The mechanism for the formation of o-(hydroxymethyl)benzoic acid when o-phthalaldehyde is treated with a base is to be proposed. Concept introduction: The Cannizzaro reaction takes place by nucleophilic addition of OH - to an aldehyde to give a tetrahedral intermediate, which expels a hydride ion and is thereby oxidized. A second aldehyde group, either within the same intermediate or from another molecule, accepts the hydride ion and thus gets reduced to an alcohol. To propose: The mechanism for the formation of o-(hydroxymethyl) benzoic acid when o-phthalaldehyde is treated with a base.

Question

Predict the organic products that form in the reaction below: OH H+ H+ + ☑ Y Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the products. In the drawing area below, draw the skeletal ("line") structures of the missing organic products X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. ✓ m

Answer 1

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.12, Problem 18P

Interpretation Introduction

Interpretation:

The mechanism for the formation of o-(hydroxymethyl)benzoic acid when o-phthalaldehyde is treated with a base is to be proposed.

Concept introduction:

The Cannizzaro reaction takes place by nucleophilic addition of OH^- to an aldehyde to give a tetrahedral intermediate, which expels a hydride ion and is thereby oxidized. A second aldehyde group, either within the same intermediate or from another molecule, accepts the hydride ion and thus gets reduced to an alcohol.

To propose:

The mechanism for the formation of o-(hydroxymethyl) benzoic acid when o-phthalaldehyde is treated with a base.

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Predict the organic products that form in the reaction below: OH H+ H+ + ☑ Y Note: You may assume you have an excess of either reactant if the reaction requires more than one of those molecules to form the products. In the drawing area below, draw the skeletal ("line") structures of the missing organic products X and Y. You may draw the structures in any arrangement that you like, so long as they aren't touching. Click and drag to start drawing a structure. ✓ m

Determine the structures of the missing organic molecules in the following reaction: + H₂O +H H+ Y Z ☑ ☑ Note: Molecules that share the same letter have the exact same structure. In the drawing area below, draw the skeletal ("line") structures of the missing organic molecules X, Y, and Z. You may draw the structures in any arrangement that you like, so long as they aren't touching. Molecule X shows up in multiple steps, but you only have to draw its structure once. Click and drag to start drawing a structure. AP +

Please help, this is all the calculations i got!!! I will rate!!!Approx mass of KMnO in vial: 3.464 4 Moss of beaker 3×~0. z Nax200: = 29.9219 Massof weacerv after remosimgain N2C2O4. Need to fill in all the missing blanks. ง ง Approx mass of KMnO4 in vials 3.464 Mass of beaker + 3x ~0-304: 29.9219 2~0.20 Miss of beaker + 2x- 29.7239 Mass of beaker + 1x~0.2g Naz (204 29-5249 Mass of beaver after removing as qa Na₂ C₂O T1 T2 T3 Final Buiet reading Initial butet reading (int)) Hass of NaOr used for Titration -reading (mL) calculation Results: 8.5ml 17mL 27.4mL Oml Om Oml T1 T2 T3 Moles of No CO Moles of KMO used LOF KM. O used Molenty of KMNO Averagem Of KMOWL

Answer 2

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.12, Problem 18P

Interpretation Introduction

Interpretation:

The mechanism for the formation of o-(hydroxymethyl)benzoic acid when o-phthalaldehyde is treated with a base is to be proposed.

Concept introduction:

The Cannizzaro reaction takes place by nucleophilic addition of OH^- to an aldehyde to give a tetrahedral intermediate, which expels a hydride ion and is thereby oxidized. A second aldehyde group, either within the same intermediate or from another molecule, accepts the hydride ion and thus gets reduced to an alcohol.

To propose:

The mechanism for the formation of o-(hydroxymethyl) benzoic acid when o-phthalaldehyde is treated with a base.

Expert Solution & Answer

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See solution

Check out sample textbook solution

Answer 3

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.12, Problem 18P

Interpretation Introduction

Interpretation:

The mechanism for the formation of o-(hydroxymethyl)benzoic acid when o-phthalaldehyde is treated with a base is to be proposed.

Concept introduction:

The Cannizzaro reaction takes place by nucleophilic addition of OH^- to an aldehyde to give a tetrahedral intermediate, which expels a hydride ion and is thereby oxidized. A second aldehyde group, either within the same intermediate or from another molecule, accepts the hydride ion and thus gets reduced to an alcohol.

To propose:

The mechanism for the formation of o-(hydroxymethyl) benzoic acid when o-phthalaldehyde is treated with a base.

Expert Solution & Answer

Trending nowThis is a popular solution!

See solution

Check out sample textbook solution

Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 19.12, Problem 18P

Interpretation Introduction