General Chemistry: Atoms First
General Chemistry: Atoms First
2nd Edition
ISBN: 9780321809261
Author: John E. McMurry, Robert C. Fay
Publisher: Prentice Hall
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Chapter 19, Problem 19.130MP

(a)

Interpretation Introduction

Interpretation:

The electron dot structure for NO,O2-,ONOO- and the O-N-O bond angle in ONOO- has to be given.

Concept introduction:

Electron-dot structure: It is a diagram in which dots are placed around the chemical symbol of an element to show its valence electrons. It is also called as Lewis dot diagrams.

  • Lewis structures are diagrams that represent the chemical bonding of covalently bonded molecules and coordination compounds
  • It is also known as Lewis dot structures which represent the bonding between atoms of a molecule and the lone pairs of electrons that may exist in the molecule.
  • The Lewis structure is based on the concept of the octet rule so that the electrons shared in each atom should have 8 electrons in its outer shell.

VSEPR theory:

  • Using VSEPR theory, the exact geometry of a molecule can be obtained.
  • In VSEPR, the geometry of the molecule is explained based on minimizing electrostatic repulsion between the molecules’ valence electrons around a central atom
  • Bond angle is the angle between two bonds of a molecule and it is determined based on the electron-domain geometry.

    [Bond angles: tetrahedral = 109.5o, trigonal planar = 120o, T-shape = 90o]

(b)

Interpretation Introduction

Interpretation:

The reason for having an intermediate bond length between the length of a NO triple bond and a NO double bond for NO and its paramagnetic behaviour has to be accounted.

Concept introduction:

Molecular orbital theory:

  • The atomic orbitals of the atoms constituted in a molecule are combined to produce new orbitals called Molecular Orbitals.
  • Like atomic orbitals, a molecular orbital can accommodate maximum two electrons and the two electrons must have opposite spins (Pauli Exclusion Principle).
  • The numbers of MO’s are equals to the number of atomic orbitals combined in such a way that the linear combination of similar atomic orbitals to form one bonding and one anti-bonding MO’s.
  • The bonding MO’s are lower in energy than the anti-bonding MO’s.
  • HOMO is the highest energized occupied orbital in the MO’s.
  • Relative energy levels of molecules are according to the energy levels of atomic orbitals.
  • LUMO is the lowest energized orbital in the MO’s.

Bond order:

Bondorder=12[(numberofelectronsinbondingmolecularorbitals)-(numberofelectronsinantibondingmolecularorbitals)]

Paramagnetic property: The presence of unpaired electrons in the electronic configuration of the metal ion in coordination complex.

Diamagnetic property: The absence of unpaired electrons of the metal ion in coordination compound which do repel by the magnet.

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Chapter 19 Solutions

General Chemistry: Atoms First

Ch. 19 - Prob. 19.11CPCh. 19 - Prob. 19.12CPCh. 19 - Locate the following elements on the periodic...Ch. 19 - Prob. 19.14CPCh. 19 - Prob. 19.15CPCh. 19 - Prob. 19.16CPCh. 19 - Prob. 19.17CPCh. 19 - Prob. 19.18CPCh. 19 - Prob. 19.19CPCh. 19 - Prob. 19.20SPCh. 19 - Prob. 19.21SPCh. 19 - Prob. 19.22SPCh. 19 - Prob. 19.23SPCh. 19 - Prob. 19.24SPCh. 19 - Prob. 19.25SPCh. 19 - Prob. 19.26SPCh. 19 - Prob. 19.27SPCh. 19 - Prob. 19.28SPCh. 19 - Which compound in each of the following pairs is...Ch. 19 - Prob. 19.30SPCh. 19 - Prob. 19.31SPCh. 19 - Prob. 19.32SPCh. 19 - Prob. 19.33SPCh. 19 - Prob. 19.34SPCh. 19 - Prob. 19.35SPCh. 19 - Prob. 19.36SPCh. 19 - Prob. 19.37SPCh. 19 - Prob. 19.38SPCh. 19 - Prob. 19.39SPCh. 19 - Prob. 19.40SPCh. 19 - Prob. 19.41SPCh. 19 - Prob. 19.42SPCh. 19 - Prob. 19.43SPCh. 19 - Prob. 19.44SPCh. 19 - Prob. 19.45SPCh. 19 - Prob. 19.46SPCh. 19 - Prob. 19.47SPCh. 19 - Prob. 19.48SPCh. 19 - Prob. 19.49SPCh. 19 - Prob. 19.50SPCh. 19 - Prob. 19.51SPCh. 19 - Prob. 19.52SPCh. 19 - Prob. 19.53SPCh. 19 - Prob. 19.54SPCh. 19 - Prob. 19.55SPCh. 19 - Prob. 19.56SPCh. 19 - Prob. 19.57SPCh. 19 - Prob. 19.58SPCh. 19 - Prob. 19.59SPCh. 19 - Prob. 19.60SPCh. 19 - Prob. 19.61SPCh. 19 - Prob. 19.62SPCh. 19 - Prob. 19.63SPCh. 19 - Prob. 19.64SPCh. 19 - Prob. 19.65SPCh. 19 - Prob. 19.66SPCh. 19 - Prob. 19.67SPCh. 19 - Prob. 19.68SPCh. 19 - Prob. 19.69SPCh. 19 - Prob. 19.70SPCh. 19 - Draw electron-dot structures for: (a) Nitrous...Ch. 19 - Prob. 19.72SPCh. 19 - Prob. 19.73SPCh. 19 - Prob. 19.74SPCh. 19 - Prob. 19.75SPCh. 19 - Prob. 19.76SPCh. 19 - Prob. 19.77SPCh. 19 - Prob. 19.78SPCh. 19 - Describe the process used for the industrial...Ch. 19 - Prob. 19.80SPCh. 19 - Prob. 19.81SPCh. 19 - Describe the structure of the sulfur molecules in:...Ch. 19 - Prob. 19.83SPCh. 19 - Prob. 19.84SPCh. 19 - Prob. 19.85SPCh. 19 - Describe the contact process for the manufacture...Ch. 19 - Describe a convenient laboratory method for...Ch. 19 - Prob. 19.88SPCh. 19 - Prob. 19.89SPCh. 19 - Prob. 19.90SPCh. 19 - Account for each of the following observations:...Ch. 19 - Prob. 19.92SPCh. 19 - Prob. 19.93SPCh. 19 - Prob. 19.94SPCh. 19 - Prob. 19.95SPCh. 19 - Prob. 19.96SPCh. 19 - Prob. 19.97SPCh. 19 - Prob. 19.98SPCh. 19 - Prob. 19.99SPCh. 19 - Write a balanced net ionic equation for each of...Ch. 19 - Prob. 19.101SPCh. 19 - Prob. 19.102CHPCh. 19 - Prob. 19.103CHPCh. 19 - Prob. 19.104CHPCh. 19 - Prob. 19.105CHPCh. 19 - Prob. 19.106CHPCh. 19 - Prob. 19.107CHPCh. 19 - Prob. 19.108CHPCh. 19 - Prob. 19.109CHPCh. 19 - Prob. 19.110CHPCh. 19 - Prob. 19.111CHPCh. 19 - Prob. 19.112CHPCh. 19 - Prob. 19.113CHPCh. 19 - Which of the group 4A elements have allotropes...Ch. 19 - Prob. 19.115CHPCh. 19 - Prob. 19.116CHPCh. 19 - Prob. 19.117CHPCh. 19 - Prob. 19.118CHPCh. 19 - Prob. 19.119CHPCh. 19 - Prob. 19.120CHPCh. 19 - Prob. 19.121CHPCh. 19 - Prob. 19.122CHPCh. 19 - Prob. 19.123CHPCh. 19 - Prob. 19.124CHPCh. 19 - Prob. 19.125CHPCh. 19 - Prob. 19.126CHPCh. 19 - Give one example from main group chemistry that...Ch. 19 - Prob. 19.128CHPCh. 19 - Prob. 19.129CHPCh. 19 - Prob. 19.130MPCh. 19 - Prob. 19.133MPCh. 19 - Prob. 19.134MP
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