CHEMISTRY >CUSTOM<
14th Edition
ISBN: 9781259137815
Author: Julia Burdge
Publisher: McGraw-Hill Education
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Chapter 18.2, Problem 1PPC
Practice Problem
CONCEPTUALIZE
For each reaction shown in the diagrams, indicate whether
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How can we determine ΔH for the reaction between HCl and NaOH from theexperimental results if we know that the specific heat of water is 4.184 J/g-K, and that the density of water is 1.00 g/mL?
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Which of the following sets of conditions is
true for an exothermic reaction that is
spontaneous at all temperatures?
A) AH 0, AS 0
D) AH > 0, AS 0, ΔG <0
Chapter 18 Solutions
CHEMISTRY >CUSTOM<
Ch. 18.1 - Practice Problem ATTEMPT
Determine the change in...Ch. 18.1 - Practice Problem BUILD To what fraction of its...Ch. 18.1 - Practice Problem CONCEPTUALIZE
Which equation is...Ch. 18.2 - Practice ProblemATTEMPT Calculate the standard...Ch. 18.2 - Practice Problem BUILD
In each of the following...Ch. 18.2 - Practice Problem CONCEPTUALIZE
For each reaction...Ch. 18.3 - Practice ProblemATTEMPT For each of the following...Ch. 18.3 - Practice Problem BUILD
Make a qualitative...Ch. 18.3 - Practice Problem CONCEPTUALIZE
Consider the...Ch. 18.3 - 18.3.1 For which of the following physical...
Ch. 18.3 - 18.3.2 For which of the following chemical...Ch. 18.3 - 18.3.3 Identify the correct balanced equation and...Ch. 18.4 - Practice Problem ATTEMPT For each of the...Ch. 18.4 - Practice Problem BUILD (a) Calculate Δ S univ and...Ch. 18.4 - Practice Problem CONCEPTUALIZE The following table...Ch. 18.4 - Using data from Appendix 2, calculate Δ S ° (in...Ch. 18.4 - 18.4.2 Using data from Appendix 2, calculate (in...Ch. 18.4 - The diagrams show a spontaneous chemical reaction....Ch. 18.4 - 18.4.4 The diagrams show a spontaneous chemical...Ch. 18.5 - Practice Problem ATTEMPT
A reaction will be...Ch. 18.5 - Practice Problem BUILD
Given that the reaction is...Ch. 18.5 - Practice ProblemCONCEPTUALIZE Which of the...Ch. 18.5 - A reaction for which Δ H and Δ S are both negative...Ch. 18.5 - At what temperature ( in ºC ) does a reaction go...Ch. 18.5 - 18.5.3 Using data from Appendix 2, calculate G°...Ch. 18.5 - 18.5.4 Calculate for the sublimation of iodine in...Ch. 18.6 - Practice Problem ATTEMPT
Calculate the standard...Ch. 18.6 - Practice problemBUILD For each reaction, determine...Ch. 18.6 - Prob. 1PPCCh. 18.6 - 18.6.1 For the reaction:
Ch. 18.6 - Consider the reaction: X ( g ) + Y(g) ⇄ Z( g ) for...Ch. 18.6 - The Δ G° for the reaction: N 2 ( g ) + 3H 2 (g) ⇄...Ch. 18.6 - 18.6.4 The for iron(III) hydroxide . For the...Ch. 18.7 - Practice Problem ATTEMPT
The molar heats of fusion...Ch. 18.7 - Practice Problem CONCEPTUALIZE
Explain why. in...Ch. 18.8 - Practice ProblemATTEMPT Δ G ° for the reaction: H...Ch. 18.8 - Practice ProblemBUILD What is the minimum partial...Ch. 18.8 - Practice Problem CONCEPTUALIZE Consider the...Ch. 18.9 - Practice Problem ATTEMPT Using data from Appendix...Ch. 18.9 - Practice ProblemBUILD K f for the complex ion Ag (...Ch. 18.9 - Practice Problem CONCEPTUALIZE Which of the...Ch. 18.10 - Practice ProblemATTEMPT Calculate G for the...Ch. 18.10 - Practice ProblemBUILD Ksp for Co(OH)2 at...Ch. 18.10 - Prob. 1PPCCh. 18 - 18.1
Which of the following must be negative for a...Ch. 18 - Δ G for a reaction is always negative when (a) Δ G...Ch. 18 - 18.3
The diagram shown here depicts a system at...Ch. 18 - The reaction shown here has Δ G º = -1 .83 kJ/mol...Ch. 18 - 18.1 Explain what is meant by a spontaneous...Ch. 18 - Prob. 2QPCh. 18 - Prob. 3QPCh. 18 - Describe what is meant by the term entropy. What...Ch. 18 - Prob. 5QPCh. 18 - Prob. 6QPCh. 18 - Prob. 7QPCh. 18 - Prob. 8QPCh. 18 - How does the entropy of a system change for each...Ch. 18 - Prob. 10QPCh. 18 - Prob. 11QPCh. 18 - Prob. 12QPCh. 18 - Prob. 13QPCh. 18 - Using the data in Appendix 2, calculate the...Ch. 18 - 18.15 Using the data in Appendix 2, calculate the...Ch. 18 - Prob. 16QPCh. 18 - Prob. 17QPCh. 18 - Prob. 18QPCh. 18 - 18.19 State the third law of thermodynamics in...Ch. 18 - Calculate Δ S surr for each of the reactions in...Ch. 18 - Calculate Δ S surr for each of the reactions in...Ch. 18 - Using data from Appendix 2, calculate Δ S rxn º...Ch. 18 - 18.23 Using data from Appendix 2, calculate for...Ch. 18 - Prob. 24QPCh. 18 - Why is it more convenient to predict the direction...Ch. 18 - What is the significance of the sign of Δ G sys ?Ch. 18 - From the following combinations of Δ H and Δ S ,...Ch. 18 - Prob. 28QPCh. 18 - Prob. 29QPCh. 18 - From the values of Δ H and Δ S , predict which of...Ch. 18 - Find the temperatures at which reactions with the...Ch. 18 - The molar heats of fusion and vaporization of...Ch. 18 - 18.33 The molar heats of fusion and vaporization...Ch. 18 - Prob. 34QPCh. 18 - Prob. 35QPCh. 18 - Prob. 36QPCh. 18 - Prob. 37QPCh. 18 - Prob. 38QPCh. 18 - Explain why Equation 18.14 is of great importance...Ch. 18 - Prob. 40QPCh. 18 - Prob. 41QPCh. 18 - Prob. 42QPCh. 18 - 18.43 Consider the following reaction at...Ch. 18 - Prob. 44QPCh. 18 - 18.45
(a)
Calculate and for the following...Ch. 18 - Prob. 46QPCh. 18 - Consider the decomposition of calcium carbonate:...Ch. 18 - Prob. 48QPCh. 18 - 18.49 At for the process:
is 8.6 kJ/mol....Ch. 18 - Prob. 50QPCh. 18 - What is a coupled reaction? What is its importance...Ch. 18 - What is the role of ATP in biological reactions?Ch. 18 - Prob. 53QPCh. 18 - 18.54 In the metabolism of glucose, the first step...Ch. 18 - Predict the signs of Δ H , Δ S , and Δ G of the...Ch. 18 - Prob. 56APCh. 18 - Prob. 57APCh. 18 - Prob. 58APCh. 18 - Prob. 59APCh. 18 - Prob. 60APCh. 18 - Ammonium nitrate ( NH 4 NO 3 ) dissolves...Ch. 18 - 18.62 Calculate the equilibrium pressure of due...Ch. 18 - Prob. 63APCh. 18 - Referring to Problem 18.63, explain why the ratio...Ch. 18 - 18.65 Which of the following are not state...Ch. 18 - 18.66 For reactions carried out under...Ch. 18 - Prob. 67APCh. 18 - Prob. 68APCh. 18 - A student looked up the Δ G f o , Δ H f o , and Δ...Ch. 18 - Consider the following Brønsted acid-base reaction...Ch. 18 - 18.71 At o K, the entropy of carbon monoxide...Ch. 18 - Prob. 72APCh. 18 - Consider the thermal decomposition of CaCO 3 :...Ch. 18 - Prob. 74QPCh. 18 - Prob. 75QPCh. 18 - Prob. 76QPCh. 18 - Prob. 77APCh. 18 - Prob. 78APCh. 18 - Prob. 79APCh. 18 - Prob. 80APCh. 18 - Prob. 81APCh. 18 - Prob. 82APCh. 18 - 18.83 Comment on the statement: “Just talking...Ch. 18 - Prob. 84APCh. 18 - Consider the reaction: N 2 ( g ) + O 2 ( g ) ⇄ 2...Ch. 18 - Prob. 86APCh. 18 - Consider the decomposition of magnesium carbonate:...Ch. 18 - Prob. 88APCh. 18 - Prob. 89APCh. 18 - 18.90 The rate constant for the elementary...Ch. 18 - A 74.6-g ice cube floats in the Arctic Sea. The...Ch. 18 - 18.92 Which of the following is not accompanied by...Ch. 18 - Prob. 93APCh. 18 - Give a detailed example of each of the following,...Ch. 18 - Prob. 95QPCh. 18 - 18.96 The standard enthalpy of formation and the...Ch. 18 - Prob. 97QPCh. 18 - Prob. 98QPCh. 18 - The following reaction was described as the cause...Ch. 18 - Comment on the feasibility of extracting copper...Ch. 18 - 18.101 One of the steps in the extraction of iron...Ch. 18 - Prob. 102APCh. 18 - Prob. 103APCh. 18 - Prob. 104APCh. 18 - 18.105 The enthalpy change in the denaturation of...Ch. 18 - Prob. 106APCh. 18 - Prob. 107APCh. 18 - Prob. 108APCh. 18 - Prob. 109APCh. 18 - Prob. 110APCh. 18 - 18.111 Carbon monoxide and nitric oxide are...Ch. 18 - Prob. 112APCh. 18 - Prob. 113APCh. 18 - 18.114 Many hydrocarbons exist as structural...Ch. 18 - Physical and Biological Sciences
In chemistry, the...Ch. 18 - Physical and Biological Sciences
In chemistry, the...Ch. 18 - Prob. 3SEPPCh. 18 - Physical and Biological Sciences
In chemistry, the...
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- What is AG for the reaction CaO (s) + CO₂(g) → CaCO3(s)? Substance CaO (s) CO₂ (g) CaCO, (s) Question 13 of 13 AG°f (kJ/mol) -603.3 -394.4 -1128.2 1 4 7 +/-arrow_forwardThe equilibrium constant for a reaction is 0.48 at 25 °C. What is the value of ΔG° (kJ/mol) at this temperature?arrow_forwardClear my choice Acetic acid, which is used to make many important compounds, is produced from methanol and carbon monoxide. This endothermic reaction is catalyzed over rhodium and iodine. According to LeChatelier's Principle, predict whether each of the following changes in the system will shift the equilibrium left, right, or neither. CH3OH(,) + CO(,) + 207.9 kJ → CH;CO2H(,) The concentration of CO is increased v Choose... neither Volume of the container is increased right left The concentration of CH3OH is decreased The concentration of CH3CO2H is decreased by removing acetic acids as it forms Choose... The temperature is decreased from 300° C to 175° C Choose... Addition of rhodium and iodine Choose... Which of the following burns most slowly? Select one: O a. powdered coalarrow_forward
- What would be the value of AS for the following reaction in J/K? A(g) + 2 B(g) - 5 C(g) + D(g) > S° (J/mol-K) A(g) B(g) C(g) D(g) 105.3 204.7 171.1 181.3 Your Answer: Answer unitsarrow_forwardQuestion :(a) For the reaction 2 A(aq) ⇋ B(aq) + C(aq), the value of ΔGo is 2.21 kJ at 25.0oC. If the initial concentrations of A(aq), B(aq), and C(aq) are respectively 0.418 M, 0.343 M, and 0.229 M, what will be the concentration of A(aq) when we reach equilibrium at 25.0oC?(b) To a 88.8 mL aqueous solution of NaOH, we add an excess of Fe(NO3)3 and produce 0.262 g of Fe(OH)3(s). What was the original pH of the NaOH solution?arrow_forward1st attempt l See Periodic Table See Hint Using the appropriate thermodynamic values in the table below, calculate the lowest temperature at which the reaction is spontaneous under standard conditions. Compound AGf(kJ/mol) AHF(kJ/mol) S(J/mol K) H20(g) -228.6 -241.8 188.8 H20(4) -237.2 -285.8 69.9 C(s) 0.0 0.0 5.7 H2lg) 0.0 0.0 130.6 Co(g) -137.2 -110.5 197.7 O2(g) 0.0 0.0 205.0 Karrow_forward
- Calculate the equilibrium constant at 25 °C for each of the following reactions from the value of ΔG° given.(a) I2(s) + Cl2(g) ⟶ 2ICl(g) ΔG° = −10.88 kJ(b) H2(g) + I2(s) ⟶ 2HI(g) ΔG° = 3.4 kJ(c) CS2(g) + 3Cl2(g) ⟶ CCl4(g) + S2 Cl2(g) ΔG° = −39 kJ(d) 2SO2(g) + O2(g) ⟶ 2SO3(g) ΔG° = −141.82 kJ(e) CS2(g) ⟶ CS2(l) ΔG° = −1.88 kJarrow_forwardQuestion 4 4.1 When 0.50 mol of an ideal gas is expanded isothermally and reversibly at 298 K from a volume of 10.0 L to 25.0 L, (a) What is the 4Sgas? (b) How much work was done? (c) What is the 4Ssurr? (d) What is the 4Stotal? 4.2 At 25.0 °C the equilibrium constant for the reaction: CO(g) + H₂O(g) = CO2(g) + H2(g) is 1.00 x 10-5, and AS° is 41.8 J K-1 mol-¹. Calculate 4Gº and AH° at 25.0 °C.arrow_forward2) Give the proper solution, the given, and what is asked.arrow_forward
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