Organic Chemistry
8th Edition
ISBN: 9781305580350
Author: William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher: Cengage Learning
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Textbook Question
Chapter 18.4, Problem 18.5P
Synthesis of nitriles by nucleophilic displacement of halide from a haloalkane (also called an
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By malonic or acetylacetic synthesis, synthesize 2-methylbutanoic acid (indicate the formulas of the compounds).
Obtain 2-methylbutanoic acid by malonic or acetylacetic synthesis (indicate the formulas of the compounds involved).
EFFICIENTS
SAMPLE READINGS
CONCENTRATIONS
Pigiadient)
TOMATO SAUCE (REGULAR)
TOMATO (REDUCED SALT)
TOMATO SAUCE (REGULAR)
TOMATO (REDUCED SALT)
58
6.274
3.898
301.7
151.2
14150
5.277
3.865
348.9
254.8
B
5.136
3.639
193.7
85.9
605
4.655
3.041
308.6
199.6
05
5.135
3.664
339.5
241.4
0139
4.676
3.662
160.6
87.6
90148
5.086
3.677
337.7
242.5
0092
6.348
3.775
464.7
186.4
PART3
5.081
3.908
223.5
155.8
5.558
3.861
370.5
257.1
4.922
3.66
326.6
242.9
4.752
3.641
327.5
253.3
50
5.018
3.815
336.1
256.0
84
4.959
3.605
317.9
216.6
38
4.96
3.652
203.8
108.7
$3
5.052
3.664
329.8
239.0
17
5.043
3.767
221.9
149.7
052
5.058
3.614
331.7
236.4
5.051
4.005
211.7
152.1
62
5.047
3.637
309.6
222.7
5.298
3.977
223.4
148.7
5.38
4.24
353.7
278.2
5
5.033
4.044
334.6
268.7
995
4.706
3.621
305.6
234.4
04
4.816
3.728
340.0
262.7
16
4.828
4.496
304.3
283.2
0.011
4.993
3.865
244.7
143.6
AVERAGE
STDEV
COUNT
95% CI Confidence Interval (mmol/L)
[Na+] (mg/100 mL)
95% Na+ Confidence Interval (mg/100 mL)
Chapter 18 Solutions
Organic Chemistry
Ch. 18.1 - Prob. 18.1PCh. 18.2 - Prob. 18.2PCh. 18.4 - Prob. 18.3PCh. 18.4 - Prob. 18.4PCh. 18.4 - Synthesis of nitriles by nucleophilic displacement...Ch. 18.5 - Complete the following transesterification...Ch. 18.6 - Complete and balance equations for the following...Ch. 18.8 - Prob. AQCh. 18.8 - Several compounds have been found to inhibit...Ch. 18.8 - Prob. CQ
Ch. 18.8 - The following sequence of steps is used to create...Ch. 18.9 - Prob. 18.8PCh. 18.9 - Prob. 18.9PCh. 18.10 - Prob. 18.10PCh. 18.10 - Show how to convert (R)-2-phenylpropanoic acid to...Ch. 18 - Prob. 18.12PCh. 18 - Write the IUPAC name for each compound. (a)...Ch. 18 - Prob. 18.14PCh. 18 - Prob. 18.15PCh. 18 - Propose a structural formula for compound A,...Ch. 18 - Propose a structural formula for compound B,...Ch. 18 - Propose a structural formula for each compound...Ch. 18 - Draw a structural formula for the principal...Ch. 18 - Prob. 18.20PCh. 18 - Prob. 18.21PCh. 18 - Prob. 18.22PCh. 18 - Prob. 18.23PCh. 18 - Prob. 18.24PCh. 18 - Show the product expected when the following...Ch. 18 - The reagent diisobutylaluminum hydride (DIBALH)...Ch. 18 - Prob. 18.27PCh. 18 - Prob. 18.28PCh. 18 - Prob. 18.29PCh. 18 - Nicotinic acid, more commonly named niacin, is one...Ch. 18 - Prob. 18.31PCh. 18 - Prob. 18.32PCh. 18 - Prob. 18.33PCh. 18 - Prob. 18.34PCh. 18 - Prob. 18.35PCh. 18 - Isoniazid, a drug used to treat tuberculosis, is...Ch. 18 - Prob. 18.37PCh. 18 - A step in a synthesis of PGE1 (prostaglandin E1,...Ch. 18 - Prob. 18.39PCh. 18 - Prob. 18.40PCh. 18 - Show how to synthesize 5-nonanone from...Ch. 18 - Prob. 18.42PCh. 18 - The following sequence of steps converts...Ch. 18 - Prob. 18.44PCh. 18 - Prob. 18.45PCh. 18 - Prob. 18.46PCh. 18 - Prob. 18.47PCh. 18 - Following is a retrosynthetic analysis for the...Ch. 18 - Prob. 18.50PCh. 18 - Given this retrosynthetic analysis, propose a...Ch. 18 - Prob. 18.52PCh. 18 - Prob. 18.53PCh. 18 - Prob. 18.54PCh. 18 - In Problem 7.28, we saw this step in Johnsons...Ch. 18 - Prob. 18.56PCh. 18 - Prob. 18.57PCh. 18 - Prob. 18.58PCh. 18 - Prob. 18.59PCh. 18 - Prob. 18.60PCh. 18 - Prob. 18.61PCh. 18 - Prob. 18.62PCh. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Using your reaction roadmap as a guide, show how...Ch. 18 - Minoxidil is a molecule that causes hair growth in...Ch. 18 - Prob. 18.69PCh. 18 - Prob. 18.70PCh. 18 - Prob. 18.71P
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