The structural formula for the given compound has to be drawn. Concept introduction: Nomenclature of amides and imides: The acyl group bonded to a nitrogen atom is the functional group of an amide. The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide. The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘ The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

Question

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Answer 1

Question

Chapter 18.1, Problem 18.1P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

(b)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(c)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(d)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

The two acyl groups bonded to a nitrogen atom is the functional group of an imide.

(e)

Interpretation Introduction

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(f)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

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Students have asked these similar questions

(a) Draw the structures for the eight constitutional isomers of molecular formula C 4H 11N. (b) Give the systematic name for each amine. (c) Identify the chirality center present in one of the amines.

Draw and name compounds that meet these descriptions:(a) Three different amides with the formula C5H11NO(b) Three different esters with the formula C6H12O2

Amines with more than 6 carbons are soluble in: a) aqueous HCI b) aqueous NaHCO3 d) water c) aqueous NaOH Which of the following would give a positive iodoform test? acetone a) benzophenone c) 3-pentanone d) cyclopentanone meth "Saponification" as the term is used in organic chemistry means: a) acidic hydrolysis of an ester b) basic hydrolysis of an ester c) acidic hydrolysis of an amide d) basic hydrolysis of an amide 3. ( Propylamine can be synthesized by the LiAlH4 reduction of: a) CH3CH2CECH b) CH3CH=NH d)) CH3CH2CEN c) CH3CH2NO2

Answer 2

Question

Chapter 18.1, Problem 18.1P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

(b)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(c)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(d)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

The two acyl groups bonded to a nitrogen atom is the functional group of an imide.

(e)

Interpretation Introduction

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(f)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

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Answer 3

Question

Chapter 18.1, Problem 18.1P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

(b)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(c)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(d)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

The two acyl groups bonded to a nitrogen atom is the functional group of an imide.

(e)

Interpretation Introduction

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(f)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

Expert Solution & Answer

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See solution

Answer 4

Question

Chapter 18.1, Problem 18.1P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

(b)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(c)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(d)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

The two acyl groups bonded to a nitrogen atom is the functional group of an imide.

(e)

Interpretation Introduction

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(f)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

Expert Solution & Answer

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See solution

Answer 5

Chapter 18.1, Problem 18.1P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

(b)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(c)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(d)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

The two acyl groups bonded to a nitrogen atom is the functional group of an imide.

(e)

Interpretation Introduction

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

(f)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

Answer 6

Chapter 18.1, Problem 18.1P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

Answer 7

Chapter 18.1, Problem 18.1P

(a)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

Answer 8

(b)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

Answer 9

(b)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

Answer 10

(c)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

Answer 12

(d)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

The two acyl groups bonded to a nitrogen atom is the functional group of an imide.

Answer 13

(d)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

The two acyl groups bonded to a nitrogen atom is the functional group of an imide.

Answer 14

(e)

Interpretation Introduction

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

Answer 15

(e)

Interpretation Introduction

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of esters of carboxylic acids:

The acyl group bonded to -OR or OAr is the functional group of a carboxylic ester.

The naming of an ester of a carboxylic acid is done by naming alkyl or aryl group bonded to oxygen first followed by the name of the acid in which the suffix –ic acid is replaced by the suffix –ate.

Answer 16

(f)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

Answer 17

(f)

Interpretation Introduction

Interpretation:

The structural formula for the given compound has to be drawn.

Concept introduction:

Nomenclature of amides and imides:

The acyl group bonded to a nitrogen atom is the functional group of an amide.

The naming of an amide can be done by giving the suffix –oic acid from the IUPAC name of the parent acid and adding –amide.

The location of the alkyl or aryl group attached on nitrogen atom in an amide is indicated by ‘N-‘

The indication “ N,N-di-“ is used for two identical alkyl or aryl groups on nitrogen atom

Answer 18

Expert Solution & Answer

Answer 19

Expert Solution & Answer

Answer 20

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Answer 21

Ch. 18.1 - Prob. 18.1P Ch. 18.2 - Prob. 18.2P Ch. 18.4 - Prob. 18.3P Ch. 18.4 - Prob. 18.4P Ch. 18.4 - Synthesis of nitriles by nucleophilic displacement...Ch. 18.5 - Complete the following transesterification...Ch. 18.6 - Complete and balance equations for the following...Ch. 18.8 - Prob. AQ Ch. 18.8 - Several compounds have been found to inhibit...Ch. 18.8 - Prob. CQ

Solution Summary: The author explains the structural formula for the given compound.

Concept explainers

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Chapter 18 Solutions