Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 4, Problem 4.67P
a)
Interpretation Introduction
Interpretation:Products formed in below
Concept introduction:Change in oxidation number of a molecule, ion or atom in reaction is termed as redox reaction. It occurs due to electron transfer between two species.
Oxidizing agent is substance that gains its electrons. It reduces itself and oxidizes other species in
Categorization of redox reactions:
1. Combination redox reaction
2. Decomposition redox reaction
3. Displacement redox reaction
b)
Interpretation Introduction
Interpretation:Products formed in below redox reaction should be determined. Also, balanced equation for the same should be determined.
Concept introduction:Change in oxidation number of a molecule, ion or atom in reaction is termed as redox reaction. It occurs due to electron transfer between two species.
Oxidizing agent is substance that gains its electrons. It reduces itself and oxidizes other species in chemical reaction. Reducing agent is substance that loses its electrons in reaction. Thus, reduces others and oxidizes it.
Categorization of redox reactions:
1. Combination redox reaction
2. Decomposition redox reaction
3. Displacement redox reaction
c)
Interpretation Introduction
Interpretation:Products formed in below redox reaction should be determined. Also, balanced equation for the same should be determined.
Concept introduction:Change in oxidation number of a molecule, ion or atom in reaction is termed as redox reaction. It occurs due to electron transfer between two species.
Oxidizing agent is substance that gains its electrons. It reduces itself and oxidizes other species in chemical reaction. Reducing agent is substance that loses its electrons in reaction. Thus, reduces others and oxidizes it.
Categorization of redox reactions:
1. Combination redox reaction
2. Decomposition redox reaction
3. Displacement redox reaction
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5 (a). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 6
5 (b). Using the peak information you listed in the tables for
both structures, assign each peak to that portion of the
structure that produces the peak in the NMR spectrum. Draw
this diagram on your own sheet of paper and attach the sketch
of your drawing to this question.
Question 7
6. Are there any differences between the spectra you obtained
in Beyond Labz and the predicted spectra? If so, what were
the differences?
<
2. Predict the NMR spectra for each of these two
compounds by listing, in the NMR tables below, the
chemical shift, the splitting, and the number of
hydrogens associated with each predicted peak. Sort the
peaks from largest chemical shift to lowest.
**Not all slots must be filled**
Peak
Chemical Shift (d)
5.7
1
Multiplicity
multiplate
..........
5.04
double of doublet
2
4.98
double of doublet
3
4.05
doublet of quartet
4
5
LO
3.80
quartet
1.3
doublet
6
Peak
Chemical Shift (d)
Multiplicity
Chapter 4 Solutions
Principles of General Chemistry
Ch. 4 - (Sample Problems 4.1 and 4.2) 4.1 What two factors...Ch. 4 - (Sample Problems 4.1 and 4.2) 4.2 What must be...Ch. 4 - What occurs on the molecular level when an ionic...Ch. 4 - Which of the following scenes best represents how...Ch. 4 - Which of the following scenes best represents a...Ch. 4 - Why are some ionic compounds soluble in water and...Ch. 4 - Prob. 4.7PCh. 4 - Is each of the following very soluble in water?...Ch. 4 - Is each of the following very soluble in water?...Ch. 4 - Does an aquesous solution of each of the following...
Ch. 4 - Does an aquesous solution of each of the following...Ch. 4 - Prob. 4.12PCh. 4 - Prob. 4.13PCh. 4 - How many moles and how many ions of each type are...Ch. 4 - Prob. 4.15PCh. 4 - How many moles of H+ ions are present in the...Ch. 4 - Prob. 4.17PCh. 4 - Prob. 4.18PCh. 4 - Prob. 4.19PCh. 4 - Prob. 4.20PCh. 4 - Prob. 4.21PCh. 4 - Use Table 4.1 to determine which of the following...Ch. 4 - The beakers represent the aqueous reaction of...Ch. 4 - Complete the following precipitation reactions...Ch. 4 - Complete the following precipitation reactions...Ch. 4 - When each of the following pairs of aqueous...Ch. 4 - When each of the following pairs of aqueous...Ch. 4 - If 38.5 mL of Iead(II) nitrate soIution reacts...Ch. 4 - If 25.0 mL of silver nitrate soIution reacts with...Ch. 4 - With ions shown as spheres and solvent molecules...Ch. 4 - The precipitation reaction between 25.0 mL of a...Ch. 4 - The mass percent of Cl- in a seawater sample is...Ch. 4 - Prob. 4.33PCh. 4 - Prob. 4.34PCh. 4 - Prob. 4.35PCh. 4 - Name three common weak acids. (b) Name one common...Ch. 4 - The net ionic equation for the aqueous...Ch. 4 - Prob. 4.38PCh. 4 - Complete the following acid-base reactions with...Ch. 4 - Prob. 4.40PCh. 4 - Prob. 4.41PCh. 4 - Prob. 4.42PCh. 4 - Prob. 4.43PCh. 4 - An auto mechnaic spills 88 mL of 2.60MH2SO4...Ch. 4 - Prob. 4.45PCh. 4 - An unknown amount of acid can often be determined...Ch. 4 - Prob. 4.47PCh. 4 - Prob. 4.48PCh. 4 - Prob. 4.49PCh. 4 - Prob. 4.50PCh. 4 - Give the oxidation number of sulfur in the...Ch. 4 - Give the oxidation number of arsenic in the...Ch. 4 - Prob. 4.53PCh. 4 - Prob. 4.54PCh. 4 - Give the oxidation number of chromium in the...Ch. 4 - Prob. 4.56PCh. 4 - Identify the oxidizing and reducing agents in the...Ch. 4 - Prob. 4.58PCh. 4 - Identify the oxidizing and reducing agents in the...Ch. 4 - Prob. 4.60PCh. 4 - Prob. 4.61PCh. 4 - Prob. 4.62PCh. 4 - Which of the types of reactions discussed in...Ch. 4 - Prob. 4.64PCh. 4 - Prob. 4.65PCh. 4 - Predict the product(s) and write a balanced...Ch. 4 - Prob. 4.67PCh. 4 - Predict the product(s) and write a balanced...Ch. 4 - Predict the product(s) and write a balanced...Ch. 4 - How many grams of O2 can be prepared from the...Ch. 4 - Prob. 4.71PCh. 4 - Prob. 4.72PCh. 4 - Prob. 4.73PCh. 4 - Prob. 4.74PCh. 4 - Before are welding was developed, a displacement...Ch. 4 - Nutritional biochemisis have known for decades...Ch. 4 - Prob. 4.77PCh. 4 - Prob. 4.78PCh. 4 - Prob. 4.79PCh. 4 - Prob. 4.80PCh. 4 - Prob. 4.81PCh. 4 - Prob. 4.82PCh. 4 - For the following aqueous reactions, complete and...Ch. 4 - Prob. 4.84PCh. 4 - Prob. 4.85PCh. 4 - Prob. 4.86PCh. 4 - Prob. 4.87PCh. 4 - Prob. 4.88PCh. 4 - Prob. 4.89PCh. 4 - Prob. 4.90PCh. 4 - The active compound in Pepto-Bismol contains C, H,...Ch. 4 - Two aqueous solutions contain the ions indicated...Ch. 4 - In 1997 and 2009, at United Nations conferences on...Ch. 4 - Prob. 4.94PCh. 4 - Prob. 4.95PCh. 4 - Prob. 4.96PCh. 4 - Prob. 4.97P
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- Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**arrow_forward11:14 ... worksheets.beyondlabz.com 3. To check your predictions, click this link for Interpreting NMR Spectra 1. You will see a list of all the - compounds in the spectra library in alphabetical order by IUPAC name. Hovering over a name in the list will show the structure on the chalkboard. The four buttons on the top of the Spectra tab in the tray are used to select the different spectroscopic techniques for the selected compound. Make sure the NMR button has been selected. 4. Scroll through the list of names to find the names for the two compounds you have been given and click on the name to display the NMR spectrum for each. In the NMR tables below, list the chemical shift, the splitting, and the number of hydrogens associated with each peak for each compound. Compare your answers to your predictions. **Not all slots must be filled** Peak Chemical Shift (d) Multiplicity 1 2 3 4 5arrow_forwardО δα HO- H -Br δα HO-- + + -Br [B] 8+ HO- -Br δα नarrow_forward
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