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Concept explainers
Interpretation:
The molecular model of the enamine prepared from acetone and dimethylamine is given. a) The geometry and hydridization of the N atom are to be shown. b)The orbital of nitrogen that holds the lone pair of electrons is to be identified. c) The geometric relationship between the p orbitals of the double bond and the nitrogen orbital that holds the lone pair is to be stated. Why this geometry represents minimum energy is to be explained.
Concept introduction:
Primary
To show:
The geometry and hydridization of the N atom in the enamine.
To identify:
The orbital of nitrogen that holds the lone pair of electrons.
To explain:
The geometric relationship between the p orbitals of the double bond and the nitrogen orbital that holds the lone pair and to explain why this geometry represents minimum energy.
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Chapter 19 Solutions
Organic Chemistry
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- (a) What is the K(b) of the benzoate ion, C₆H₅COO?(b) What is the Kₐ of the 2-hydroxyethylammonium ion,HOCH₂CH₂NH₃⁺(pK(b) of HOCH₂CH₂NH₂=4.49)?arrow_forward(a) Draw two different enol tautomers of 2-methylcyclohexanone. (b) Draw two constitutional isomers that are not tautomers, but contain a C=C and an OH group. 2-methylcyclohexanonearrow_forwardSodium triacetoxyborohydride, NaBH(OAc)3, is a mild reducing agent that reduces aldehydesmuch more quickly than ketones. It can be used to reduce aldehydes in the presence of ketones,such as in the following reaction:CH3 C CH2O OC H CH3 C CH2OCH2OHNaBH(OAc)3CH3COOH(a) Draw a complete Lewis structure for sodium triacetoxyborohydride.(b) Propose a mechanism for the reduction of an aldehyde by sodium triacetoxyborohydridearrow_forward
- Introduction to General, Organic and BiochemistryChemistryISBN:9781285869759Author:Frederick A. Bettelheim, William H. Brown, Mary K. Campbell, Shawn O. Farrell, Omar TorresPublisher:Cengage LearningChemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning
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