1. Ampicillin is an antibiotic used to prevent and treat several bacterial infections.Bacampicillin is a derivative of ampicillin (a prodrug) that enhances the oralbioavailability of the parent antibiotics. In the body, Bacampicillin decomposes torelease Ampicillin and side products. Provide a mechanism for the followingreaction. For simplicity, replace the core structure with R.NH2BacampicillinNNH2SH3O+AmpicillinOHΗCO2Η

Step 1: Step 2: Step 3: Step 4:

Answered: 1. Ampicillin is an antibiotic used to…

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter18: Functional Derivatives Of Carboxylic Acids

Section: Chapter Questions

Problem 18.69P

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H₂N Provide the missing structures. NH2 CH3 1) DCC N. 2) LIAIH 3) H₂O Boc₂O (1 equiv) The aliphatic amine is a stronger base/nucleophile. Why
Self Study/Amines-Reactions Name: 1) Show how m-toluidine (shown on the right) can be converterd to the following compounds using any neccesary reagents. (You can use a previously synthesized compound to carry on). H3C. NH2 a) H3C CN m-toluonitrile H3C. b) CH,NH2 H3C. m-iodotoluene OH d) HC. m-cresol
I) Sketch a stepwise mechanism for the reaction of secondary amine with an acid chloride to generate an amide and H-CI II) Name the general class of organic compound that each of these molecules belong to i) R NR2 ii) R ii1) iv) R-CEN
Explain why a much better yield of primary amine is obtained from the reaction of an alkyl halide with azide ion (-N3), followed by catalytic hydrogenation. (Hint: An alkyl azide is not nucleophilic.)
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The following three derivatives of succinimide are anticonvulsants and have found use in the treatment of epilepsy, particularly petit mal seizures. Ph Ph `N' `N' ČH3 ČH3 Methsuximide Ethosuximide Phensuximide Following is a synthesis of phensuximide. CN Ph CN Ph CN 1. NaOH, H2O 2. HC, Н20 NaOEt KCN Ph-CHO cOOEt H cOOEt NC COOEt 3. Нeat Ethyl cyanoacetate (A) (B) Benzaldehyde Ph Ph Ph CH;NH2 НООС СООН Et0oC COOEt `N' (C) (D) ČH3 Phensuximide Methsuximide is formed by a similar pathway to that shown for phensuximide. Draw the structure of the compound that reacts with ethyl cyanoacetate in the synthesis of methsuximide.
27) Hydrolysis of an ester: O II CH,-C-O-CH2-CH2-CH, + H20 28) Acid/ Base reaction of an amine CH3-CH2-NH2 H2CO3 29) Hydrolysis of an amide 11 CH3-CH2-CH2-CH2-CH2-C-NH-CH2-CH2-CH, + H20 OMIC Molecules
a) Provide the complete mechanism for the following reaction. MeO CH;CH2NH2 CH;OH b) Design a synthesis for this primary amine starting from benzene. CH2CH2NH2 но
When aspirin is made from acetic acid, the by product is H2O; when acetic anhydride 1Sused, the by-product is acetic acid. When acetyl chloride is used (see above), the by product is HC1. Which route should you use if you were working for Leica, a company that mass produces aspirin on a daily basis? Why?
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Can you please give an explanation for question 2( A to J)? Thank you

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