3. Assign absolute configuration (Rors) to each chirality center. a. H Nitz C. он b. 0 H-C. C H 7 C. ་-4 917-417 refs H 1つ ८ ડુ d. Но f. -2- 01 Ho -OH 2HN
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- Mark all chiral carbons with a star in the following molecules._10. Which of the following chiral compounds has a S configuration? CH3 CH3 COOH соон Br HO А. В. НО CH2CH3 NH2 CI С. CH3 D.7. Which of the following drawings represents the enantiomer of compound X? CH, H,C-C-CH, ОН CH, CH, OH OH OH CH, H,C-C-CH, H,C-C-CH, H,C HO, ÓH OH A. В. С. 8. Which of the compounds below is (are) chiral? Br А. А В. В С. С Br Br Br D. D E. A and B F. B and D Br Br Br А. В. D.
- 4. For each of the following molecules, label each stereocenter as R or S. Label the molecules appropriately as chiral or meso. a. b. methionine NH₂ H d. но. OH c. D = 2H, T = ³H, isotopes of hydrogen. f.T. OH OH CI Y ОНIX. Assign R, S configurations to each indicated chirality center in the molecules below. HO. HO 16. OH Ye H HO₂C H 14. HO CO₂H OH The configuration of carbon 14 is The configuration of carbon 16 is The configuration of carbon 18 is H CH,NH, H 15. H₂N CH3CH₂ 17. COOH ----CH3 H CH3 The configuration of carbon 15 is The configuration of carbon 17 is 18.Q4: a: Assign the absolute configuration of all chiral centers in molecules B and C by writing R or S directly adjacent to the chiral carbon. COOH COOH COOH ÇOOH ÇOOH H- HO- но H- H. HO- но H. но HO. H- OH но -H- но H. HO- H. COOH COOH COOH COOH COOH A C b: List any pairs of enantiomers: c: List any pairs of identical molecules: d: List any pairs of diastereomers: e: List all meso compounds: f: List all dextrorotatory compounds:
- Specify the configurations (R or S) of chiral centers a and b in the chem3D structure below. H3C. CH3 b a ČH3 ball & stick v labels Carbon a: Carbon b:Assign the absolute configuration of all chiral centres in the compound in the image?Part A. For each pair of isomers A and B, choose the one molecule that is chiral.
- Chrome File Edit View History Bookmarks Profiles Tab Window Help OO stereoisomershw.chem420.f16 X + ← → C G Search Google or type a URL stereoisomershw.chem420.f16.s20.s23 TE 26 1 • Quedla od 22,293 . MAR 8 H 010 C 2. Assign the R or S configuration to each chiral center in the molecules below. CH₂OH H₂C 1 / 1 W H =CH₂ CH3 CH(CH3)2 125% 12 + H3C CH3 Br A .CH,NH, H₂ W m P H 34% ¹ CH₂CH₂CH3 CH3 O Wed 5:01 PM CHBrCH₂CI H₂N CH₂Cl 3 4 (numbers indicate the IUPAC numbering) =S + Q III ⠀ :.. O 2. Give the molecula formula for the following compounds and star the chiral center(s) in each one of them if there is any. HO NO2 HS N' HOOJ HN Но H. CH3 followingnotegu F. HOO) HO, CH3 HOO). N. ఆరింది 3. Define chiral and an achiral molecules. 4. Define structural (or constitutional isomers). Draw as many constitutional isomers as possible with a molecular formula of C6H14 5. Define stereoisomers and give an example of two stereoisomers (draw them in line-angle notation). 6. Define diastereomers and give an example of two diastereomers (draw them in line-angle notation). 7. Define enantiomers and give an example of two enantiomers (draw them in line-angle notation).5. Assign R and S to each chiral center. Br H. CI NH2 H, OH H... OCH3 CH3 H. NC A A [ [ Choose ] [ Choose ] [ Choose ] C [ [ Choose ] D

