Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Part c
![Follow the detailed instructions provided in each of the subsections (a-c):
a) Fill in the following reaction scheme by drawing the structure of intermediate 3 and
products 4-5. Chemical formulas have been added as guidance.
H,C
CI
H,N
CH3
H, SO,
2
CH3
C,H,,NO,
C,H,NO,
CH,OH
1
- HCI
H20
3
Step 1
Step 2
H2N
CH,
OH
C,H,,N,O,
Assign the absolute stereochemistry of the stereogenic centre in compound 1.
b) If the methyl ester in compound 1 was replaced by a carboxylic acid, compound 1 could
react with itself. Can you predict which product will be formed?
H,N
HO.
CH2
C,H;NO,
Step 1
7
c) Using curly arrows, draw the mechanism of Step 2.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fa72596f5-82dc-4814-95fe-774498eae908%2F390f0bba-ace5-4848-880d-81206953db3c%2Fhda0yzs_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Follow the detailed instructions provided in each of the subsections (a-c):
a) Fill in the following reaction scheme by drawing the structure of intermediate 3 and
products 4-5. Chemical formulas have been added as guidance.
H,C
CI
H,N
CH3
H, SO,
2
CH3
C,H,,NO,
C,H,NO,
CH,OH
1
- HCI
H20
3
Step 1
Step 2
H2N
CH,
OH
C,H,,N,O,
Assign the absolute stereochemistry of the stereogenic centre in compound 1.
b) If the methyl ester in compound 1 was replaced by a carboxylic acid, compound 1 could
react with itself. Can you predict which product will be formed?
H,N
HO.
CH2
C,H;NO,
Step 1
7
c) Using curly arrows, draw the mechanism of Step 2.
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