Organic Chemistry
Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Chapter 18.1, Problem 18.1P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

(b)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -ORorOAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(c)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -ORorOAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(d)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

The two acyl groups bonded to a nitrogen atom is the functional group of an imide.

(e)

Interpretation Introduction

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -ORorOAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(f)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

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Chapter 18 Solutions

Organic Chemistry

Ch. 18.8 - The following sequence of steps is used to create...Ch. 18.9 - Prob. 18.8PCh. 18.9 - Prob. 18.9PCh. 18.10 - Prob. 18.10PCh. 18.10 - Show how to convert (R)-2-phenylpropanoic acid to...Ch. 18 - Prob. 18.12PCh. 18 - Write the IUPAC name for each compound. (a)...Ch. 18 - Prob. 18.14PCh. 18 - Prob. 18.15PCh. 18 - Propose a structural formula for compound A,...Ch. 18 - Propose a structural formula for compound B,...Ch. 18 - Propose a structural formula for each compound...Ch. 18 - Draw a structural formula for the principal...Ch. 18 - Prob. 18.20PCh. 18 - Prob. 18.21PCh. 18 - Prob. 18.22PCh. 18 - Prob. 18.23PCh. 18 - Prob. 18.24PCh. 18 - Show the product expected when the following...Ch. 18 - The reagent diisobutylaluminum hydride (DIBALH)...Ch. 18 - Prob. 18.27PCh. 18 - Prob. 18.28PCh. 18 - Prob. 18.29PCh. 18 - Nicotinic acid, more commonly named niacin, is one...Ch. 18 - Prob. 18.31PCh. 18 - Prob. 18.32PCh. 18 - Prob. 18.33PCh. 18 - Prob. 18.34PCh. 18 - Prob. 18.35PCh. 18 - Isoniazid, a drug used to treat tuberculosis, is...Ch. 18 - Prob. 18.37PCh. 18 - A step in a synthesis of PGE1 (prostaglandin E1,...Ch. 18 - Prob. 18.39PCh. 18 - Prob. 18.40PCh. 18 - Show how to synthesize 5-nonanone from...Ch. 18 - Prob. 18.42PCh. 18 - The following sequence of steps converts...Ch. 18 - Prob. 18.44PCh. 18 - Prob. 18.45PCh. 18 - Prob. 18.46PCh. 18 - Prob. 18.47PCh. 18 - Following is a retrosynthetic analysis for the...Ch. 18 - Prob. 18.50PCh. 18 - Given this retrosynthetic analysis, propose a...Ch. 18 - Prob. 18.52PCh. 18 - Prob. 18.53PCh. 18 - Prob. 18.54PCh. 18 - In Problem 7.28, we saw this step in Johnsons...Ch. 18 - Prob. 18.56PCh. 18 - Prob. 18.57PCh. 18 - Prob. 18.58PCh. 18 - Prob. 18.59PCh. 18 - Prob. 18.60PCh. 18 - Prob. 18.61PCh. 18 - Prob. 18.62PCh. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Minoxidil is a molecule that causes hair growth in...Ch. 18 - Prob. 18.69PCh. 18 - Prob. 18.70PCh. 18 - Prob. 18.71P
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