Which of the following reactions are oxidation- reduction reactions?
a.
b.
c.
d.
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General Chemistry: Principles and Modern Applications (11th Edition)
- Triiodide ions are generated in solution by the following (unbalanced) reaction in acidic solution: IO3(aq) + I(aq) I3(aq) Triiodide ion concentration is determined by titration with a sodium thiosulfate (Na2S2O3) solution. The products are iodide ion and tetrathionate ion (S4O6). a. Balance the equation for the reaction of IO3 with I ions. b. A sample of 0.6013 g of potassium iodate was dissolved in water. Hydrochloric acid and solid potassium iodide were then added. What is the minimum mass of solid KI and the minimum volume of 3.00 M HQ required to convert all of the IO3 ions to I ions? c. Write and balance the equation for the reaction of S2O32 with I3 in acidic solution. d. A 25.00-mL sample of a 0.0100 M solution of KIO. is reacted with an excess of KI. It requires 32.04 mL of Na2S2O3 solution to titrate the I3 ions present. What is the molarity of the Na2S2O3 solution? e. How would you prepare 500.0 mL of the KIO3 solution in part d using solid KIO3?arrow_forward4.112 A metallurgical firm wishes to dispose of 1300 gallons of waste sulfuric acid whose molarity is 1.37 M. Before disposal, it will be reacted with calcium hydroxide (slaked lime), which costs $0.23 per pound. (a) Write the balanced chemical equation for this process. (b) Determine the cost that the firm will incur from this use of slaked lime.arrow_forwardElemental bromine is the source of bromine compounds. The element is produced from certain brine solutions that occur naturally. These brines are essentially solutions of calcium bromide that, when treated with chlorine gas, yield bromine in a displacement reaction. What are the molecular equation and net ionic equation for the reaction? A solution containing 40.0 g of calcium bromide requires 14.2 g of chlorine to react completely with it, and 22.2 g of calcium chloride is produced in addition to whatever bromine is obtained. How many grams of calcium bromide are required to produce 10.0 pounds of bromine?arrow_forward
- Sodium thiosulfate, Na2S2O3, is used as a fixer in black-and-white photography. Suppose you have a bottle of sodium thiosulfate and want to determine its purity. The thiosulfate ion can be oxidized with I2 according to the balanced, net ionic equation I2(aq) + 2 S2O32(aq) 2 I(aq) + S4O62 (aq) If you use 40.21 mL of 0.246 M I2 in a titration, what is the weight percent of Na2S2O3 in a 3.232-g sample of impure material?arrow_forward1. Sometimes a reaction can fall in more than one category. Into what category (or categories) does the reaction of Ba(OH)2(aq) + H+PO4(aq) fit? acid-base and oxidation-reduction oxidation-reduction acid-base and precipitation precipitationarrow_forwardBromine is obtained from sea water by the following redox reaction: Cl2(g) + 2 NaBr(aq) 2 NaCl(aq) + Br2() (a) What has been oxidized? What has been reduced? (b) Identify the oxidizing and reducing agents.arrow_forward
- Chlorine gas was first prepared in 1774 by C. W. Scheele by oxidizing sodium chloride with manganese(IV) oxide. The reaction is NaCl(aq) + H2SO4(aq) + MnO2(s) Na2SO4(aq) + MnCl2(aq) + H2O(l) + Cl2 (g) Balance this equation.arrow_forwardOxidation of 1.00 g of carbon monoxide, CO, produces 1.57 g of carbon dioxide, CO2. How many grams of oxygen were required in this reaction?arrow_forwardYou wish to determine the weight percent of copper in a copper-containing alloy. After dissolving a 0.251 -g sample of the alloy in acid, an excess of KI is added, and the Cu2+ and I ions undergo the reaction 2 Cu2+(aq) + 5 I(aq) 2 CuI(s) + I3(aq) The liberated I3 is titrated with sodium thiosulfate according to the equation I3 (aq) + 2 S2O32(aq) S4O62(aq) + 3 I (aq) (a) Designate the oxidizing and reducing agents in the two reactions above. (b) If 26.32 mL of 0.101 M Na2S2O3 is required for titration to the equivalence point, what is the weight percent of Cu in the alloy?arrow_forward
- Write the net ionic equation for the reaction, if any, that occurs on mixing (a) solutions of sodium hydroxide and magnesium chloride. (b) solutions of sodium nitrate and magnesium bromide. (c) magnesium metal and a solution of hydrochloric acid to produce magnesium chloride and hydrogen. Magnesium metal reacting with HCl.arrow_forwardThe carbon dioxide exhaled in the breath of astronauts is often removed from the spacecraft by reaction with lithium hydroxide 2LiOH(s)+CO2(g)Li2CO3(s)+H2O(l) Estimate the grams of lithium hydroxide required per astronaut per day. Assume that each astronaut requires 2.50 103 kcal of energy per day. Further assume that this energy can be equated to the heat of combustion of a quantity of glucose, C6H12O6, to CO2(g) and H2O(l). From the amount of glucose required to give 2.50 103 kcal of heat, calculate the amount of CO2 produced and hence the amount of LiOH required. The H for glucose(s) is 1273 kJ/mol.arrow_forwardMagnesium metal (a component of alloys used in aircraft and a reducing agent used in the production of uranium, titanium, and other active metals) is isolated from sea water by the following sequence of reactions: Mg2+(aq)+Ca(OH)2(aq)Mg(OH)2(s)+Ca2+(aq)Mg(OH)2(s)+2HCl(aq)MgCl2(s)+2H2O(l)MgCl2(l)electrolysisMg(s)+Cl2+Cl2(g) Sea water has a density of 1.026 g/cm3 and contains 1272 parts per million of magnesium a5 Mg2+(aq) by mass. What mass, in kilograms, of Ca(OH)2; is required to precipitate 99.9% of the magnesium in 1.00103 L of sea water?arrow_forward
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