2. Selectivity. Show the product(s) obtained or the appropriate reagent(s) to be used for the following transformations. a. H Hill 1. CH2N2, Et2O 2. Ac₂O, pyridine A HO₂C ŎCH3 OH 3. cat. OsO4 NalO4 (excess) H2O, MeOH 4. CH2N2, Et2O 1. SAE, (-)-DIPT b. Me 앤 OH 2. MeOH, CSA 50 °C 3a. O3, MeOH CH2Cl2, -70 °C 3b. Me2S B 56%

2. Selectivity. Show the product(s) obtained or the appropriate reagent(s) to be used for the following transformations. a. H Hill 1. CH2N2, Et2O 2. Ac₂O, pyridine A HO₂C ŎCH3 OH 3. cat. OsO4 NalO4 (excess) H2O, MeOH 4. CH2N2, Et2O 1. SAE, (-)-DIPT b. Me 앤 OH 2. MeOH, CSA 50 °C 3a. O3, MeOH CH2Cl2, -70 °C 3b. Me2S B 56%

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

5. Given the reactions below, provide the missing products and explain the differences among the Haloform reactions. 1. Cl, NaOH, H,O, cold temp 2. НC HO Br Br 1. Cl2, NaOH, H20, cold temp 2. H3O* 1. Cl2, NaOH, H,O, cold temp 2. H2SO4
How can you change the reaction at the top the provide the reaction at the bottom
Part 1: What are the outcomes of the following reactions? OH ob you bot you CH₂CH₂OH H₂SO4 (cat.) CH3NH2 (excess) NaOH H₂O NH3 (excess) H₂O H₂SO4 (cat.) CH3CH₂OH КОН, Д
Give IUPAC names to the following molecules. CI a. b. b. b. C. d. Br CI- Draw all the products (alkyl halides) of the following reactions and classify them as primary, secondary, or tertiary a. OH X . Br Br Complete the following reactions by filling in the missing reagents. a. OH NBS hv OH hv, CC14 Br NBS ť Licu C. -MgBr CI → CI Br Br
7. Reaction Scheme. NH₂ NH2 or two differnet methods (no same steps/reagents) C5H12N2 1. xs Mel, xs K2CO3 2. Ag2O, H₂O 3. heat Br2, xs NaOH, xs H₂O OHC 1.03 2. DMS CHO
Provide the major organic product for the 1. LilH 4 2.нсін, о Provide the major organic product of the following reaction. following reaction. ?. 6. Provide the major organic product for the following reaction. HO Br OH NH - Br 1. LIAIH4 2. HC1, H₂O 7. Provide the major organic product of the following reaction. concentrated KMnO4 reflux
Gg.40.
Specify both the alcohol starting material and the reagents you would use in each step in a synthesis of the compound shown. If the synthesis requires only two steps enter "none" for step 3. Br Alcohol Starting Materials 1. methanol 2. ethanol 3. 1-propanol 4. 2-propanol 5. cyclohexanol Reagents available a. LIAIH4 f. PBrs k. CH3 CH2 CH, MgBr; then H30+ b. H2 SO4 g. CrO3, H2 SO4, H2O 1. C3 H5 MgBr (phenylmagnesium bromide); then H3O* с. НСI h. NaH m. (CH3)2 CHMgBr: then H30+ d. HBr i. CH;MgBr; then H30+ n. Dess-Martin periodinane (DMP) e. SOCI, j. CH3 CH2 MgBr; then H3O+ Write the number/letters of the alchol/reagents in the boxes below. Alcohol starting material Previous Next
4. Provide the products for the reactions. Take note of the changes and how they tie together for the overall result. Br NaNH2 H20 З еq Br Br NaNH2 2 eq Br Bгz 1. NANH2, 3 eq 2. H20 Он conc. H2SO4 Br2 1. NaNH2, 3 eq heat 2. Нао
Specify both the alcohol starting material and the reagents you would use in each step in a synthesis of the compound shown. If the synthesis requires only two steps enter "none" for step 3. OH Alcohol Starting Materials 1. methanol 2. ethanol 3. 1-propanol 4. 2-propanol 5. cyclohexanol Reagents available a. LIAIH4 f. PB13 k. CH3 CH2 CH2 MgBr; then H3O+ b. H2 SO4 g. Cr03, H,SO4, H2O 1. C6 H5 MgBr (phenylmagnesium bromide); then H30* c. HCI h. NaH m. (CH3)2 CHMgBr: then H30+ d. HBr i. CH3MgBr; then H30+ n. Dess-Martin periodinane (DMP) e. SOCI, j. CH3 CH2 MgBr; then H30+
Give me detailed Solution with explanation needed...don't give Handwritten answer
8. Provide the products for the reactions shown. HgSO4 HgSO4 H2SO4, H20 H2SO4, H20 2 products HgSO4 H2SO4, H2O 2 products? 1. R2BH 1. R2BH 2. HаОг. NaOH 2. H2O2, NaOH 2 products 1. R2BH 2. Н2О2, NaOH 2 products?