Give the expected major product of reaction of 2,2-dimethylcyclopropane with each of the following reagents.2. Reaction with dilute H₂SO, in methanol.Select Draw Templates MoreCHCEraseQQQc. Reaction with dilute aqueous HBr.Select Drew Templates MoreEracQQQb. Reaction with NaOCH, in methanol.Select Draw Templates Mored. Reaction with concentrated HBr.Select Draw Templates MoreEnaQQQe. Reaction with CH, Mg1, then H*, H₂O1. Reaction with CH,Li, then H', H₂O

Answered: Give the expected major product of…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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6. Provide reagents and intermediates in the indicated boxes to complete the reaction scheme. + H NaBH3CN, HCI (two steps, no acidic hydrolysis, from one product) 016H (w/o heat) 1. MeLi (xs) 2. HCI, H₂O NH₂ 1. Saponification 2. A 0 1. MeMgBr (xs) 2. HCI, H₂O 018 Me NH₂ 1. Dibal H, 2. H3O+ POCk3, pyr or + 1. LIAIH(O'Bu)3 (XS) 2. acidic workup
C. Draw the structure for the product formed in each of step of the following synthetic sequences. 1. C NH₂ SOCI₂ or P₂O5 or POCI3 (dehydration) 1.CH3MgBr 2.H3O+ 1. NaOH, 12 2. H3O+ + yellow precipitate
2. Selectivity. Show the product(s) obtained or the appropriate reagent(s) to be used for the following transformations. a. H Hill 1. CH2N2, Et2O 2. Ac₂O, pyridine A HO₂C ŎCH3 OH 3. cat. OsO4 NalO4 (excess) H2O, MeOH 4. CH2N2, Et2O 1. SAE, (-)-DIPT b. Me 앤 OH 2. MeOH, CSA 50 °C 3a. O3, MeOH CH2Cl2, -70 °C 3b. Me2S B 56%
Be sure to answer all parts. Synthesize the following compound from cyclohexanol, ethanol, and any other needed reagents. он Part 1 out of 2 Preparation of organometallic reagent: B CH3CH2OH CH3CH2MGB. draw structure... Draw the intermediate product above and select the correct reagent for A. NaBr O MgBr2 Br2 HBr Select the correct reagent for B. O Mgo O Mgl, O Mg O MgBr2 Next part
2. Predict the major organic product(s) for each of the following reactions. Be sure to clearly indicate the proper stereochemical relationships between groups (if appropriate), and write the word "racemic" next to any compound that is formed as a racemic mixture. a. b. C. d. Ph NaOH H₂O CH3 CH3 + недон H2SO4 OH CH2N2 Et₂O OH CH3 DCC + H3C OH Ph NH2
Draw the structure of the major organic product of the following reaction.
Draw the products of the two step reaction sequence shown below. Use wedge and dash bonds to indicate stereochemistry where appropriate. Ignore inorganic byproducts.
4. Reactivity. Propose a mechanism for each of the following transformations to explain the observed regioselectivity and stereochemistry. a. -COCI SiMe3 AICI3 Mé `Me 76% b. Me (Ph;P)4Pd (cat.) CO-Me EtzN, CH3CN, reflux Me MeO2C 80% с. Me Me SiMe3 n-BugNF DMF, HMPA 69% d. EtAICI (2 eq) toluene -SiMe3 85%
4
Give detailed Solution with explanation needed
3 Complete the following table, filling in the missing major product(s), reagents/conditions, starting material and/or name of the reaction as shown in the example. Starting Materials Ex. b. C. d. dj f. 09 ỌCH3 CH3 CH3 NO₂ Reagents H₂O H* (cat.) C1₂ AICI3 HNO3 H₂SO4 SO3 H₂SO4 Br₂ FeBr3 AICI3 Major Product(s) O= OH
Give the major organic product or missing starting material for the following reactions. Do whichever letter but please explain the process

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