Practice ProblemATTEMPT
Calculate the standard entropy change for the following reactions at
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- For which of the following reactions, if any, if ΔS ° positive?arrow_forwardDetermine the free energy change for each of the following reactions, which are run under standard state conditions and 25 °C. Identify each as either spontaneous or nonspontaneous at these conditions.(a) C(s, graphite) + O2(g) ⟶ CO2(g)(b) O2(g) + N2(g) ⟶ 2NO(g)(c) 2Cu(s) + S(g) ⟶ Cu2 S(s)(d) CaO(s) + H2 O(l) ⟶ Ca(OH)2(s)(e) Fe2 O3(s) + 3CO(g) ⟶ 2Fe(s) + 3CO2(g)(f) CaSO4 ·2H2 O(s) ⟶ CaSO4(s) + 2H2 O(g)arrow_forwardDo te the entropy change that occurs in the system when 56.2g of liquid hexane (86.17 g/mol) boils at its normal boiling point of 68.7°C. The enthaloy of vaporization for hexane is 3156 k/mol. (18) (A) (B) (C) (D) (E) 60.2 J/K 0.300 J/K 2.06 x 10 J/K 92.3 J/K 20.6 J/Karrow_forward
- Find G° for the reactions using ΔH°(f ) and S° values.arrow_forwardFor each of the following reactions, decide whether entropy is increasing (+S) or decreasing (−S).arrow_forwardCalculate ΔS°298 for the following changes.(a) SnCl4(l) ⟶ SnCl4(g)(b) CS2(g) ⟶ CS2(l)(c) Cu(s) ⟶ Cu(g)(d) H2 O(l) ⟶ H2 O(g)(e) 2H2(g) + O2(g) ⟶ 2H2 O(l)(f) 2HCl(g) + Pb(s) ⟶ PbCl2(s) + H2(g)(g) Zn(s) + CuSO4(s) ⟶ Cu(s) + ZnSO4(s)arrow_forward
- Using the standard molar entropies in Appendix C, calculatethe standard entropy change, ΔS°, for the “water-splitting”reaction at 298 K:2 H2O(l)---->2 H2(g) + O2(g) (a) 326.3 J/K (b) 265.7 J/K (c) 163.2 J/K (d) 88.5 J/K(e) -326.3 J/Karrow_forwardConsider the reaction: KCIO4(s) →KCI(s) + 202(g) and the table of values given on the right. Do you expect this reaction to be spontaneous at room temperature? Why? (A) Yes, because AGrxn is negative. (B) Yes, because Hrxn is negative. (C) Yes, because AHrxn is positive. (D) No, because AGrxn is positive. (E) No, because Hrxn is positive. Substance AG fº (kJ/mol) KCIO4(s) -300.4 KCI(s) -408.2 02(8) 0 ΔΗ,° (kJ/mol) -433 -437 0arrow_forwardFor which reaction will ΔS be positive? Group of answer choices N2O4(g) ⟶ 2 NO2(g) 2 H2(g) + O2(g) ⟶2 H2O(g) 3 NO(g) ⟶NO2(g) + N2O(g) 2 SO2(g) + O2(g) ⟶2 SO3(g)arrow_forward
- QUESTION 22 At what temperature, in Kelvin, does the following reaction change from spontaneous to non-spontaneous 2 A (aq) + 2 B (aq) 2 C (aq) + 1 D (aq) if AH° (A)= 0.8219 kJ/mol, AH° (B) = -40.5308 kJ/mol, AH° (C) = -85.3178 kJ/mol, and AH (D) = -70 8643 kJ/mol AS (A)= 76.117 J/(mol K), AS (B) = -15.8072 J/(mol K), AS (C) = 18.4425 J/(mol K), and AS" (D) = -8.6387 J/(mol K)arrow_forwardWithout doing a calculation, predict the sign of ΔS for each of the following reactions:arrow_forward10:59 1 Question 13 of 20 Submit Which of the following sets of conditions is true for an exothermic reaction that is spontaneous at all temperatures? A) AH 0, AS 0 D) AH > 0, AS 0, ΔG <0arrow_forward
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