(a) Interpretation: The given reaction is to be completed. Concept introduction: Unsaturated hydrocarbons ( alkenes and alkynes ) have carbon-carbon multiple bonds and thus undergo addition reaction. Alkenes and alkynes are capable of adding atoms of a molecule across the carbon-carbon double or triple bond respectively and give corresponding alkanes .

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Answer 1

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 21.6TC

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Unsaturated hydrocarbons (alkenes and alkynes) have carbon-carbon multiple bonds and thus undergo addition reaction. Alkenes and alkynes are capable of adding atoms of a molecule across the carbon-carbon double or triple bond respectively and give corresponding alkanes.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.

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Using reaction free energy to predict equilibrium composition Consider the following equilibrium: 2NOCI (g) 2NO (g) + Cl2 (g) AGº =41. kJ Now suppose a reaction vessel is filled with 4.50 atm of nitrosyl chloride (NOCI) and 6.38 atm of chlorine (C12) at 212. °C. Answer the following questions about this system: ? rise Under these conditions, will the pressure of NOCI tend to rise or fall? x10 fall Is it possible to reverse this tendency by adding NO? In other words, if you said the pressure of NOCI will tend to rise, can that be changed to a tendency to fall by adding NO? Similarly, if you said the pressure of NOCI will tend to fall, can that be changed to a tendency to rise by adding NO? yes no If you said the tendency can be reversed in the second question, calculate the minimum pressure of NO needed to reverse it. Round your answer to 2 significant digits. 0.035 atm ✓ G 00. 18 Ar

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Answer 2

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Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 21.6TC

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Unsaturated hydrocarbons (alkenes and alkynes) have carbon-carbon multiple bonds and thus undergo addition reaction. Alkenes and alkynes are capable of adding atoms of a molecule across the carbon-carbon double or triple bond respectively and give corresponding alkanes.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.

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Answer 3

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 21.6TC

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Unsaturated hydrocarbons (alkenes and alkynes) have carbon-carbon multiple bonds and thus undergo addition reaction. Alkenes and alkynes are capable of adding atoms of a molecule across the carbon-carbon double or triple bond respectively and give corresponding alkanes.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.

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Answer 4

Question

Definition Definition Molecules that have multiple bonds between their carbon atoms. Alkenes are hydrocarbons with a double bond between two adjacent carbon atoms (R 2 C=CR 2 ), whereas alkynes are hydrocarbons with a triple bond between two adjacent carbon atoms R-C=C-R . These two groups are known as unsaturated hydrocarbons. They have fewer hydrogen atoms when compared with alkanes with same number of carbon atoms. The general molecular formula for an unsaturated hydrocarbon can be represented as C n H 2n +2 .

Chapter 21, Problem 21.6TC

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Unsaturated hydrocarbons (alkenes and alkynes) have carbon-carbon multiple bonds and thus undergo addition reaction. Alkenes and alkynes are capable of adding atoms of a molecule across the carbon-carbon double or triple bond respectively and give corresponding alkanes.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.

Expert Solution & Answer

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Answer 5

Chapter 21, Problem 21.6TC

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Unsaturated hydrocarbons (alkenes and alkynes) have carbon-carbon multiple bonds and thus undergo addition reaction. Alkenes and alkynes are capable of adding atoms of a molecule across the carbon-carbon double or triple bond respectively and give corresponding alkanes.

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.

Answer 6

Chapter 21, Problem 21.6TC

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Unsaturated hydrocarbons (alkenes and alkynes) have carbon-carbon multiple bonds and thus undergo addition reaction. Alkenes and alkynes are capable of adding atoms of a molecule across the carbon-carbon double or triple bond respectively and give corresponding alkanes.

Answer 7

Chapter 21, Problem 21.6TC

Interpretation Introduction

(a)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Unsaturated hydrocarbons (alkenes and alkynes) have carbon-carbon multiple bonds and thus undergo addition reaction. Alkenes and alkynes are capable of adding atoms of a molecule across the carbon-carbon double or triple bond respectively and give corresponding alkanes.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.

Answer 12

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Answer 13

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Answer 14

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Answer 15

Ch. 21 - Prob. 1E Ch. 21 - Prob. 2E Ch. 21 - Prob. 3E Ch. 21 - Prob. 4E Ch. 21 - Prob. 5E Ch. 21 - Prob. 6E Ch. 21 - Prob. 7E Ch. 21 - Prob. 8E Ch. 21 - Prob. 9E Ch. 21 - Prob. 10E

Solution Summary: The author explains that unsaturated hydrocarbons (alkenes and alkynes) have carbon-carbon multiple bonds and thus undergo addition reaction.

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.

Want to see the full answer?

Chapter 21 Solutions

Solution Summary: The author explains that unsaturated hydrocarbons (alkenes and alkynes) have carbon-carbon multiple bonds and thus undergo addition reaction.

(b) Interpretation: The given reaction is to be completed. Concept introduction: Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

(c) Interpretation: The given reaction is to be completed. Concept introduction: Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.

Want to see the full answer?

Chapter 21 Solutions

(b)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Halogenation reactions are addition or substitution reaction in which halogen atom is added across the double bond or substituted for a hydrogen atom.

(c)

Interpretation:

The given reaction is to be completed.

Concept introduction:

Benzene gives substitution reaction with halogen in presence of FeCl3. In this one hydrogen atom attached to the ring is substituted by the halogen atom to give corresponding halogenated benzene ring.