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Practice Problem 5.11
List the substituents in each of the following sets in order of priority, from highest to lowest:
(a)
(b)
(c)
(d)
(e)
(f)
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Chapter 5 Solutions
Organic Chemistry
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Introductory Chemistry (5th Edition) (Standalone Book)
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Chemistry & Chemical Reactivity
- Font Paragraph Predict the main organic product of the following reactions: (a) CH2-CHCHCH3 H*, H2O, heat CH3 (b) CH-СНСНСH3 Br2 CH3 (c) CH-CHCHСH3 (1) BH3 CH3 (2) H2О2, ОН-arrow_forwardPart A Calculate AHrxn for the following reaction: CH4 (g) + 4C12 (g) → CC14 (g) + 4HCI(g) given these reactions and their AH values: C(s) + 2H2(g) C(s) + 2C12(g) H2 (g) + CH4(g), → CCL4(g), Cl2 (g) → 2HCI(g), AH = -74.6 kJ AH = -95.7 kJ AH = -184.6 kJ Express the enthalpy in kilojoules to one decimal place. Vα ΑΣφ ΔΗ- kJ %D Submit Request Answerarrow_forwardWhich Newman projection corresponds to point A on the graph of potential energy vs. rotation about the C2-C3 bond?arrow_forward
- Convert the following bond-line structure to a Newman projection (look from C5 to C4). Then draw the highest and lowest energy conformer for the molecule: H Harrow_forward7. Assign E or Z configuration to the following molecules: (A) (B) (C) (D) (E) I = Z; II = E I=E: II = Z I= E; II = E I=Z; II = Z I= E; II is neither E nor Z OH I II C1arrow_forwardRank the following groups in order of decreasing priority. −H, −CH3, −Cl, −CH2Clarrow_forward
- 3. Rank the substituents in each of the following sets: (а) -Н, -ОН, -СH2CH3, -СH2CH2ОН (b) -СО2Н, -СО2CH3, -СH2ОН, -он (c) –CN, –CH2NH2, -CH2NHCH3, –NH2 (d) –SH, -CH2SCH3, –CH3, -SSCH3arrow_forwardThe degree of unsaturation, or index of hydrogen deficiency, is the number of pi bonds plus rings in a molecule. Specify the degree of unsaturation (index of hydrogen deficiency) of the following formulas: (a) C9H12 (b) C,H40| (c) C,H,N2arrow_forward(a) (b) 1. CH3MgBr 2. H3O+ H3C OH I H3C-C-C-CH3 H3C H ОН H CH3 CH3 H3C CH3 H3C H₂SO4 C=Carrow_forward
- (i) how many bonds does the molecule have? (ii) how many unhybridized p-orbitals total does the carbon labeled (b) have? (iii) how many unhybridized p-orbitals total does the carbon labeled (a) have? H-CEC-N (a) c=c=Ö: (b) H Harrow_forward4. Which Newman projection corresponds to point A on the graph of potential energy vs. rotation about the C₂-C3 bond? Potential Energy- (A) (C) 0 H CH3 Q. 'Н H H H₂ H 60 CH₁ H -CH3 H A CH3 120 180 Degrees of Rotation (B) (D) n 300 240 HH H H 360 CH3 CH3 CH3 HDCH3 H&H Harrow_forwardThe degree of unsaturation, or index of hydrogen deficiency, is the number of pi bonds plus rings in a molecule. Specify the degree of unsaturation (index of hydrogen deficiency) of the following formulas: (a) C24H30 (b) C15H22 (c) C,H¡Cl,Narrow_forward
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning