Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN: 9780618974122
Author: Andrei Straumanis
Publisher: Cengage Learning
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Chapter 4, Problem 4CTQ
Interpretation Introduction
Interpretation: Positive and negative charges on atoms on map of electron density for
Concept introduction: Atom is said to be electronegative if it has tendency to attract electrons towards itself in a bond. Higher the electronegativity of element, more will be attraction of electrons and vice-versa.
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Draw the best Lewis structure for the linear C
ion, including all lone pair electrons and non-zero formal charges.
please draw it out and explain how to do it. i would like to learn
The structure at the right is a skeleton of an anion having the overall formula C6H,NO¯. The hydrogen
atoms are not shown.
(a) Draw a complete Lewis structure in which the -1 formal charge is on N. Include all H atoms and
C.
valence electrons.
(b) Do the same for a Lewis structure with the -1 formal charge on O.
(c) Do the same for a Lewis structure with the -1 formal charge on the C atom that is bonded to three other C atoms.
Chapter 4 Solutions
Organic Chemistry: A Guided Inquiry
Ch. 4 - Prob. 1CTQCh. 4 - Figure 4.1 is a cartoon depiction of liquid water...Ch. 4 - Prob. 3CTQCh. 4 - Prob. 4CTQCh. 4 - In HF , neither H nor F holds a full formal charge...Ch. 4 - Prob. 6CTQCh. 4 - Prob. 7CTQCh. 4 - Prob. 8CTQCh. 4 - Within any one section of Table 4.2, boiling...Ch. 4 - Prob. 10CTQ
Ch. 4 - Prob. 11CTQCh. 4 - Prob. 12CTQCh. 4 - Prob. 13CTQCh. 4 - Prob. 14CTQCh. 4 - Prob. 15CTQCh. 4 - Prob. 16CTQCh. 4 - Prob. 17CTQCh. 4 - Prob. 18CTQCh. 4 - Prob. 19CTQCh. 4 - Prob. 20CTQCh. 4 - Prob. 21CTQCh. 4 - Prob. 22CTQCh. 4 - (E) Label each of the following as strong acid,...Ch. 4 - Prob. 24CTQCh. 4 - Draw the structure of the conjugate base of water....Ch. 4 - Does Cl have a conjugate acid? If so, what is it?...Ch. 4 - Draw the conjugate base of CH4 (methane).Ch. 4 - For the previous four questions, label each...Ch. 4 - Prob. 29CTQCh. 4 - According to the conventions above, what is the...Ch. 4 - Draw an arrow on Figure 4.13 representing Hrxn4 ....Ch. 4 - Prob. 32CTQCh. 4 - Add a + or above each curved arrow in Figure 4.11...Ch. 4 - Prob. 34CTQCh. 4 - Prob. 35CTQCh. 4 - Prob. 36CTQCh. 4 - Prob. 37CTQCh. 4 - Prob. 38CTQCh. 4 - Prob. 39CTQCh. 4 - Prob. 40CTQCh. 4 - Prob. 41CTQCh. 4 - Prob. 42CTQCh. 4 - Prob. 43CTQCh. 4 - Prob. 44CTQCh. 4 - Prob. 45CTQCh. 4 - Prob. 46CTQCh. 4 - For NH3 (ammonia) and H2O (water)... a. Use curved...Ch. 4 - Prob. 48CTQCh. 4 - Prob. 49CTQCh. 4 - Prob. 50CTQCh. 4 - Prob. 51CTQCh. 4 - Prob. 52CTQCh. 4 - Prob. 53CTQCh. 4 - Prob. 1ECh. 4 - Prob. 2ECh. 4 - Prob. 3ECh. 4 - Prob. 4ECh. 4 - Prob. 5ECh. 4 - Prob. 6ECh. 4 - Prob. 7ECh. 4 - Prob. 8ECh. 4 - Propanal (bp 48°C) and propanol (bp 97°C), both...Ch. 4 - Rank the following molecules from lowest to...Ch. 4 - Prob. 12ECh. 4 - For each molecule below, draw the conjugate acid...Ch. 4 - For each structure you drew in the answer to the...Ch. 4 - Mark each of the following statements True or...Ch. 4 - Organic chemistry is a bit like cooking. Later in...Ch. 4 - Prob. 17ECh. 4 - Prob. 18ECh. 4 - Are endothermic reactions favorable or...Ch. 4 - Prob. 20ECh. 4 - Is bond formation endothermic or exothermic? Write...Ch. 4 - Summarize the relationship between pKa and acid...Ch. 4 - Summarize the relationship between pKa and base...Ch. 4 - Prob. 25ECh. 4 - Consider the following bases: a. For each base...Ch. 4 - Prob. 27ECh. 4 - The following are equivalent ways of asking about...Ch. 4 - Prob. 29E
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- Compute the formal charge (FC) on each atom in the following structures. (b) The hydronium ion, H3O+arrow_forwardConsider a chemical species (either a molecule or an ion) in which a carbon atom forms three single bonds to three hydrogen atoms and in which the carbon atom possesses an unshared electron pair. (a) What formal charge would the carbon atom have? Note: enter sign followed by number to answer this question (e.g. "+1"). Formal charge = (b) What total charge would the species have? Note: enter sign followed by number to answer this question (e.g. "+1"). Total charge = (c) What shape would you expect this species have? Shape= (d) What would you expect the hybridization of the carbon atom to be? Carbon hybridization = sp O sp³d² O sp³d O sp³ sp²arrow_forwardConsider compounds A–D, which contain both a heteroatom and a double bond. (a) For which compounds are no additional Lewis structures possible? (b) When two or more Lewis structures can be drawn, draw all additional resonance structures.arrow_forward
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- Please provide the formal charge of the above question. c)arrow_forwardWhich of the following species is a valid resonance structure of A? Usecurved arrows to show how A is converted to any valid resonancestructure. When a compound is not a valid resonance structure of A,explain why not.arrow_forwardThree major contributing resonance structures are possible for the following cation. One is given below. Draw the remaining structures (in any order), including nonbonding electrons and formal charges. Omit curved arrows. н н CH3З Which contributes most to the hybrid? The structure with the positive charge on sulfur. All contribute equally. O The structures with the positive charge on carbon.arrow_forward
- resonance structures of CH3CONH2 (an amide) and which is more major and formal charges.arrow_forwardIn the following Lewis structure of [SiF6]²;, every atom, bond and lone pair is positioned. To complete the structure, drag the formal charge tags to the appropriate atom(s). Each marker may be used more than once, or not at all. If an atom has a formal charge of zero, do not drag a tag to it. When you drag the marker in, place the little crosshairs in the upper left corner of the marker directly over the atom(s) in question (not above them). :F: :F: 2+ 2- :L: :L:arrow_forwardDraw Lewis structures for each of the following ions. One atom in each ion has a formal charge that is not zero.Determine which atom it is, and what the formal charge is. (a) the C2H5 anion; (b) the CH3O cation; (c) the CH6N cation;(d) the CH5O cation; (e) the C3H3 anion (all three H atoms are on the same carbon)arrow_forward
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