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Concept explainers
(a)
Interpretation:
IUPAC name of the given compound has to be assigned.
Concept Introduction:
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain
alkane is replaced by “-amine”. - Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
In a line-angle structural formula, the point of intersection and the end points represent a carbon atom.
(b)
Interpretation:
IUPAC name of the given compound has to be assigned.
Concept Introduction:
IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.
- Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
(c)
Interpretation:
IUPAC name of the given compound has to be assigned.
Concept Introduction:
IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.
- Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
In a line-angle structural formula, the point of intersection and the end points represent a carbon atom.
(b)
Interpretation:
IUPAC name of the given compound has to be assigned.
Concept Introduction:
IUPAC nomenclature for amine: There are about five rules to be followed in giving IUPAC name for an amine.
- Longest carbon chain has to be identified that is attached to nitrogen atom.
- Suffix “-e” in name of the parent chain alkane is replaced by “-amine”.
- Numbering of the carbon chain is done from the end that is near the nitrogen atom.
- Point of attachment of the nitrogen atom in the carbon chain is indicated by a number before the parent chain name.
- In case if substituents are present, then the identity and location of substituents are appended to the front in the parent chain name.
If the compound contains two amine groups, then the suffix “-e” is replaced by diamine. Tertiary and secondary amines are named as N-substituted primary amines.
Common name for amine is given in a single word. Primary amine is named as alkylamine. Secondary amine is named as alkylalkylamine. Tertiary amine is named as alkylalkylalkylamine.
In a line-angle structural formula, the point of intersection and the end points represent a carbon atom.
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Chapter 17 Solutions
Study Guide with Selected Solutions for Stoker's General, Organic, and Biological Chemistry, 7th
- Synthesize the following compound from cyclohexanol, ethanol, and any other needed reagentsarrow_forwardFor a titration of 20.00 mL of 0.0500 M H2SO4 with 0.100 M KOH, calculate the pH at each of the following volume of KOH used in the titration: 1) before the titration begin; 2) 10.00 mL; 3) 20.00 mL; 4) 30.00 mL. Ka2 = 1.20×10-2 for H2SO4.arrow_forwardCurved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s) Be sure to account for all bond-breaking and bond-making steps Problem 73 of 10 Drawing Amows ro HO Donearrow_forward
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- Show work with explanation needed. Don't give Ai generated solutionarrow_forwardA Elschboard Part of SpeechT-D Alt Leaming App app.aktiv.com Curved arrows are used to illustrate the flow of electrons. Using the provided resonance structures, draw the curved electron- pushing arrows to show the interconversion between resonance hybrid contributors. Be sure to account for all bond-breaking and bond-making steps. Include all lone pairs and formal charges in the structures. Problem 45 of 10 I Select to Add Arrows N Please selarrow_forwardSo I'm working on molecular geometry. Can you help me with this stuff here and create three circles: one that's 120, one that’s 180, and one that’s 109.5?arrow_forward
- Curved arrows are used to illustrate the flow of electrons. Using the provided starting and product structures, draw the curved electron-pushing arrows for the following reaction or mechanistic step(s). Be sure to account for all bond-breaking and bond-making steps. Problem 164 of N Select to Add Arrows CHI CH 1 1 1 Parrow_forwardusing these can you help me , I guess convert them to lewis dit structures or full drawn out skeletal and I guess is that what would help me depict the bond angle.arrow_forwardShow reaction mechanism with explanation.don't give Ai generated solutionarrow_forward
- General, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage LearningOrganic And Biological ChemistryChemistryISBN:9781305081079Author:STOKER, H. Stephen (howard Stephen)Publisher:Cengage Learning,Chemistry for Today: General, Organic, and Bioche...ChemistryISBN:9781305960060Author:Spencer L. Seager, Michael R. Slabaugh, Maren S. HansenPublisher:Cengage Learning
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning
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