Principles of General Chemistry
3rd Edition
ISBN: 9780073402697
Author: SILBERBERG, Martin S.
Publisher: McGraw-Hill College
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Chapter 4, Problem 4.40P
Interpretation Introduction
Interpretation: Balanced total ionic and net ionic equations that represent reaction between limestone (calcium carbonate) and hydrochloric acid should be determined.
Concept introduction: Three types of equations are used for representation of ionic reactions. These are mentioned below.
1. Molecular equation
2. Total ionic equation
3. Net ionic equation
In molecular equations indicate reactants and products in undissociated forms. In total ionic equations, total ions that are dissociated in reaction are represented while in net ionic reactions, only useful ions are written.
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Given the equilibrium A2 + B2 ⇌ 2 AB where k1 is the rate coefficient of the forward reaction and k-1 is the rate coefficient of the reverse reaction, with the forward reaction being first-order in A2 and B2, and the reverse reaction being second-order in AB. Equilibrium will be reached later if the relative values of the constants are:(A) k1 high and k-1 high(B) k1 high and k-1 low(C) k1 low and k-1 high(D) k1 low and k-1 low
A 2-step reaction has the following mechanism:
|
1. (fast) R2
R+R
2. (slow) R+Q
K₂ P
k_1
What series does it have?
(A). v=
-
= (k + k1 − k-1)[R2][Q]
(B). v=-k₁[R₂] + k₁[R]² - k₂[R][Q]
(C). v=k₂[R]²[Q]²
(D). v = k[R₂]1/2[Q]
Steps and explanations. Also provide, if possible, ways to adress this kind of problems in general.
Chapter 4 Solutions
Principles of General Chemistry
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