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- Instead of using NaCl to melt the ice on your sidewalk you decide to use CaCl2. If you add 35.0 g of CaCl2 to 150. g of water, what is the freezing point of the solution? (Assume i = 2.7 for CaCl2.)arrow_forwardSamples of each of the substances listed below are dissolved in 125 g of water. Which of the solutions has the highest boiling point? (a) 3.0 g sucrose, C12H22O11 (b) 1.0 g glycerol, C3H3(OH)3 (c) 1.0 g propylene glycol, C3H6(OH)2 (d) 2.0 g glucose, C6H12(OH)2arrow_forwardThe solubility of lead nitrate at 100C is 140.0 g/100 g water. A solution at 100C consists of 57.0 g of lead nitrate in 64.0 g of water. When the solution is cooled 10C to 25.0 g of lead nitrate crystallize out. What is the solubility of lead nitrate in g/100 g water at 10C?arrow_forward
- a. Use the following data to calculate the enthalpy of hydration for calcium chloride and calcium iodide. Lattice Energy Hsoln CaCl2(s) 2247kj/mol 46kj/mol Cal2(s) 2059kj/mol 104kj/mol b. Based on your answers to part a, which ion, Cl or I, is more strongly attracted to water?arrow_forward6-21 Are mixtures of gases true solutions or heterogeneous mixtures? Explain.arrow_forwardIf you prepared a saturated aqueous solution of potassiumchloride at 25°C and then heated it to 50°C, wouldyou describe the solution as unsaturated, saturated, orsupersaturated? Explain.arrow_forward
- How much N2 can dissolve in water at 25 C if the N2 partial pressure is 585 mm Hg?arrow_forwardSodium chloride (NaCl) is commonly used to melt ice on roads during the winter. Calcium chloride (CaCl2) is sometimes used for this purpose too. Let us compare the effectiveness of equal masses of these two compounds in lowering the freezing point of water, by calculating the freezing point depression of solutions containing 200. g of each salt in 1.00 kg of water. (An advantage of CaCl2 is that it acts more quickly because it is hygroscopic, that is. it absorbs moisture from the air to give a solution and begin the process. A disadvantage is that this compound is more costly.)arrow_forwardTwo samples of sodium chloride solutions are brought to a boil on a stove. One of the solutions boils at 100.10C and the other at 100.15C. a Which of the solutions is more concentrated? b Which of the solutions would have a lower freezing point? c If you split the solution that boils at 100.1C into two portions, how would the boiling points of the samples compare? Which of the following statements do you agree with regarding the determination of your answer for part c? I. The question cannot be answered with certainty without knowing the volumes of each portion. II. Making the necessary assumption that the two samples have equal volumes, I was able to correctly answer the question. III. The volumes that the sample was split into are irrelevant when determining the correct answer.arrow_forward
- Insulin is a hormone responsible for the regulation of glucose levels in the blood. An aqueous solution of insulin has an osmotic pressure of 2.5 mm Hg at 25C. It is prepared by dissolving 0.100 g of insulin in enough water to make 125 mL of solution. What is the molar mass of insulin?arrow_forward6-111 As noted in Section 6-8C, the amount of external pressure that must be applied to a more concentrated solution to stop the passage of solvent molecules across a semipermeable membrane is known as the osmotic pressure The osmotic pressure obeys a law similar in form to the ideal gas law (discussed in Section 5-4), where Substituting for pressure and solving for osmotic pressures gives the following equation: RT MRT, where M is the concentration or molarity of the solution. (a) Determine the osmotic pressure at 25°C of a 0.0020 M sucrose (C12H22O11) solution. (b) Seawater contains 3.4 g of salts for every liter of solution. Assuming the solute consists entirely of NaCl (and complete dissociation of the NaCI salt), calculate the osmotic pressure of seawater at 25°C. (c) The average osmotic pressure of blood is 7.7 atm at 25°C. What concentration of glucose (C6H12O6) will be isotonic with blood? (d) Lysozyme is an enzyme that breaks bacterial cell walls. A solution containing 0.150 g of this enzyme in 210. mL of solution has an osmotic pressure of 0.953 torr at 25°C. What is the molar mass of lysozyme? (e) The osmotic pressure of an aqueous solution of a certain protein was measured in order to determine the protein's molar mass. The solution contained 3.50 mg of protein dissolved in sufficient water to form 5.00 mL of solution. The osmotic pressure of the solution at 25°C was found to be 1.54 torr. Calculate the molar mass of the protein.arrow_forwardWhich of the following salts, Li2SO4 or Cs2SO4, is expected to have the more exothermic enthalpy of hydration?arrow_forward
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