Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 5, Problem 33P
Interpretation Introduction

Interpretation:

From the given options, molecules that are chiral and capable of existing as enantiomers are to be identified.

Concept introduction:

Enantiomers are a type of stereoisomers that are non-superposable mirror images of each other.

A chiral molecule is one that has non-superposa-ble mirror image and an achiral molecule is one that has superposable mirror image.

A chiral molecule and its mirror image are enantiomers.

Enantiomers exist only for chiral molecules.

For any molecule to have enantiomers, there must be one chiral center present.

A common chiral center present in molecules is a carbon atom attached to four different groups.

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Draw a bond-line diagram for the compounds below. Which of the following compounds is chiral?  (a) 2-bromobutane (b) methylcyclohexane (draw a chair configuration)
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