Organic Chemistry
Organic Chemistry
12th Edition
ISBN: 9781118875766
Author: T. W. Graham Solomons, Craig B. Fryhle, Scott A. Snyder
Publisher: WILEY
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Chapter 5, Problem 21PP

Practice Problem 5.21

The following are formulas for three compounds, written in noneclipsed conformations. In each instance tell which compound (A, 8, or C on the previous page) each formula represents.

(a)

Chapter 5, Problem 21PP, Practice Problem 5.21 The following are formulas for three compounds, written in noneclipsed , example  1

(b)

Chapter 5, Problem 21PP, Practice Problem 5.21 The following are formulas for three compounds, written in noneclipsed , example  2

(c)

Chapter 5, Problem 21PP, Practice Problem 5.21 The following are formulas for three compounds, written in noneclipsed , example  3

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2.35 Consider 1-bromo-2-methylpropane and draw the following.(a) The staggered conformation(s) of lowest energy(b) The staggered conformation(s) of highest energy
2.34 Consider 1-bromopropane, CH3CH2CH2Br.(a) Draw a Newman projection for the conformation in which !CH3 and !Br are anti (dihedral angle 1808).(b) Draw Newman projections for the conformations in which !CH3 and !Br are gauche (dihedral angles 608 and 3008).(c) Which of these is the lowest energy conformation?(d) Which of these conformations, if any, are related by reflection?
(a) which if the structure of trans-1,2-dimethylcyclopentane? (b) which is the most stable conformation of 1-bromo-2-ethylcyclohexane? (c) which is the least stable conformation of 1-bromo-2-ethylcyclohexane? (d) which is the more stable configuration of 1,3-dimethylcyclopentane?   *Et = ethyl

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