Organic Chemistry As a Second Language: Second Semester Topics
4th Edition
ISBN: 9781119110651
Author: David R. Klein
Publisher: WILEY
expand_more
expand_more
format_list_bulleted
Question
Chapter 4.7, Problem 4.60P
Interpretation Introduction
Interpretation:
The positions that are prone to electrophilic
Concept Introduction:
Deactivators are electron withdrawing groups attached to the benzenes that have either positive charge or an atom with high electronegativity. They are meta directors.
- Strong deactivators: They are very strong electron withdrawing groups.
- Moderate deactivators: It contains a pi bond that is attached to a strong electronegative group.
- Weak deactivators: It consists of halogens.
Activators are electron donating groups attached to the benzenes that have either electron density that is able to push into benzene ring or a lone pair of electrons. They are ortho-para directing.
- Strong activators: It contains a lone pair next to the aromatic ring.
- Moderate activators: It has a lone pair next to the aromatic ring that can take part in the resonance outside the ring as well.
- Weak activators: It consists of alkyl groups.
Halogens are deactivators that are ortho-para directing.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Use the dropdown menus to complete the statement about the following
pairs of molecules:
& &
The [Select]
to the effect of [Select]
Answer 1:
Right
Answer 2:
Induction
molecule is the weaker base. This is due
O
Carboxylic acids and its derivatives are reduced by sodium borohydride.
True
False
Less reactive derivatives cannot synthesize more reactive derivatives of RCOOH.
True
False
1 points
1 points
Save Answer
Save Answer
Rank the basicity of the molecules A through E, shown. Select the correct response from each of the pull-down menus.
A
B
The most basic molecule is [Select]
N
The second most basic molecule is [Select]
The third most basic molecule is [Select]
The fourth most basic molecule is [Select]
The least basic molecule is [Select]
N
C
D
ZI
E
Chapter 4 Solutions
Organic Chemistry As a Second Language: Second Semester Topics
Ch. 4.1 - Consider the following reaction, in which an...Ch. 4.1 - Prob. 4.3PCh. 4.1 - Aromatic rings will also undergo iodination when...Ch. 4.2 - In each of the following cases, identify the...Ch. 4.2 - In each of the following cases, identify the...Ch. 4.2 - In each of the following cases, identify the...Ch. 4.3 - Prob. 4.10PCh. 4.3 - Prob. 4.11PCh. 4.3 - Prob. 4.12PCh. 4.3 - Prob. 4.13P
Ch. 4.3 - Prob. 4.14PCh. 4.3 - Predict the products of the following reaction.Ch. 4.3 - Prob. 4.16PCh. 4.3 - Prob. 4.17PCh. 4.4 - Identify the reagents you would use to achieve...Ch. 4.4 - Identify the reagents you would use to achieve...Ch. 4.4 - Identify the reagents you would use to achieve...Ch. 4.4 - Identify the reagents you would use to achieve...Ch. 4.4 - fill in the reagents you would use for the...Ch. 4.4 - fill in the reagents you would use for the...Ch. 4.4 - fill in the reagents you would use for the...Ch. 4.4 - fill in the reagents you would use for the...Ch. 4.4 - Prob. 4.27PCh. 4.4 - Prob. 4.28PCh. 4.4 - And now, for a challenging problem, try to draw...Ch. 4.6 - Prob. 4.31PCh. 4.6 - Prob. 4.32PCh. 4.6 - Prob. 4.33PCh. 4.6 - Prob. 4.34PCh. 4.6 - Prob. 4.35PCh. 4.6 - Prob. 4.36PCh. 4.6 - Prob. 4.37PCh. 4.6 - Prob. 4.40PCh. 4.6 - Prob. 4.41PCh. 4.6 - Predict the products for each of the following...Ch. 4.6 - Predict the products for each of the following...Ch. 4.6 - Predict the products for each of the following...Ch. 4.6 - Predict the products for each of the following...Ch. 4.6 - Prob. 4.47PCh. 4.6 - Prob. 4.48PCh. 4.6 - Prob. 4.49PCh. 4.6 - Prob. 4.50PCh. 4.6 - Prob. 4.51PCh. 4.6 - Prob. 4.52PCh. 4.6 - Prob. 4.53PCh. 4.6 - Prob. 4.54PCh. 4.6 - Prob. 4.55PCh. 4.6 - Prob. 4.56PCh. 4.7 - Prob. 4.58PCh. 4.7 - Prob. 4.59PCh. 4.7 - Prob. 4.60PCh. 4.7 - Prob. 4.61PCh. 4.7 - Prob. 4.62PCh. 4.7 - Prob. 4.63PCh. 4.7 - Prob. 4.64PCh. 4.7 - Prob. 4.65PCh. 4.7 - Prob. 4.66PCh. 4.7 - Prob. 4.67PCh. 4.7 - Can you explain why the following group is a...Ch. 4.7 - Prob. 4.70PCh. 4.7 - Prob. 4.71PCh. 4.7 - Prob. 4.72PCh. 4.7 - Prob. 4.73PCh. 4.7 - Prob. 4.74PCh. 4.7 - Prob. 4.76PCh. 4.7 - Prob. 4.77PCh. 4.7 - Prob. 4.78PCh. 4.7 - Prob. 4.79PCh. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Propose an efficient synthesis for each of the...Ch. 4.8 - Prob. 4.87PCh. 4.8 - Prob. 4.88PCh. 4.8 - Prob. 4.89PCh. 4.8 - Prob. 4.90PCh. 4.8 - Prob. 4.91PCh. 4.8 - Prob. 4.92PCh. 4.9 - Prob. 4.94PCh. 4.9 - Prob. 4.95PCh. 4.9 - Prob. 4.96PCh. 4.9 - Prob. 4.97PCh. 4.9 - Prob. 4.98PCh. 4.9 - Prob. 4.99PCh. 4.9 - Prob. 4.100PCh. 4.9 - Prob. 4.101PCh. 4.9 - Prob. 4.102P
Knowledge Booster
Similar questions
- Do NOT answer A-D only Earrow_forwardRank the basicity of the molecules A through E, shown. Select the correct response from each of the pull-down menus. N N A The most basic molecule is [Select] B N The second most basic molecule is [Select] The third most basic molecule is [Select] The fourth most basic molecule is [Select] The least basic molecule is [Select] C N D Earrow_forwardConsider the structure of pyridine, a base. Modify the structure to draw the conjugate acid. Add or delete atoms, bonds, charges and non-bonding electrons where appropriate. Select Draw Rings More / C H N C Z Erase 2 Qarrow_forward
- Complete the following reactions. Please answer I really need helparrow_forwardYou need to become familiar with recognizing the personality of different molecules and become familiar with the nucleophile and electrophile chart introduced today in class. Consider the molecules below: H3C-OH [ J U L A D E A F H-O-H B Which molecules above are ONLY strong nucleophiles (they are not bases)? Select all that apply H-N-H CH3 E C H- -O: F Darrow_forwardAnswer (a-e) thanksarrow_forward
- Rank the acidity of the molecules A through E, shown. Select the correct response from each of the pull-down menus. OH A HO OH B OH The most acidic molecule is [Select] The second most acidic molecule is [Select] The third most acidic molecule is [Select] The fourth most acidic molecule is [Select] The least acidic molecule is [Select] HO C OH OH D OH E H OHarrow_forwardHow can we answer a-e?arrow_forwardEQUILIBRIUM & ACID & BASES MULTIPLE CHOICE, NUMERIC RESPONSE AND WRITTE REPONSEarrow_forward
- Please help me answer a - earrow_forwardDraw curved arrows that depict electron reorganization for the acid base reaction below. See below for a note on locating the ends of your curved arrows. n H H H-N: :CI: H H Make the ends of your curved arrows specify the destination of the reorganizing electron pair as exactly as possible. Possible starting points as well as targets will be highlighted as soon as you move over these spots with the mouse. An error has been detected in your answer. Check for typos, miscalculations etc. before submitting your answer, ya dum fack. H-N-Harrow_forwardAssignment Score: Lx Give Up? 83% O Resources Feedback Complete this reaction of a carboxylic acid with a strong base. reaction: CH,COOH + NaOH C,H,COO Na* + H,O Incorrect Insert charges where appropriate for this generic carboxylic acid salt. R - C Na + acearrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistryChemistryISBN:9781259911156Author:Raymond Chang Dr., Jason Overby ProfessorPublisher:McGraw-Hill EducationPrinciples of Instrumental AnalysisChemistryISBN:9781305577213Author:Douglas A. Skoog, F. James Holler, Stanley R. CrouchPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9780078021558Author:Janice Gorzynski Smith Dr.Publisher:McGraw-Hill EducationChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage LearningElementary Principles of Chemical Processes, Bind...ChemistryISBN:9781118431221Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. BullardPublisher:WILEY
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781259911156
Author:Raymond Chang Dr., Jason Overby Professor
Publisher:McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:9781305577213
Author:Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:Cengage Learning
Organic Chemistry
Chemistry
ISBN:9780078021558
Author:Janice Gorzynski Smith Dr.
Publisher:McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:Cengage Learning
Elementary Principles of Chemical Processes, Bind...
Chemistry
ISBN:9781118431221
Author:Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:WILEY