, 7 and 8 please consider ONLY the kinetic enolate EtOOC A B D E LL MCPBA 1. NaOH, Br2 2. H3O+ 3. Br2, PBr3 4. H₂O 1. LDA, THF 2. Mel 3. LDA, THF 4. Mel 1. NaOH 2. H 9 10 10 Br2 H3O+ 1 1. NaOH, Br2 2. H₂O+ 1. LDA, THF 3 2. Mel 8 4 7 5. 1. LDA, THF 2. Br COOEt 1. LDA, THF 2. 1. LDA. THF 2. B D E COOEt EtOOC COOEt EtOOC F COOEt
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