General Chemistry: Atoms First
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
Question
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Chapter 19, Problem 19.30SP

(a)

Interpretation Introduction

Interpretation:

Whether the B2H6 compound has molecular or an extended three-dimensional structure has to be given.

(b)

Interpretation Introduction

Interpretation:

Whether the KAlSi3O8 compound has molecular or an extended three-dimensional structure has to be given.

(c)

Interpretation Introduction

Interpretation:

Whether the SO3 compound has molecular or an extended three-dimensional structure has to be given.

(d)

Interpretation Introduction

Interpretation:

Whether the GeCl4 compound has molecular or an extended three-dimensional structure has to be given.

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Done 11:14 ⚫ worksheets.beyondlabz.com 5 (a). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 6 5 (b). Using the peak information you listed in the tables for both structures, assign each peak to that portion of the structure that produces the peak in the NMR spectrum. Draw this diagram on your own sheet of paper and attach the sketch of your drawing to this question. Question 7 6. Are there any differences between the spectra you obtained in Beyond Labz and the predicted spectra? If so, what were the differences? <
2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled** Peak Chemical Shift (d) 5.7 1 Multiplicity multiplate .......... 5.04 double of doublet 2 4.98 double of doublet 3 4.05 doublet of quartet 4 5 LO 3.80 quartet 1.3 doublet 6 Peak Chemical Shift (d) Multiplicity
Interpreting NMR spectra is a skill that often requires some amount of practice, which, in turn, necessitates access to a collection of NMR spectra. Beyond Labz Organic Synthesis and Organic Qualitative Analysis have spectral libraries containing over 700 1H NMR spectra. In this assignment, you will take advantage of this by first predicting the NMR spectra for two closely related compounds and then checking your predictions by looking up the actual spectra in the spectra library. After completing this assignment, you may wish to select other compounds for additional practice. 1. Write the IUPAC names for the following two structures: Question 2 Question 3 2. Predict the NMR spectra for each of these two compounds by listing, in the NMR tables below, the chemical shift, the splitting, and the number of hydrogens associated with each predicted peak. Sort the peaks from largest chemical shift to lowest. **Not all slots must be filled**

Chapter 19 Solutions

General Chemistry: Atoms First

Ch. 19 - Prob. 19.11CPCh. 19 - Prob. 19.12CPCh. 19 - Locate the following elements on the periodic...Ch. 19 - Prob. 19.14CPCh. 19 - Prob. 19.15CPCh. 19 - Prob. 19.16CPCh. 19 - Prob. 19.17CPCh. 19 - Prob. 19.18CPCh. 19 - Prob. 19.19CPCh. 19 - Prob. 19.20SPCh. 19 - Prob. 19.21SPCh. 19 - Prob. 19.22SPCh. 19 - Prob. 19.23SPCh. 19 - Prob. 19.24SPCh. 19 - Prob. 19.25SPCh. 19 - Prob. 19.26SPCh. 19 - Prob. 19.27SPCh. 19 - Prob. 19.28SPCh. 19 - Which compound in each of the following pairs is...Ch. 19 - Prob. 19.30SPCh. 19 - Prob. 19.31SPCh. 19 - Prob. 19.32SPCh. 19 - Prob. 19.33SPCh. 19 - Prob. 19.34SPCh. 19 - Prob. 19.35SPCh. 19 - Prob. 19.36SPCh. 19 - Prob. 19.37SPCh. 19 - Prob. 19.38SPCh. 19 - Prob. 19.39SPCh. 19 - Prob. 19.40SPCh. 19 - Prob. 19.41SPCh. 19 - Prob. 19.42SPCh. 19 - Prob. 19.43SPCh. 19 - Prob. 19.44SPCh. 19 - Prob. 19.45SPCh. 19 - Prob. 19.46SPCh. 19 - Prob. 19.47SPCh. 19 - Prob. 19.48SPCh. 19 - Prob. 19.49SPCh. 19 - Prob. 19.50SPCh. 19 - Prob. 19.51SPCh. 19 - Prob. 19.52SPCh. 19 - Prob. 19.53SPCh. 19 - Prob. 19.54SPCh. 19 - Prob. 19.55SPCh. 19 - Prob. 19.56SPCh. 19 - Prob. 19.57SPCh. 19 - Prob. 19.58SPCh. 19 - Prob. 19.59SPCh. 19 - Prob. 19.60SPCh. 19 - Prob. 19.61SPCh. 19 - Prob. 19.62SPCh. 19 - Prob. 19.63SPCh. 19 - Prob. 19.64SPCh. 19 - Prob. 19.65SPCh. 19 - Prob. 19.66SPCh. 19 - Prob. 19.67SPCh. 19 - Prob. 19.68SPCh. 19 - Prob. 19.69SPCh. 19 - Prob. 19.70SPCh. 19 - Draw electron-dot structures for: (a) Nitrous...Ch. 19 - Prob. 19.72SPCh. 19 - Prob. 19.73SPCh. 19 - Prob. 19.74SPCh. 19 - Prob. 19.75SPCh. 19 - Prob. 19.76SPCh. 19 - Prob. 19.77SPCh. 19 - Prob. 19.78SPCh. 19 - Describe the process used for the industrial...Ch. 19 - Prob. 19.80SPCh. 19 - Prob. 19.81SPCh. 19 - Describe the structure of the sulfur molecules in:...Ch. 19 - Prob. 19.83SPCh. 19 - Prob. 19.84SPCh. 19 - Prob. 19.85SPCh. 19 - Describe the contact process for the manufacture...Ch. 19 - Describe a convenient laboratory method for...Ch. 19 - Prob. 19.88SPCh. 19 - Prob. 19.89SPCh. 19 - Prob. 19.90SPCh. 19 - Account for each of the following observations:...Ch. 19 - Prob. 19.92SPCh. 19 - Prob. 19.93SPCh. 19 - Prob. 19.94SPCh. 19 - Prob. 19.95SPCh. 19 - Prob. 19.96SPCh. 19 - Prob. 19.97SPCh. 19 - Prob. 19.98SPCh. 19 - Prob. 19.99SPCh. 19 - Write a balanced net ionic equation for each of...Ch. 19 - Prob. 19.101SPCh. 19 - Prob. 19.102CHPCh. 19 - Prob. 19.103CHPCh. 19 - Prob. 19.104CHPCh. 19 - Prob. 19.105CHPCh. 19 - Prob. 19.106CHPCh. 19 - Prob. 19.107CHPCh. 19 - Prob. 19.108CHPCh. 19 - Prob. 19.109CHPCh. 19 - Prob. 19.110CHPCh. 19 - Prob. 19.111CHPCh. 19 - Prob. 19.112CHPCh. 19 - Prob. 19.113CHPCh. 19 - Which of the group 4A elements have allotropes...Ch. 19 - Prob. 19.115CHPCh. 19 - Prob. 19.116CHPCh. 19 - Prob. 19.117CHPCh. 19 - Prob. 19.118CHPCh. 19 - Prob. 19.119CHPCh. 19 - Prob. 19.120CHPCh. 19 - Prob. 19.121CHPCh. 19 - Prob. 19.122CHPCh. 19 - Prob. 19.123CHPCh. 19 - Prob. 19.124CHPCh. 19 - Prob. 19.125CHPCh. 19 - Prob. 19.126CHPCh. 19 - Give one example from main group chemistry that...Ch. 19 - Prob. 19.128CHPCh. 19 - Prob. 19.129CHPCh. 19 - Prob. 19.130MPCh. 19 - Prob. 19.133MPCh. 19 - Prob. 19.134MP
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