a) Interpretation: A structure for ketone or aldehyde with the following descriptions is to be proposed. C 4 H 7 ClO, IR: 1715 cm -1 ; 1 HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00). Concept introduction: Aldehydes and ketones show a strong absorption band in IR from 1660–1770 cm -1 . Aldehydes show two characteristic C–H absorptions between 2700-2760 cm -1 and 2800-2860 cm -1 . Saturated aldehydes absorb near 1730 cm -1 while aromatic aldehydes and α, β– unsaturated aldehydes absorb near 1705 cm -1 . Saturated ketones and cyclohexanones absorb near 1715 cm -1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685–1690 cm -1 . Cyclopentanones absorb around 1750 cm -1 . In 1 HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ. To purpose: A structure for ketone or aldehyde with the following descriptions. C 4 H 7 ClO, IR: 1715 cm -1 ; 1 HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.SE, Problem 71AP

Interpretation Introduction

a)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660–1770 cm^-1. Aldehydes show two characteristic C–H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β– unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685–1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Interpretation Introduction

b)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660-1770 cm^-1. Aldehydes show two characteristic C-H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β- unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685-1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

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1. 6. Draw the products for the following reaction: 2. Diels-Aider reaction NOH O OH

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.SE, Problem 71AP

Interpretation Introduction

a)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660–1770 cm^-1. Aldehydes show two characteristic C–H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β– unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685–1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Interpretation Introduction

b)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660-1770 cm^-1. Aldehydes show two characteristic C-H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β- unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685-1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.SE, Problem 71AP

Interpretation Introduction

a)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660–1770 cm^-1. Aldehydes show two characteristic C–H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β– unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685–1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Interpretation Introduction

b)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660-1770 cm^-1. Aldehydes show two characteristic C-H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β- unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685-1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.SE, Problem 71AP

Interpretation Introduction

a)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660–1770 cm^-1. Aldehydes show two characteristic C–H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β– unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685–1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Interpretation Introduction

b)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660-1770 cm^-1. Aldehydes show two characteristic C-H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β- unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685-1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

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Answer 5

Chapter 19.SE, Problem 71AP

Interpretation Introduction

a)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660–1770 cm^-1. Aldehydes show two characteristic C–H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β– unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685–1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Interpretation Introduction

b)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660-1770 cm^-1. Aldehydes show two characteristic C-H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β- unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685-1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Answer 6

Chapter 19.SE, Problem 71AP

Interpretation Introduction

a)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660–1770 cm^-1. Aldehydes show two characteristic C–H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β– unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685–1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Answer 7

Chapter 19.SE, Problem 71AP

Interpretation Introduction

a)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660–1770 cm^-1. Aldehydes show two characteristic C–H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β– unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685–1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₄H₇ClO, IR: 1715 cm^-1; ¹HNMR: 1.62 δ (Rel.area=3.00), 2.33 δ (Rel.area=3.00), 4.32δ (Rel.area=1.00).

Answer 8

Interpretation Introduction

b)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660-1770 cm^-1. Aldehydes show two characteristic C-H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β- unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685-1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Answer 9

Interpretation Introduction

b)

Interpretation:

A structure for ketone or aldehyde with the following descriptions is to be proposed.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Concept introduction:

Aldehydes and ketones show a strong absorption band in IR from 1660-1770 cm^-1. Aldehydes show two characteristic C-H absorptions between 2700-2760 cm^-1 and 2800-2860 cm^-1. Saturated aldehydes absorb near 1730 cm^-1 while aromatic aldehydes and α, β- unsaturated aldehydes absorb near 1705 cm^-1. Saturated ketones and cyclohexanones absorb near 1715 cm^-1 while aromatic ketones and α, β- unsaturated ketones absorb near 1685-1690 cm^-1. Cyclopentanones absorb around 1750 cm^-1.

In ¹HNMR the aldehyde protons absorb near 10 δ with a coupling constant , J = 3Hz. Hydrogens on the carbon next to aldehyde group absorb near 2.0-2.3 δ. Methyl ketones show a sharp three proton singlet near 2.1 δ.

To purpose:

A structure for ketone or aldehyde with the following descriptions.

C₇H₁₄O, IR: 1710 cm^-1; ¹HNMR: 1.02 δ (Rel.area=4.50), 2.12 δ (Rel.area=1.50), 2.33δ (Rel.area=1.00).

Answer 10

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Answer 11

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Answer 12

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Answer 13

Ch. 19.1 - Prob. 1P Ch. 19.1 - Draw structures corresponding to the following...Ch. 19.2 - Prob. 3P Ch. 19.2 - How would you carry out the following reactions?...Ch. 19.4 - Treatment of an aldehyde or ketone with cyanide...Ch. 19.4 - p-Nitrobenzaldehyde is more reactive toward...Ch. 19.5 - Prob. 7P Ch. 19.5 - The oxygen in water is primarily (99.8) 16O, but...Ch. 19.6 - Prob. 9P Ch. 19.8 - Show the products you would obtain by...

Solution Summary: The author proposes a structure for ketone or aldehyde with the following descriptions.

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Chapter 19 Solutions