4. Reactivity. Propose a mechanism for each of the following transformations to explain the observed regioselectivity and stereochemistry. a. -COCI SiMe3 AICla CH2Cl2 Me Me 76%

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4. Reactivity. Propose a mechanism for each of the following transformations to
explain the observed regioselectivity and stereochemistry.
a.
-COCI
SiMe3
AICI3
Mé
`Me
76%
b.
Me
(Ph;P)4Pd (cat.)
CO-Me
EtzN, CH3CN, reflux
Me
MeO2C
80%
с.
Me
Me
SiMe3
n-BugNF
DMF, HMPA
69%
d.
EtAICI (2 eq)
toluene
-SiMe3
85%
Transcribed Image Text:4. Reactivity. Propose a mechanism for each of the following transformations to explain the observed regioselectivity and stereochemistry. a. -COCI SiMe3 AICI3 Mé `Me 76% b. Me (Ph;P)4Pd (cat.) CO-Me EtzN, CH3CN, reflux Me MeO2C 80% с. Me Me SiMe3 n-BugNF DMF, HMPA 69% d. EtAICI (2 eq) toluene -SiMe3 85%
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